Abstract
Control and optimization of curing process is very important for the production of high quality composite parts. Crosslinking of molecules of thermoset resin occurs in this phase, which involves exothermy of reaction, chemical shrinkage (Sh) and development of thermo-physical and thermo-mechanical properties. Exact knowledge of the evolution of all these parameters is required for the better understanding and improvement of the fabrication process. Sh is one such property of thermoset matrix, which is difficult to characterize due to its coupling with thermal expansion/contraction. A number of techniques have been used to determine volume Sh of thermoset matrix, which later on has been used to find tensor of Sh for the simulation of residual stresses and shape distortion of composite part, etc. Direct characterization of volume Sh of composites has also been made by some authors. Though not much, but some work has also been reported to determine the Sh of composite part in a specific direction. In this article, all the techniques used in the literature for the characterization of Sh of resin and composite are reported briefly with their respective advantages, disadvantage and important results.
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Abou Msallem Y, Jacquemin F, Boyard N, Poitou A, Delaunay D, Chatel S (2010) Compos Part A 41(1):108. doi:10.1016/j.compositesa.2009.09.025
Shimbo M, Yamabe M, Miyano Y (1998) Viscoelastic analysis of residual stress in thermosetting resins introduced during curing process. In: Allison IM (ed) 11th International conference on experimental mechanics, Oxford, p 1325
Hodges J, Yates B, Darby MI, Wostenholm GH, Clemmet JF, Keates TF (1989) J Mater Sci 24(6):1984. doi:10.1007/bf02385410
Lingois P, Berglund L, Greco A, Maffezoli A (2003) J Mater Sci 38(6):1321. doi:10.1023/a:1022811315807
Bogetti TA, Gillespie JW (1992) J Compos Mater 26(5):626. doi:10.1177/002199839202600502
Harris B (1978) J Mater Sci 13(1):173. doi:10.1007/bf00739288
Kim KS, Hahn HT (1989) Compos Sci Technol 36(2):121. doi:10.1016/0266-3538(89)90083-3
White SR, Kim YK (1998) Mech Compos Mater Struct 5(2):153. doi:10.1080/10759419808945897
Hahn HT, Pagano NJ (1975) J Compos Mater 9(1):91. doi:10.1177/002199837500900110
Lee S, Schile R (1982) J Mater Sci 17(7):2095. doi:10.1007/bf00540428
Wisnom MR, Gigliotti M, Ersoy N, Campbell M, Potter KD (2006) Compos Part A 37(4):522
Yoon KJ, Kim J-S (2001) J Compos Mater 35(3):253. doi:10.1177/002199801772662244
Dano M-L, Hyer MW (1998) Int J Solids Struct 35(17):2101. doi:10.1016/s0020-7683(97)00167-4
Nawab Y, Jaquemin F, Casari P, Boyard N, Sobotka V (2013) J Compos Mater 47(3):327. doi:10.1177/0021998312440130
Chekanov YA, Korotkov VN, Rozenberg BA, Dhzavadyan EA, Bogdanova LM (1995) Polymer 36(10):2013. doi:10.1016/0032-3861(95)91446-E
Eom Y, Boogh L, Michaud V, Sunderland P, Månson JA (2004) Polym Eng Sci 41(3):492
ASTM (2012) Standard test method for linear shrinkage of cured thermosettings casting resins during cure. ASTM D2566–79
