Abstract
In this study, we synthesized an aliphatic–aromatic regular network as a novel covalent organic networks called TEPN-1 (Thiol-ene Polymer Network) and TEPN-2 via thiol-ene chemistry. TEPN-1 and TEPN-2 were analyzed by FTIR, 13C-NMR, Brunauer–Emmett–Teller, thermogravimetric analysis and elemental analysis. Solvent uptake capacity of TEPN-1 and TEPN-2 was employed against 26 solvents which are frequently used in chemical industry. It is found that TEPN-1 has the highest swelling adsorption ratio with chloroform and DCM (13.7 and 11.5 g.g−1, respectively), while TEPN-2 has 9.2 and 7.5 g.g−1, respectively. Both TEPN-1 and TEPN-2 have very minimal water uptake (0.165 and 0.189 g.g−1, respectively). TEPN-1 and TEPN-2 are efficient adsorbents for most of organic solvents including water-miscible organic solvents such as THF, dioxane and pyridine.
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Acknowledgements
This work was supported by TUBITAK (Project No.112M096, COST TD1004). The authors also thank to Semra Filikci and Mehmet Ulasan for their support.
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Yavuz, M.S., Citir, M. Highly efficient chlorinated solvent uptake by novel covalent organic networks via thiol-ene chemistry. Polym. Bull. 79, 6343–6356 (2022). https://doi.org/10.1007/s00289-021-03809-4
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DOI: https://doi.org/10.1007/s00289-021-03809-4