Abstract
In situ measurements of aerosol particle chemistry and cloud microphysics made during the Cloud–Aerosol Interaction and Precipitation Enhancement Experiment (CAIPEEX) in 2015 over the Western Ghats and its rain shadow region are presented in this study. The high ratio of cloud condensation nuclei (CCN) to large sized aerosol (above 0.1 µm) concentrations indicates Aitken mode aerosols as the major contributor towards the observed CCN. Morphology and chemical composition of airborne aerosol samples collected from different altitudes and the warm cloud layers indicated distinct particle chemistry on the dry and wet days. The majority of the particles sampled were heterogeneous and internally mixed with two or more aerosol species indicating multiple sources and atmospheric aging, even during the wet days. Si-rich particles (up to 73%) were the dominant species in samples collected during dry days when the shallow clouds with narrow drop size distribution were observed. A higher concentration of Na-rich particles (up to 50%) was observed on wet days when the clouds were majorly multiple layers of stratus, which had broader cloud droplet spectra. Internally mixed carbonaceous and iron/cobalt-rich aerosols from local pollution sources were found on both wet and dry days suggesting boundary layer venting of aerosols. Large droplets were observed near the cloud base over the Western Ghats compared to those formed over the rain shadow region.
Similar content being viewed by others
Availability of data and material
The data are available on request from the website http://www.tropmet.res.in/~caipeex.
References
Beswick KM, Gallagher MW, Webb AR, Norton EG, Perry F (2008) Application of the Aventech AIMMS20AQ airborne probe for turbulence measurements during the Convective Storm Initiation Project. Atmos Chem Phys 8:5449–5463
Bisht DS, Srivastava AK, Pipal AS, Srivastava MK, Pandey AK, Tiwari S, Pandithurai G (2015) Aerosol characteristics at a rural station in southern peninsular India during CAIPEEX-IGOC: physical and chemical properties. Environ Sci Pollut Res 22:5293–5304. https://doi.org/10.1007/s11356-014-3836-1
Buseck PR, Pósfai M (1999) Airborne minerals and related aerosol particles: effects on climate and the environment. Proc Natl Acad Sci USA 96(7):3372–3379. https://doi.org/10.1073/pnas.96.7.3372
Buseck PR, Adachi K, Gelencsér A, Tompa É, Pósfai M (2014) Ns-Soot: a material-based term for strongly light-absorbing carbonaceous particles. Aerosol Sci Technol 48(7):777–788. https://doi.org/10.1080/02786826.2014.919374
Dave P, Bhushan M, Venkataraman C (2017) Aerosols cause intraseasonal short-term suppression of Indian monsoon rainfall. Sci Rep 7(1):17347. https://doi.org/10.1038/s41598-017-17599-1
Dipu S, Prabhakaran T, Pandithurai G, Dudhia J, Pfister G, Rajesh K, Goswami BN (2013) Impact of elevated aerosol layer on the cloud macrophysical properties prior to monsoon onset. Atmos Environ 70:454–467. https://doi.org/10.1016/j.atmosenv.2012.12.036
Freney EJ, Adachi K, Buseck PR (2010) Internally mixed atmospheric aerosol particles: hygroscopic growth and light scattering. J Geophys Res 115:D19210. https://doi.org/10.1029/2009JD013558
Gayatri K, Patade S, Prabha TV (2017) Aerosol–cloud interaction in deep convective clouds over the indian peninsula using spectral (Bin) microphysics. J Atmos Sci 74(10):3145–3166
Geng H, Kang S, Jung H-J, Choël M, Kim H, Ro C-U (2010) Characterization of individual submicrometer aerosol particles collected in Incheon, Korea, by quantitative transmission electron microscopy energy-dispersive X-ray spectrometry. J Geophys Res Atmos 115:D15. https://doi.org/10.1029/2009JD013486
