Abstract
Real-time FTIR spectroscopy was used to study the UV-light induced crosslinking of a pressure sensitive adhesive based on a saturated acrylic polymer bearing a photoreactive functional group in the side chain. To simulate production parameters, e.g., cure speed and number of required UV lamps, single or multiple UV-light flash experiments were performed which have shown that the amount of crosslinked polymer chains in the adhesive depends on the applied UV dose. The same result was observed by varying the intensity of the UV-light. The properties of the pressure sensitive adhesive, e.g., peel and shear strength, were determined by UV curing using a laboratory irradiation unit. These results were compared with those of the RTIR spectroscopy experiments.
Similar content being viewed by others
References
Schumacher, K.-H., Düsterwald, U., and Fink, R., “UV-Acrylic Hotmelts—Combining Hotmelt Coating Technology with Acrylic High Performance Chemistry,”Proc. RadTech Europe 99, Berlin, 559 (1999).
Mehnert, R., “Radiation Curing: Definition and Basic Characteristics,” inUV & EB Curing Technology & Equipment, Mehnert, R., Pincus, A., and Janovský, I. (Eds.), John Wiley & Sons/SITA Technology Ltd., London, 1999.
Kauffman, T. and Mitry, M., “A New Cure for Sticky Situations. Examining Technology Advances and Market Opportunities for UV/EB Curable Pressure Sensitive Adhesives,”Adhesives Age, 2, s8 (2000).
Glofelter, C., “Valuable Properties. Tg Region Breadth is Critical to UV-Curable PSA Performance,”Adhesives Age, 2, s24 (2000).
Erickson, J.R. and Mancinelli, P.A., “UV-Curable PSAs Offer Excellent Performance and Fast Production Rates. High Speed, Hi-Tech,”Adhesives Age, 2, s11 (2000).
Dupont, M., Masse, M., and Schneider, J., “Rubber-Based Radiation Curable Pressure Sensitive Adhesives,”Proc. RadTech Europe 99, Berlin, 551 (1999).
Zöllner, S., “UV-Curable Acrylic Pressure Sensitive Adhesives. Features, Mechanisms, Milestones,”Proc. RadTech Europe 99, Berlin, 543 (1999).
Schumacher, K.-H. and Sandborn, T., “UV-Acrylic Hot Melts—Performance and Processing of an Attractive Raw Material for Self-Adhesive Articles,”Tech. Proc. RadTech North America 2000, Baltimore, 185 (2000).
Crivello, J.V. and Dietliker, K.,Photoinitiators for Free Radical Cationic & Anionic Photopolymerization, John Wiley & Sons/SITA Technology Ltd., London, 1998.
Decker, C. and Moussa, K., “Photopolymerization of Multi-functional Monomers in Condensed Phase,”J. Appl. Polym. Sci., 34, 1603 (1987).
Decker, C., “Kinetic Analysis and Performance of UV-Curable Coatings,” inRadiation Curing: Science and Technology, Pappas, S.P. (Ed.), Plenum Press, New York, 1992.
Scherzer, T. and Decker, U., “Real-Time FTIR-ATR Spectroscopy to Study the Kinetics of Ultrafast Photopolymerization Reactions Induced by Monochromatic UV Light,”Vibr. Spectr., 19, 385 (1999).
Tauber, A., Scherzer, T., and Mehnert, R., “UV Curing of Aqueous Polyurethane Acrylate Dispersions. A Comparative Study by Real-Time FTIR Spectroscopy and Pilot Scale Curing,”Journal of Coatings Technology,72, No. 911, 51 (2000).
Colthup, N.B., Daly, L.H., and Wiberley, S.E.,Introduction to Infrared and Raman Spectroscopy, Academic Press, Inc., San Diego, 1992.
Mehnert, R., “UV Curing Equipment—Polychromatic UV Lamps,” inUV & EB Curing Technology & Equipment, Mehnert, R., Pincus, A., and Janovský, I. (Eds.), John Wiley & Sons/SITA Technology Ltd., London, 1999.
Müller, R., “UV-Systems for Curing of Radiation-Curable UV-Acrylates,”Proc. RadTech Europe 99, Berlin, 591 (1999).
Herlihy, S.L. and Battersby, G.C., “UV Inner Filter Effects and Photoinitiation Efficiency,”Proc. RadTech North America 94, Orlando, 156 (1994).
Author information
Authors and Affiliations
Additional information
Permoserstr. 15, D-04318 Leipzig, Germany. Tel: +49-341-235-2049; fax: +49-341-235-2584.
Rights and permissions
About this article
Cite this article
Tauber, A., Scherzer, T., Weiß, I. et al. UV curing of a pressure sensitive adhesive coating studied by real-time FTIR spectroscopy and laboratory scale curing experiments. Journal of Coatings Technology 74, 41–47 (2002). https://doi.org/10.1007/BF02720163
Issue Date:
DOI: https://doi.org/10.1007/BF02720163