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Mid-infrared laser absorption spectrometers based upon all-diode laser difference frequency generation and a room temperature quantum cascade laser for the detection of CO, N2O and NO

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Abstract

We describe the performance of two mid-infrared laser spectrometers for carbon monoxide, nitrous oxide and nitric oxide detection. The first spectrometer for CO and N2O detection around 2203 cm-1 is based upon all-diode laser difference frequency generation (DFG) in a quasi-phase matched periodically-poled lithium niobate (PPLN) crystal using two continuous-wave room-temperature distributed feedback diode lasers at 859 and 1059 nm. We also report on the performance of a mid-infrared spectrometer for NO detection at ∼ 1900 cm-1 based upon a thermoelectrically-cooled continuous-wave distributed feedback quantum cascade laser (QCL). Both spectrometers had a single-pass optical cell and a thermoelectrically cooled HgCdZnTe photovoltaic detector. Typical minimum detection limits of 2.8 ppmv for CO, 0.6 ppmv for N2O and 2.7 ppmv for NO have been demonstrated for a 100 averaged spectra acquired within 1.25 s and a cell base length of 21 cm at ∼ 100 Torr. Noise-equivalent absorptions of 10-5 and 10-4 Hz-1/2 are typically demonstrated for the QCL and the DFG based spectrometers, respectively.

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Authors and Affiliations

  1. TDL Sensors Ltd, Core Technology Facility, 46 Grafton St, Manchester, M13 9NT, UK

    V.L. Kasyutich & R.J. Holdsworth

  2. School of Chemical Engineering and Analytical Science, University of Manchester, P.O. Box 88, Manchester, M60 1QD, UK

    P.A. Martin

Authors
  1. V.L. Kasyutich
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  2. R.J. Holdsworth
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  3. P.A. Martin
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Correspondence to V.L. Kasyutich.

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PACS

42.55.Px; 42.62.Fi; 42.65.-k; 42.72.Ai; 42.68.Ca

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Kasyutich, V., Holdsworth, R. & Martin, P. Mid-infrared laser absorption spectrometers based upon all-diode laser difference frequency generation and a room temperature quantum cascade laser for the detection of CO, N2O and NO. Appl. Phys. B 92, 271–279 (2008). https://doi.org/10.1007/s00340-008-3097-0

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  • DOI: https://doi.org/10.1007/s00340-008-3097-0

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