George SK, Nair PR, Parameswaran K, Jacob S, Abraham A (2008) Seasonal trends in chemical composition of aerosols at a tropical coastal site of India. J Geophys Res 113:D16209. https://doi.org/10.1029/2007JD009507
Guo L, Turner AG, Highwood EJ (2016) Local and remote impacts of aerosol species on Indian summer monsoon rainfall in a GCM. J Clim 29(19):6937–6955. https://doi.org/10.1175/JCLI-D-15-0728.1
Hazra A, Goswami BN, Chen J-P (2013) Role of interactions between aerosol radiative effect, dynamics, and cloud microphysics on transitions of monsoon intraseasonal oscillations. J Atmos Sci 70:2073–2087. https://doi.org/10.1175/JAS-D-12-0179.1
Hegde P, Sarin MM, Sudheer AK, Manjunatha BR (2007) Characteristics of atmospheric aerosols over Mangalore region: southwest coast of India. Atmos Environ 41:7751–7766
Heymsfield AJ, Schmitt C, Bansemer A, Twohy CH (2010) Improved representation of ice particle masses based on observations in natural clouds. J Atmos Sci 67:3303–3318. https://doi.org/10.1175/2010JAS3507.1
Hwang H, Ro C-U (2006) Single-particle characterization of municipal solid waste (MSW) ash particles using low-Z particle electron probe X-ray microanalysis. Atmos Environ 40:2873–2881. https://doi.org/10.1016/j.atmosenv.2006.01.004
Jin Q, Yang Z-L, Wei J (2016) Seasonal responses of Indian summer monsoon to dust aerosols in the Middle East, India, and China. J Clim 29(17):6329–6349
Johnson KS, Zuberi B, Molina LT, Molina MJ, Iedema MJ, Cowin JP, Gaspar DJ, Wang C, Laskin A (2005) Processing of soot in an urban environment: case study from the Mexico City Metropolitan Area. Atmos Chem Phys 5:3033–3043. https://doi.org/10.5194/acp-5-3033-2005
Kim N, Park M, Soo S, Sung J, Jung H, Young J (2018) Impact of urban aerosol properties on cloud condensation nuclei (CCN) activity during the KORUS-AQ field campaign. Atmos Environ 185:221–236. https://doi.org/10.1016/j.atmosenv.2018.05.019
Konwar M, Maheshkumar RS, Kulkarni JR, Freud E, Goswami BN, Rosenfeld D (2012) Aerosol control on depth of warm rain in convective clouds. J Geophys Res Atmos 117:D13204. https://doi.org/10.1029/2012JD017585
Konwar M, Das SK, Deshpande SM, Chakravarty K, Goswami BN (2014) Microphysics of clouds and rain over the Western Ghat. J Geophys Res Atmos 119:6140–6159. https://doi.org/10.1002/2014JD021606
Kumar S, Bhat GS (2017) Vertical structure of orographic precipitating clouds observed over south Asia during summer monsoon season. J Earth Syst Sci 126:114. https://doi.org/10.1007/s12040-017-0897-9
Lance S, Brock CA, Rogers D, Gordon JA (2010) Water droplet calibration of the Cloud Droplet Probe (CDP) and in-flight performance in liquid, ice and mixed-phase clouds during ARCPAC. Atmos Meas Technol 3:1683–1706. https://doi.org/10.5194/amt-3-1683-2010
Lasher-Trapp SG, Cooper WA, Blyth AL (2005) Broadening of droplet size distributions from entrainment and mixing in a cumulus cloud. Q J Roy Meteorol Soc 131:195–220. https://doi.org/10.1256/qj.03.199
Laskin A, Cowin JP, Iedema MJ (2006) Analysis of individual environmental particles using modern methods of electron microscopy and X-ray microanalysis. J Electron Spectrosc Relat Phenom 150(2–3):260–274. https://doi.org/10.1016/j.elspec.2005.06.008
Laskin A, Moffet RC, Gilles MK, Fast JD, Zaveri RA, Wang B, Nigge P, Shutthanandan J (2012) Tropospheric chemistry of internally mixed sea salt and organic particles: Surprising reactivity of NaCl with weak organic acids. J Geophys Res Atmos 117:D15. https://doi.org/10.1029/2012JD017743
Lawson RP, Woods S, Morrison H (2015) The microphysics of ice and precipitation development in tropical cumulus clouds. J Atmos Sci 72:2429–2445
