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Determination and Method Validation of Metamitron in Soil by RP-HPLC

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Abstract

A simple, rapid and economical method was developed and validated for the determination of metamitron using UV detector with RP-HPLC. Study of metamitron in soil was carried out. The compound was extracted from soil by methanol and clean-up was done on C-18 SPE column. Recovery ranged from 90.75 % to 94.05 % within 0.1–2.0 μg g−1 and RSD 1.80 %. Retention time was 3.8 min and limit of detection and limit of quantification were 0.001 and 0.008 μg g−1. The results indicated that the reported method could meet the requirement for the analysis of metamitron in trace amounts.

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References

  • Arranz A, De Betono SF, Moreda Jose M, Cid A, Arranz JF (1997) Preconcentration and voltammetric of the herbicide metamitron with silica-modified carbon paste electrode. Mikrochim Acta 127:273–279

    Article  CAS  Google Scholar 

  • Drozdzyñski D, Folkman W (2006) Determination of metamitron residues in sugar beet plants and soil applying solid-supported liquid–liquid extraction followed by gradient RP-HPLC. Chem Anal (Warsaw) 51:439

    Google Scholar 

  • EU Pesticide database (2013). http://ec.europa.eu/sanco_pesticides/public/index.cfm?event=substance.resultat&s=1. Accessed on 20 Jan, 2013

  • European Union Reference Laboratory (2011). Pesticides in fruits and vegetables. University of Almeria, Spain. www.crl-pesticides.eu/library/docs/fv/Validation-oliveoil.pdf. Assessed on 25 Dec, 2012

  • Ghebbioni C, Trevisan M (1992) Determination of sugarbeet herbicides in soil samples by HPLC. Pesticide Sci 34:105–107

    Article  CAS  Google Scholar 

  • Goicolea MA, Arranz JF, Barrio RJ, Gómez de Balugera Z (1991) Differential-pulse adsorptive stripping voltammetry of the herbicides metamitron and isometiozine. Fresenius J Anal Chem 339(3):166–168

    Article  CAS  Google Scholar 

  • Hongji P, Qunfeng Z, Li Changping (2000) Analysis of metamitron by HPLC. Pesticide Sci Adm 2000(2):4–24

    Google Scholar 

  • Kucharski M, Domaradzki K, Barbara W (2008) Micro-rates of herbicides used in sugar beet crop—influence on herbicide residues level in roots and soil. Pestycydy 3–4:63–69

    Google Scholar 

  • Moros J, Armenta S, Garrigues S, de la Guardia M (2006) Quality controls of metamitron in agrochemicals using Fourier transform infrared spectroscopy in the middle and near range. Anal Chim Acta 565(2):255–260

    Article  CAS  Google Scholar 

  • SANCO/12495/2011 (2011) Method validation and quality control procedures for pesticides residue analysis in food and feed. www.ec.europa.eu/food/plants/protection/pesticides/docs/qualControl_en.pdf. Assessed on 20 Dec, 2012

  • Tomlin CDS (2002) The pesticide manual, 12th edn. British Crop Protection Council (BCPC) Publication, Hampshire, pp 608–609

    Google Scholar 

  • Valentin JFA, Altuna GA, Diez-Caballero RJB, Garcia AA (1989) Study of the conditions for the determination of metamitron by differential pulse polarography. Fresenius J Anal Chem 333(3):218–220

    Article  Google Scholar 

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Acknowledgments

The authors thankful to M/s Punjab Chemicals and Crop Protection Limited, India for providing analytical grade and formulation of metamitron and G.B.P.U.A & T, Pantnagar (India) for providing facilities related to research.

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Correspondence to Shishir Tandon.

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Kumar, S., Tandon, S. & Sand, N.K. Determination and Method Validation of Metamitron in Soil by RP-HPLC. Bull Environ Contam Toxicol 92, 165–168 (2014). https://doi.org/10.1007/s00128-013-1151-z

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  • DOI: https://doi.org/10.1007/s00128-013-1151-z

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