Abstract
Herein, superhydrophobic 4037 aluminum alloy surface with self-cleaning and anti-icing properties has been fabricated by a low-cost processing consisting of HCl/H2O2 treatment and modification of an ultra-low concentration of fluoroalkylsilane. Via a chemical etching, a coral-like hierarchical micro-nano structure has been formed on 4037 aluminum alloy substrate. Then, the wettability of etched surface treated with different levels of fluoroalkylsilane has been investigated. The results show that the etched surface after been modified with petroleum ether containing 20 mg fluoroalkylsilane can result in superhydrophobicity with a water contact angle of 160.8° and a sliding angle of 2.4°. Especially, effects of solvents on the wettability of fabricated surface have also been studied. It is found that alkane such as petroleum ether is suitably used as a solvent for fluoroalkylsilane due to a reduction on fluoroalkylsilane. In addition, obvious self-cleaning and anti-icing behaviors of the as-prepared superhydrophobic surface have been proved, which will extend the further application of aluminum alloy.
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R. Hensel, A. Finn, R. Helbig, H.G. Braun, C. Neinhuis, W.J. Fischer, C. Werner, Biologically inspired omniphobic surfaces by reverse imprint lithography. Adv. Mater. 26(13), 2029–2033 (2013). https://doi.org/10.1002/adma.201305408
S. Wang, K. Liu, X. Yao, L. Jiang, Bioinspired surfaces with superwettability: new insight on theory, design, and applications. Chem. Rev. 115(16), 8230–8293 (2015). https://doi.org/10.1021/cr400083y
W. Barthlott, C. Neinhuis, Purity of the sacred lotus, or escape from contamination in biological surfaces. Planta 202(1), 1–8 (1997). https://doi.org/10.1007/s004250050096
G. Wen, Z. Guo, W. Liu, Biomimetic polymeric superhydrophobic surfaces and nanostructures: from fabrication to applications. Nanoscale 9(10), 3338–3366 (2017). https://doi.org/10.1039/c7nr00096k
S. Haghanifar, P. Lu, M.I. Kayes, S. Tan, K.J. Kim, T. Gao, P. Ohodnicki, P.W. Leu, Self-cleaning, high transmission, near unity haze OTS/silica nanostructured glass. J. Mater. Chem. C 6(34), 9191–9199 (2018). https://doi.org/10.1039/C8TC02513D
Y. Zhu, J. Zhang, Y. Zheng, Z. Huang, L. Feng, L. Jiang, Superhydrophobic, and conductive polyaniline/polystyrene films for corrosive environments. Adv. Funct. Mater. 16(4), 568–574 (2006). https://doi.org/10.1002/adfm.200500624
L. Feng, L. Zhao, X. Qiang, Y. Liu, Z. Sun, B. Wang, Fabrication of superhydrophobic copper surface with excellent corrosion resistance. Appl. Phys. A: Mater. Sci. Process 119(1), 75–83 (2015). https://doi.org/10.1007/s00339-014-8959-1
P. Guo, Y. Zheng, M. Wen, C. Song, Y. Lin, L. Jiang, Icephobic/anti-icing properties of micro/nanostructured surfaces. Adv. Mater. 24(19), 2642–2648 (2012). https://doi.org/10.1002/adma.201104412
X. Lu, X. Huang, L. Wang, Superhydrophobic hierarchical structure carbon mesh films for oil/water separation application. Appl. Phys. A: Mater. Sci. Process 123(8), 538 (2017). https://doi.org/10.1007/s00339-017-1113-0
T. Yang, H. Pan, G. Tian, B. Zhang, D. Xiong, Y. Gao, C. Yan, X. Chu, N. Chen, S. Zhong, L. Zhang, W. Deng, W. Yang, Hierarchically structured PVDF/ZnO core-shell nanofibers for self-powered physiological monitoring electronics. Nano Energy 72, 104706 (2020). https://doi.org/10.1016/j.nanoen.2020.104706
S. Wang, L. Jiang, Definition of superhydrophobic states. Adv. Mater. 19, 13423–13424 (2007). https://doi.org/10.1002/adma.200700934
