Annulation reactions of pyridine-2-sulfenyl chloride with phenyl vinyl chalcogenides and allyl phenyl chalcogenides proceeded regioselectively, but with different regiochemical outcomes and led to the formation of new 2- and 3-substituted [1,3]thiazolo[3,2-a]-pyridinium derivatives in 90–100% yields.
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Spectral characterization was performed using the equipment at the Baikal Collective Use Analytical Center of the Siberian Branch of the Russian Academy of Sciences.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2020, 56(9), 1226–1229
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Potapov, V.A., Ishigeev, R.S., Shkurchenko, I.V. et al. Different regiochemical outcomes in annulation reactions of pyridine-2-sulfenyl chloride with phenyl vinyl chalcogenides and allyl phenyl chalcogenides. Chem Heterocycl Comp 56, 1226–1229 (2020). https://doi.org/10.1007/s10593-020-02803-4
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DOI: https://doi.org/10.1007/s10593-020-02803-4