Abstract
The properties of oxide films on mild steel formed anodically in aqueous solution containing oxalic acid were investigated by means of electrochemical impedance spectroscopy (EIS). The morphology of the passive layers at different stages of film formation was investigated using scanning electron microscopy (SEM). Passivation of mild steel in oxalic acid solution is a multi-stage process that occurs before passive layer breakdown. The influence of potential on the electrochemical behavior of the passive layer was also investigated. Depending on the passive layer potential, the EIS spectra obtained exhibited a one- or two-time constant system. This suggests the formation of either a one layer or two layer oxide film on the mild steel surface, depending on the passivation potential.
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Ahmad N, Macdiarmid AG (1996) Synth Met 78:103
Su W, Iroh JO (1997) J Appl Polym Sci 65:417
Schirmeisen M, Beck F (1989) J Appl Electrochem 19:401
Sazou D, Georgoios C (1997) J Electroanal Chem 429:81
Su W, Iroh JO (1997) J Appl Polym Sci 65:617
Ashrafi A, Golozar MA, Mallakpour S (2003) Iran Polym J 12:485
Martyak NM, MeAndrew P, McCaskie JE, Dijon J (2002) Prog Org Coat 45:23
Su W, Iroh JO (1999) Electrochim Acta 44:3321
Su W, Iroh JO (1999) Electrochim Acta 44:4655
Camalet JL, Lacroix JC, Aeiyach S, Chane-Ching K, Lacaze PC (1996) J Electroanal Chem 416:179
Guo XP, Imaizumi H, Katoh K (1995) J Electroanal Chem 383:99
Guo XP, Tomoe Y, Imaizumi H, Katoh K (1998) J Electroanal Chem 445:95
Klyuev AL, Rotenberg ZA, Batrakov VV (2005) Russ J Electrochem 41:87
Hamadov L, Kadri A, Benbrahim W (2005) Appl Surf Sci 252:1510
Saltykov SN, Makarov GV, Toroptseva EL, Filatova YB (2004) Prot Met 40:56
Saltykov SN, Makarov GV, Toroptseva EL (2002) Prot Met 37:163
Mansfeld F, Kendig MW (1985) J Electrochem Soc 132:290
Acknowledgements
The authors thank the Vice Chancellor for Research and Center of Graduate Studies, Isfahan University of Technology for financial support. Editing of the manuscript by Mrs Chris Abachi and Mr Gaetano Giglione is greatly appreciated.
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Ashrafi, A., Golozar, M.A. & Mallakpour, S. EIS investigation of passive film formation on mild steel in oxalic acid solution. J Appl Electrochem 38, 225–229 (2008). https://doi.org/10.1007/s10800-007-9429-7
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DOI: https://doi.org/10.1007/s10800-007-9429-7