Leena PP, Anilkumar V, Sravanthi N, Patil R, Chakravarty K, Saha SK, Pandithurai G (2018) On the precipitation susceptibility of monsoon clouds to aerosols using high altitude ground-based observations over Western Ghats, India. Atmos Environ 185:128–136. https://doi.org/10.1016/j.atmosenv.2018.05.001
Li J, Anderson JR, Buseck PR (2003) TEM study of aerosol particles from clean and polluted marine boundary layers over the North Atlantic. J Geophys Res Atmos 108(D6):4189. https://doi.org/10.1029/2002JD002106
Li WJ, Zhang DZ, Shao LY, Zhou SZ, Wang WX (2011a) Individual particle analysis of aerosols collected under haze and non-haze conditions at a high-elevation mountain site in the North China plain. Atmos Chem Phys 11(22):11733–11744. https://doi.org/10.5194/acp-11-11733-2011
Li W, Shao L, Shen R, Yang S, Wang Z, Tang UW (2011b) Internally mixed sea salt, soot, and sulfates at Macao, a coastal city in South China. J Air Waste Manag Assoc 61:1166–1173. https://doi.org/10.1080/10473289.2011.603996
Kleinman LI, Daum PH, Lee Y-N, Lewis ER, Sedlacek III AJ, Senum GI, Springston SR, Wang J, Hubbe J, Jayne J, Min Q, Yum SS, Allen G (2012) Aerosol concentration and size distribution measured below, in, and above cloud from the DOE G-1 during VOCALS-REx. Atmos Chem Phys 12(1):207–223. https://doi.org/10.5194/acp-12-207-2012
Kulkarni JR, Maheshkumar RS, Morwal SB, Padmakumari B, Konwar M, Deshpande CG, Joshi RR, Bhalwankar RV, Pandithurai G, Safai PD, Narkhedkar SG, Dani KK, Nath A, Nair Sathy, Sapre VV, Puranik PV, Kandalgaonkar SS, Mujumdar VR, Khaladkar RM, Vijaykumar R, Prabha TV, Goswami BN (2012) Cloud Aerosol Interaction and Precipitation Enhancement Experiment (CAIPEEX): overview and preliminary results. Curr Sci 102:413–425
Liu PSK, Leaitch WR, Strapp JW, Wasey MA (1992) Response of particle measuring systems airborne ASASP and PCASP to NaCl and latex particles. Aerosol Sci Technol 16(2):83–95. https://doi.org/10.1080/02786829208959539
Ma N, Zhao C, Tao J, Wu Z, Kecorius S, Wang Z, Größ J, Liu H, Bian Y, Kuang Y, Teich M, Spindler G, Müller K, van Pinxteren D, Herrmann H, Hu M, Wiedensohler A (2016) Variation of CCN activity during new particle formation events in the North China Plain. Atmos Chem Phys 16:8593–8607. https://doi.org/10.5194/acp-16-8593-2016,2016
Maheskumar RS, Narkhedkar SG, Morwal SB, Padmakumari B, Kothawale DR, Joshi RR, Deshpande CG, Bhalwankar RV, Kulkarni JR (2014) Mechanism of high rainfall over the Indian west coast region during the monsoon season. Clim Dyn 43:1513–1529. https://doi.org/10.1007/s00382-013-1972-9
McFiggans G, Artaxo P, Baltensperger U, Coe H, Facchini MC, Feingold G, Fuzzi S, Gysel M, Laaksonen A, Lohmann U, Mentel TF, Murphy DM, O’Dowd CD, Snider JR, Weingartner E (2006) The effect of physical and chemical aerosol properties on warm cloud droplet activation. Atmos Chem Phys 6(9):2593–2649. https://doi.org/10.5194/acp-6-2593-2006
McMeeking GR, Bart M, Chazette P, Haywood JM, Hopkins JR, McQuaid JB, Morgan WT, Raut JC, Ryder CL, Savage N, Turnbull K, Coe H (2012) Airborne measurements of trace gases and aerosols over the London metropolitan region. Atmos Chem Phys 12(11):5163–5187. https://doi.org/10.5194/acp-12-5163-2012
Morwal SB, Narkhedkar SG, Padmakumari B, Maheskumar RS, Kulkarni JR (2018) Characteristics of precipitating monsoon clouds over rain-shadow and drought-hit regions of India using radar. Clim Dyn 50:3571–3594. https://doi.org/10.1007/s00382-017-3826-3
Nair PR, George SK, Sunilkumar SV, Parameswaran K, Jacob S, Abraham A (2006) Chemical composition of aerosols over peninsular India during winter. Atmos Environ 40(34):6477–6493. https://doi.org/10.1016/j.atmosenv.2006.02.031
