Abstract
This review (with 142 references) summarize the state of the art in molecularly imprinting technology as applied to the surface of carbon nanotubes (CNTs) which result in so-called CNTs@MIPs. These nanomaterials offer a remedy to the flaws of traditional MIPs, such as poor site accessibility for templates, slow mass transfer and template leakage. They also are flexible in that different materials can be integrated with CNTs. Given the advantages of using CNT@MIPs, this technology has experienced rapid expansion, not the least because CNT@MIPs can be produced at low cost and by a variety of synthetic approaches. We summarize methods of, and recent advances in the synthesis of CNT@MIPs, and then highlight some representative applications. We also comment on their potential future developments and research directions.
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Abbreviations
- 2 or 4-VP:
-
2-or 4-vinylpyridine
- AA:
-
Acrylic acid
- AEP:
-
(p-acryloylaminophenyl)-{(4-aminophenyl)-diethyl ammonium}-ethylphosphate
- AIBN:
-
Azo-bisisobutyronitrile
- APS:
-
Ammonium persulfate
- APTMS:
-
Aminopropyltrimethoxysilane
- β-CD:
-
Beta-cyclodextrin
- BDC:
-
N,N-diethyldithiocarbamate
- BSA:
-
Bovine serum albumin
- CLRP:
-
Controlled/living free radical polymerization
- CNTs:
-
Carbon nanotubes
- CNTs@MIPs:
-
Molecularly imprinted polymers on the surface of carbon nanotubes
- CS:
-
Chitosan
- CSDT:
-
Chitosan derivative
- DMAc:
-
Dimethyl acetamide
- DMF:
-
Dimethyl formamide
- DMSO:
-
Dimethyl sulfoxide
- DVB:
-
Divinylbenzene
- ECL:
-
Electrochemiluminescence
- EE:
-
Ethoxyethanol
- EGDMA or EDMA:
-
Ethylene glycol dimethacrylate
- FQs:
-
Fluoroquinolones
- Ga(III):
-
Gallium(III)
- MAA:
-
Methacrylic acid
- MIM:
-
Molecularly imprinted membrane
- MIPPy:
-
Molecular imprinted polypyrrole
- MIPs:
-
Molecularly imprinted polymers
- MIT:
-
Molecular imprinting technology
- MTMOS:
-
Methyltrimethoxysilane
- MWNTs:
-
Multiwalled carbon nanotubes
- NNMBA:
-
N,N-methylenebisacrylamide
- NPA:
-
4-nitrophenyl acrylate
- OTA:
-
Ochratoxin A
- PAMAM:
-
Polyamide amine
- PEG:
-
Polyethylene glycol
- PETRA:
-
Pentaerythritol triacrylate
- PPy:
-
Polypyrrole
- PTMOS:
-
phenyltrimethoxysilane
- SPE:
-
Solid-phase extraction
- SPME:
-
Solid phase micro extraction
- SWNTs:
-
Single-walled carbon nanotubes
- TCP:
-
2,4,6-Trichlorophenol
- TEOS:
-
Tetraethylorthosilicate
- THF:
-
Tetrahydrofuran
- μ-SPP:
-
Micro-solid phase preconcentration
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Acknowledgments
This work was supported by the National Natural Science Foundation of China(Grant NO. 81402899), the Open Project of Key Laboratory of Modern Toxicology of the Ministry of Education (Grant NO. NMUMT201404), and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.
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Hao Dai and Deli Xiao equally contributed to this work and should be considered co-first authors.
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Dai, H., Xiao, D., He, H. et al. Synthesis and analytical applications of molecularly imprinted polymers on the surface of carbon nanotubes: a review. Microchim Acta 182, 893–908 (2015). https://doi.org/10.1007/s00604-014-1376-5
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DOI: https://doi.org/10.1007/s00604-014-1376-5