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Synthesis and characterization of a new liquid polymer precursor for Si–B–C–N ceramics

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Abstract

A new liquid polyborosilazane precursor for Si–B–C–N ceramic was synthesized by co-condensation reaction of boron trichloride, organodichlorosilanes, and hexamethyldisilazane. The structure and properties of polyborosilazane were studied by means of Fourier transform-infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), rheology, and thermogravimetric analysis (TGA). The conversion of polymer to ceramic and the high-temperature behavior of the new polymer-derived ceramic were investigated by TG–MS, FT-IR, X-ray diffraction (XRD) and high-temperature TGA (HTGA). The ceramics showed good oxidative resistance and thermal stability with weight gain of 1.8 wt% at 1350 °C under air atmosphere and weight loss of 2.6% at 1900 °C under Ar atmosphere.

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Acknowledgement

The authors would thank the National Science Foundation of China (NSFC, No. 50973113) for financial support.

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Authors and Affiliations

  1. Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 10090, People’s Republic of China

    Zongbo Zhang, Fan Zeng, Juanjuan Han, Yongming Luo & Caihong Xu

  2. Graduate University of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Zongbo Zhang

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  1. Zongbo Zhang
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  2. Fan Zeng
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  3. Juanjuan Han
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  4. Yongming Luo
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  5. Caihong Xu
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Correspondence to Yongming Luo or Caihong Xu.

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Zhang, Z., Zeng, F., Han, J. et al. Synthesis and characterization of a new liquid polymer precursor for Si–B–C–N ceramics. J Mater Sci 46, 5940–5947 (2011). https://doi.org/10.1007/s10853-011-5549-x

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  • DOI: https://doi.org/10.1007/s10853-011-5549-x

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