Nair S, Resmi EA, Gayatri K, Malap N, Patade S, Prabha TV (2015) Thermodynamical and cloud microphysical response during the transition from southwest to northeast monsoon. Atmos Res 166:182–194. https://doi.org/10.1016/j.atmosres.2015.06.018
Nandargi S, Mulye SS (2012) Relationships between rainy days, mean daily intensity, and seasonal rainfall over the Koyna catchment during 1961–2005. Sci World J. https://doi.org/10.1100/2012/894313
Narkhedkar SG, Morwal SB, Padmakumari B, Deshpande CG, Kothawale DR, Maheskumar RS, Kulkarni JR (2015) Rainfall mechanism over the rain-shadow region of north peninsular India. Clim Dyn 45:1493–1512. https://doi.org/10.1007/s00382-014-2403-2
Niemi JV, Saarikoski S, Tervahattu H, Mäkelä T, Hillamo R, Vehkamäki H, Sogacheva L, Kulmala M (2006) Changes in background aerosol composition in Finland during polluted and clean periods studied by TEM/EDX individual particle analysis. Atmos Chem Phys 6(12):5049–5066. https://doi.org/10.5194/acp-6-5049-2006
Padmakumari B, Maheskumar RS, Harikishan G, Morwal SB, Prabha TV, Kulkarni JR (2013) In situ measurements of aerosol vertical and spatial distributions over continental India during the major drought year 2009. Atmos Res 80:107–121
Padmakumari B, Maheskumar RS, Anand V, Axisa D (2017) Microphysical characteristics of convective clouds over ocean and land from aircraft observations. Atmos Res 195:62–71. https://doi.org/10.1016/j.atmosres.2017.05.011
Padmakumari B, Maheskumar RS, Harikrishnan G, Morwal SB, Kulkarni JR (2018) Rain-shadow: an area harbouring “Grey Ocean’’’ clouds.” Atmos Res 205:70–79. https://doi.org/10.1016/j.atmosres.2018.02.005
Patade S, Shete S, Malap N, Gayatri K, Prabha TV (2016) Observational and simulated cloud microphysical features of rain formation in the mixed phase clouds observed during CAIPEEX. Atmos Res 169(A):32–45: https://doi.org/10.1016/j.atmosres.2015.09.018
Pósfai M, Simonics R, Li J, Hobbs PV, Buseck PR (2003) Individual aerosol particles from biomass burning in southern Africa: 1. Compositions and size distributions of carbonaceous particles. J Geophys Res Atmos 108(D13):8483. https://doi.org/10.1029/2002JD002291
Prabha TV, Khain A, Maheshkumar RS, Pandithurai G, Kulkarni JR, Konwar M, Goswami BN (2011) Microphysics of premonsoon and monsoon clouds as seen from in situ measurements during CAIPEEX. J Atmos Sci 68:1882–1901
Rangno AL, Hobbs PV (2005) Microstructures and precipitation development in cumulus and small cumulonimbus clouds over the warm pool of the tropical Pacific Ocean. Q J Roy Meteorol Soc 131:639–673
Roberts GC, Nenes A (2005) A continuous-flow streamwise thermal-gradient CCN chamber for atmospheric measurements. Aerosol Sci Technol 39(3):206–221. https://doi.org/10.1080/027868290913988
Roldin P, Ehn M, Kurtén T, Olenius T, Rissanen MP, Sarnela N, Elm J, Rantala P, Hao L, Hyttinen N, Heikkinen L, Worsnop DR, Pichelstorfer L, Xavier C, Clusius P, Öström E, Petäjä T, Kulmala M, Vehkamäki H, Virtanen A, Riipinen I, Boy M (2019) The role of highly oxygenated organic molecules in the Boreal aerosol-cloud-climate system. Nat Commun 10:4370. https://doi.org/10.1038/s41467-019-12338-8
Sanap SD, Pandithurai G (2015) The effect of absorbing aerosols on Indian monsoon circulation and rainfall: a review. Atmos Res 164–165:318–327. https://doi.org/10.1016/j.atmosres.2015.06.002
Satheesh SK, Krishna Moorthy K (1997) Aerosol characteristics over coastal regions of the Arabian Sea. Tellus B Chem Phys Meteorol 49B:417–428. https://doi.org/10.3402/tellusb.v49i4.15979