N. Saleema, D.K. Sarkar, D. Gallant, R.W. Paynter, X.G. Chen, Chemical nature of superhydrophobic aluminum alloy surfaces produced via a one-step process using fluoroalkyl-silane in a base medium. ACS Appl. Mater. Interf. 3(12), 4775–4781 (2011). https://doi.org/10.1021/am201277x
S. Wang, L. Feng, L. Jiang, One-step solution-immersion process for the fabrication of stable bionic superhydrophobic surfaces. Adv. Mater. 18(6), 767–770 (2006). https://doi.org/10.1002/adma.200501794
C.V. Ngo, D.M. Chun, Control of laser-ablated aluminum surface wettability to superhydrophobic or superhydrophilic through simple heat treatment or water boiling post-processing. Appl. Surf. Sci. 435, 974–982 (2018). https://doi.org/10.1016/j.apsusc.2017.11.185
X. Su, H. Li, X. Lai, Z. Yang, Z. Chen, W. Wu, X. Zeng, Vacuum-assisted layer-by-layer superhydrophobic carbon nanotube films with electrothermal and photothermal effects for deicing and controllable manipulation. J. Mater. Chem. A 35, 16910–16919 (2018). https://doi.org/10.1039/c8ta05273e
J. Bravo, L. Zhai, Z. Wu, R.E. Cohen, M.F. Rubner, Transparent superhydrophobic films based on silica nanoparticles. Langmuir 23(13), 7293–7298 (2007). https://doi.org/10.1021/la070159q
S. Piltan, J. Seyfi, I. Hejazi, S.M. Davachi, H.A. Khonakdar, Superhydrophobic filter paper via an improved phase separation process for oil/water separation: study on surface morphology, composition and wettability. Cellulose 23(6), 3913–3924 (2016). https://doi.org/10.1007/s10570-016-1059-y
N. Xu, D.K. Sarkar, G.X. Chen, H. Zhang, W. Tong, Superhydrophobic copper stearate/copper oxide thin films by a simple one-step electrochemical process and their corrosion resistance properties. RSC Adv. 6(42), 35466–35478 (2016). https://doi.org/10.1039/c6ra01944g
B.N. Sahoo, B. Kandasubramanian, Recent progress in fabrication and characterisation of hierarchical biomimetic superhydrophobic structures. RSC Adv. 4(42), 22053–22093 (2014). https://doi.org/10.1039/c4ra00506f
S. Peng, D. Tian, X. Yang, W. Deng, Highly efficient and large-scale fabrication of superhydrophobic alumina surface with strong stability based on self-congregated alumina nanowires. ACS Appl. Mater. Interf. 6(7), 4831–4841 (2014). https://doi.org/10.1021/am4057858
M. Ruan, W. Li, B. Wang, B. Deng, F. Ma, Z. Yu, Preparation and anti-icing behavior of superhydrophobic surfaces on aluminum alloy substrates. Langmuir 29(27), 8482–8491 (2013). https://doi.org/10.1021/la400979d
W. Li, Y. Wang, Y. Feng, Q. Wang, X. Xu, G. Li, G. Dong, C.E. Jing, X. Fan, P. Wang, A cost-effective method for preparing robust and conductive superhydrophobic coatings based on asphalt. Scanning. 2020, 1–8 (2020). https://doi.org/10.1155/2020/5642124
F. Zhang, P. Zhang, Fabrication and characterization of superhydrophobic surfaces on aluminum alloy substrates. Appl. Surf. Sci. 321, 166–172 (2014). https://doi.org/10.1016/j.apsusc.2014.09.147
A. Khaskhoussi, L.E. Proverbio, Superhydrophobic self-assembled silane monolayers on hierarchical 6082 aluminum alloy for anti-corrosion applications. Appl. Sci. Basel 10(8), 2656 (2020). https://doi.org/10.3390/app10082656
A.R.C. Carneiro, F.A.D. Ferreira, M. Houmard, Easy functionalization process applied to develop super-hydrophobic and oleophobic properties on ASTM 1200 aluminum surface. Surf. Interf. Anal. 50(12–13), 1370–1383 (2018). https://doi.org/10.1002/sia.6532
Z. Wei, D. Jiang, J. Chen, S. Ren, L. Li, Fabrication of mechanically robust superhydrophobic aluminum surface by acid etching and stearic acid modification. J. Adhes. Sci. Technol. 31, 2380–2397 (2017). https://doi.org/10.1080/01694243.2017.1302698