Scarnato S, China KN, Mazzoleni C (2015) Perturbations of the optical properties of mineral dust particles by mixing with black carbon: a numerical simulation study. Atmos Chem Phys 15(12):6913–6928. https://doi.org/10.5194/acp-15-6913-2015
Simelane PS, Delene D, Ahlness H, Langerud D (2013) Evaluation of pilot estimated updrafts using aircraft integrated meteorological measurement system (AIMMS) measurements. J Weather Modif 45(1):63–71
Smith S, Ward M, Lin R, Brydson R, Dall’Osto M, Harrison RM (2012) Comparative study of single particle characterisation by Transmission Electron Microscopy and time-of-flight aerosol mass spectrometry in the London atmosphere. Atmos Environ 62:400–407. https://doi.org/10.1016/j.atmosenv.2012.08.028
Spracklen DV, Bonn B, Carslaw KS (2008) Boreal forests, aerosols and the impacts on clouds and climate. Philos Trans Roy Soc A 366:4613–4626. https://doi.org/10.1098/rsta.2008.0201
Stein AF, Draxler RR, Rolph GD, Stunder BJB, Cohen MD, Ngan F (2015) NOAA’s HYSPLIT atmospheric transport and dispersion modeling system. Bull Am Meteorol Soc 96:2059–2077. https://doi.org/10.1175/BAMS-D-14-00110.1
Unga F, Choël M, Derimian Y, Deboudt K, Dubovik O, Goloub P (2018) Microscopic observations of core-shell particle structure and implications for atmospheric aerosol remote sensing. J Geophys Res Atmos 123(24):13944–13962. https://doi.org/10.1029/2018JD028602
Varghese M, Prabha TV, Malap N, Resmi EA, Murugavel P, Safai PD, Axisa D, Pandithurai G, Dani K (2016) Airborne and ground based CCN spectral characteristics: Inferences from CAIPEEX–2011. Atmos Environ 125:324–336. https://doi.org/10.1016/j.atmosenv.2015.06.041
Varghese M, Prabha TV, Murugavel P, Anu AS, Resmi EA, Dinesh G, Jaya Rao Y, Nagare B, Safai PD, Nair S, Nandakumar K, Vishnu R, Bhavani Kumar Y (2019) Aerosol and cloud droplet characteristics over Ganges Valley during break phase of monsoon: a case study. Atmos Res 220:125–140. https://doi.org/10.1016/j.atmosres.2019.01.013
Varghese M, Leena PP, Murugavel P, Bankar S, Todekar K, Chowdhuri S, Safai PD, Malap N, Konwar M, DixitS JR, Y, Prabha TV, (2020) New particle formation observed from a rain shadow region of the Western Ghats, India. Toxicol Environ Chem 102(7–8):305–333. https://doi.org/10.1080/02772248.2020.1789134
Varghese M, Prabha TV, Patade S, Gayatri K, Safai PD, Axisa D (2021) Characteristics of CCN activation and cloud microphysics over the east coast of India during the Northeast Monsoon onset. Atmos Res 257(9):105589. https://doi.org/10.1016/j.atmosres.2021.105589
Varmaraja MKR, Asnani GC, Salvelkar PS, Jain AR, Rao DN, Rao SV, Kishore P, Hareesh M (1999) Layered clouds in the Indian monsoon region. Proc Ind Acad Sci Earth Planet Sci 108:287–295. https://doi.org/10.1007/BF02840506
Yang L, Mukherjee S, Pandithurai G, Waghmare V, Safai PD (2019) Influence of dust and sea-salt sandwich effect on precipitation chemistry over the Western Ghats during summer monsoon. Sci Rep 9:19171. https://doi.org/10.1038/s41598-019-55245-0
Yu H, Li W, Zhang Y, Tunved P, Dall’Osto M, Shen X, Sun J, Zhang X, Zhang J, Shi Z (2019) Organic coating on sulfate and soot particles during late summer in the Svalbard Archipelago. Atmos Chem Phys 19:10433–10446. https://doi.org/10.5194/acp-19-10433-2019
Zhang Q, Quan J, Tie X, Huang M, Ma X (2011) Impact of aerosol particles on cloud formation: aircraft measurements in China. Atmos Environ 45(3):665–672. https://doi.org/10.1016/j.atmosenv.2010.10.025
Zhang YM, Zhang XY, Sun JY, Hu GY, Shen XJ, Wang YQ, Wang TT, Wang DZ, Zhao Y (2014) Chemical composition and mass size distribution of PM1 at an elevated site in central east China. Atmos Chem Phys 14(22):12237–12249. https://doi.org/10.5194/acp-14-12237-2014
Zhang F, Ren J, Fan T, Chen L, Xu W, Sun Y, Zhang R, Liu J, Jiang S, Jin X, Wu H, Li S, Cribb MC, Li Z (2019) Significantly enhanced aerosol CCN activity and number concentrations by nucleation initiated haze events: a case study in urban Beijing. J Geophys Res Atmos 124:14102–14113. https://doi.org/10.1029/2019JD031457
Zhou S, Yuan Q, Li W, Lu Y, Zhang Y, Wang W (2014) Trace metals in atmospheric fine particles in one industrial urban city: spatial variations, sources, and health implications. J Environ Sci 26(1):205–213. https://doi.org/10.1016/S1001-0742(13)60399-X
Zuberi B, Johnson KS, Aleks GK, Molina LT, Molina MJ, Laskin A (2005) Hydrophilic properties of aged soot. Geophys Res Lett 32(1):L01807. https://doi.org/10.1029/2004GL021496
Acknowledgements
The Ministry of Earth Sciences (MoES) fully funds the CAIPEEX program and the Indian Institute of Tropical Meteorology (IITM), Govt. of India. The filter sampling was designed and fabricated at IITM and was implemented for aircraft sampling. The authors are grateful to all the CAIPEEX aircraft and ground team for helping with the data collection. The authors from Mahatma Gandhi University (MGU) acknowledge the financial support from Department of Science and Technology (DST), Govt. of India for funding through FIST & PURSE and SAIF schemes and University Grants Commission (UGC), Govt. of India through the SAP-DRS program. The authors are thankful to DST-Nano Mission and MGU for funding the characterization facilities. The authors from MGU gratefully acknowledge IITM for scientific guidance, technical expertise, and financial support for this study. The MERRA-2 model data for dust loading was plotted using the online GIOVANNI platform (https://giovanni.gsfc.nasa.gov/giovanni/) provided by NASA. Back trajectory analysis was produced using the online version of the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT4) model (http://www.arl.noaa.gov/ready/hysplit4.html). The ERA5 reanalysis data used in this study was freely downloaded from https://cds.climate.copernicus.eu/cdsapp#!/home. Authors MV and JJ acknowledge Sathy Nair for preparing the meteorological briefings from the daily weather reports of IMD.
Funding
The Ministry of Earth Sciences, Govt. of India fully funds the CAIPEEX program and IITM. The HR-TEM and EDS facility of the International and Inter University Centre for Nanoscience and Nanotechnology (IIUCNN), MGU, was funded by the Department of Science and Technology (DST) Nano Mission for the project titled 'Development of Engineered Nanostructured Materials for High-Performance Applications' order No. SR/NM/NS-54/2009, 2708.2010 and 14.07.2011.
Author information
Authors and Affiliations
Contributions
Authors TVP and MV designed the study. PM designed the filter sampling system used in this study. MK, SB, TVP, PM, REA, MV made the aircraft observations used in this study. AAS and JJ performed the single-particle analysis using HR-TEM and EDS under the guidance of NK and ST. MV and JJ did the different analyses and prepared the manuscript. Authors TVP, ST, NK, MK, and SB reviewed the manuscript. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have influenced the work reported in this paper.
Additional information
Responsible Editor: Sang-Woo Kim.
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Varghese, M., Jose, J., Anu, A.S. et al. Cloud and aerosol characteristics during dry and wet days of southwest monsoon over the rain shadow region of Western Ghats, India. Meteorol Atmos Phys 133, 1299–1316 (2021). https://doi.org/10.1007/s00703-021-00811-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00703-021-00811-3