M. Wang, D. Zhang, Y. Zhen, C. Yang, Y. Tian, X. Liu, A contrastive investigation on the anticorrosive performance of stearic acid and fluoroalkylsilane-modified superhydrophobic surface in salt, alkali, and acid solution. Langmuir 36(34), 10279–10292 (2020). https://doi.org/10.1021/acs.langmuir.0c02080
V. Purcar, I. Stamatin, O. Cinteza, C. Petcu, V. Raditoiu, M. Ghiurea, T. Miclaus, A. Andronie, Fabrication of hydrophobic and antireflective coatings based on hybrid silica films by sol-gel process. Surf. Coat. Technol. 206, 4449–4454 (2012). https://doi.org/10.1016/j.surfcoat.2012.04.094
S. Xu, Q. Wang, N. Wang, Eco-friendly fabrication of superhydrophobic surface with anti-corrosion by transferring dendrite-like structures to aluminum substrate. Colloid Surf. A- Physicochem. Eng. Asp. 595, 124719 (2020). https://doi.org/10.1016/j.colsurfa.2020.124719
X. Liu, H. Shen, J. Liu, J. Zhang, Y. Chen, Z. Zhang, F. Zhang, N. Guan, D. Zhao, Z. Jin, A green, maskless, and universal preparation method for patterned surfaces on various metal substrates. Appl. Surf. Sci. 514, 145838 (2020). https://doi.org/10.1016/j.apsusc.2020.145838
X. Li, S. Yin, S. Huang, H. Luo, Q. Tang, Fabrication of durable superhydrophobic Mg alloy surface with water-repellent, temperature-resistant, and self-cleaning properties. Vacuum 173, 10917 (2020). https://doi.org/10.1016/j.vacuum.2020.109172
X. Li, Q. Zhang, Z. Guo, T. Shi, J. Yu, M. Tang, X. Huang, Fabrication of superhydrophobic surface with improved corrosion inhibition on 6061 aluminum alloy substrate. Appl. Surf. Sci. 342, 76–83 (2015). https://doi.org/10.1016/j.apsusc.2015.03.040
X. Li, Q. Zhang, Z. Guo, J. Yu, M. Tang, X. Huang, Low-cost and large-scale fabrication of a superhydrophobic 5052 aluminum alloy surface with enhanced corrosion resistance. RSC Adv. 5, 29639–29646 (2015). https://doi.org/10.1039/c5ra00324e
B. Bhushan, M. Nosonovsky, The rose petal effect and the modes of superhydrophobicity. Philos. T. R. Soc. A 368(1929), 4713–4728 (2010). https://doi.org/10.1098/rsta.2010.0203
A.B.D. Cassie, S. Baxter, Wettability of porous surfaces. Trans. Faraday Soc. 40, 546–551 (1944). https://doi.org/10.1039/tf9444000546
N. Saleema, D.K. Sarkar, R.W. Paynter, X.G. Chen, Superhydrophobic aluminum alloy surfaces by a novel one-step process. ACS Appl. Mater. Interf. 2(9), 2500–2502 (2010). https://doi.org/10.1021/am100563u
D.K. Sarkar, R.W. Paynter, One-step deposition process to obtain nanostructured superhydrophobic thin films by galvanic exchange reactions. J. Adhes. Sci. Tech. 24(6), 1181–1189 (2010). https://doi.org/10.1163/016942409X12598231568546
A. Alizadeh, M. Yamada, R. Li, W. Shang, S. Otta, S. Zhong, M.L. Blohm, Dynamics of ice nucleation on water repellent surfaces. Langmuir 28(6), 3180–3186 (2012). https://doi.org/10.1021/la2045256
Y. Shen, J. Tao, H. Tao, S. Chen, L. Pan, T. Wang, Anti-icing potential of superhydrophobic Ti6Al4V surfaces: ice nucleation and growth. Langmuir 31(39), 10799–10806 (2015). https://doi.org/10.1021/acs.langmuir.5b02946
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This work was supported by the National Natural Science Foundation of China (U1833202).
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Shi, T., Xue, S., Ma, X. et al. Fabrication of superhydrophobic micro-nanostructured aluminum alloy surface via a cost-effective processing using an ultra-low concentration of fluoroalkylsilane. Appl. Phys. A 127, 399 (2021). https://doi.org/10.1007/s00339-021-04553-2
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DOI: https://doi.org/10.1007/s00339-021-04553-2