Starkweather HW, Taylor GB (1930) J Am Chem Soc 52(12):4708. doi:10.1021/ja01375a011
Li C, Potter K, Wisnom MR, Stringer G (2004) Compos Sci Technol 64(1):55
Zhang J, Xu YC, Huang P (2009) Express Polym Lett 3(9):534
Madhukar MS, Genidy MS, Russell JD (2000) J Compos Mater 34(22):1882. doi:10.1106/hucy-dy2b-2n42-ujbx
Boyard N, Millischer A, Sobotka V, Bailleul JL, Delaunay D (2007) Compos Sci Technol 67(6):943. doi:10.1016/j.compscitech.2006.07.004
Li W, Lee LJ (1998) Polymer 39(23):5677. doi:10.1016/S0032-3861(98)00074-3
Nawab Y, Tardif X, Boyard N, Sobotka V, Casari P, Jacquemin F (2012) Compos Sci Technol 73:81. doi:10.1016/j.compscitech.2012.09.018
Pingsheng H, Zhiqiang Z, Caiyuan P, Renjie W (1989) J Mater Sci 24(5):1528. doi:10.1007/BF01105666
Yates B, McCalla BA (1979) J Mater Sci 14:1207. doi:10.1007/BF00561306
Snow AW, Armistead JP (1991) Dilatometry on thermoset resins. Naval Research Laboratory, Washington, DC
Huang Y-J, Liang C-M (1996) Polymer 37(3):401. doi:10.1016/0032-3861(96)82909-0
Parlevliet PP, Bersee HEN, Beukers A (2010) Polym Test 29(4):433
Khoun L, Hubert P (2010) Polym Compos 31(9):1603. doi:10.1002/pc.20949
Russell JD, Madhukar MS, Genidy MS, Lee AY (2000) J Compos Mater 34(22):1926. doi:10.1106/uy9u-f2qw-2fkk-91kg
Zoller P, Bolli P, Pahud V, Ackermann H (1976) RevSciInstrum 47(8):948
Li W, Lee LJ (2000) Polymer 41(2):685
Ramos JA, Pagani N, Riccardi CC, Borrajo J, Goyanes SN, Mondragon I (2005) Polymer 46(10):3323
Kinkelaar M, Muzumdar S, Lee LJ (1995) Polym Eng Sci 35(10):823
Hwang SJ, Chang YS (2005) J Polym Sci Part B 43(17):2392. doi:10.1002/polb.20540
Kinkelaar M, Lee LJ (1992) J Appl Polym Sci 45(1):37
Kinkelaar M, Wang B, Lee LJ (1994) Polymer 35(14):3011
Saraswat MK, Jansen KMB, Ernst LJ (2006) CORD Conf Proc 2:782. doi:10.1109/estc.2006.280100
Nawab Y, Boyard N, Sobotka V, Casari P, Jacquemin F (2011) Adv Mater Res 326:19
Millischer A (2000) Transferts thermiques dans le procede d’injection BMC (Bulk Molding Compound). Université de Nantes, Nantes
Boyard N, Vayer M, Sinturel C, Erre R, Delaunay D (2004) J Appl Polym Sci 92(5):2976. doi:10.1002/app.20312
Massé H, Arquis É, Delaunay D, Quilliet S, Le Bot PH (2004) Int J Heat Mass Transf 47(8–9):2015
Nawab Y, Casari P, Boyard N, Jacquemin F (2013) J Mater Sci 48(6):2394. doi:10.1007/s10853-012-7026-6
Aduriz X, Lupi C, Boyard N, Bailleul JL, Leduc D, Sobotka V, Lefèvre N, Chapeleau X, Boisrobert C, Delaunay D (2007) Compos Sci Technol 67(15):3196
Bucknall CB, Partridge IK, Phillips MJ (1991) Polymer 32(4):636. doi:10.1016/0032-3861(91)90475-X
Ochi M, Yamashita K, Shimbo M (1991) J Appl Polym Sci 43(11):2013. doi:10.1002/app.1991.070431108
Magniez K, Vijayan A, Finn N (2012) Polym Eng Sci 52(2):346. doi:10.1002/pen.22088
Stone MA, Fink BK, Bogetti TA, Gillespie JW (2000) Polym Eng Sci 40(12):2489
Flores F, Gillespie JW, Bogetti TA (2002) Polym Eng Sci 42(3):582
Lange J, Toll S, Månson J-AE, Hult A (1995) Polymer 36(16):3135
Schoch KF, Panackal PA, Frank PP (2004) Thermochim Acta 417(1):115
Ruiz E, Trochu F (2005) J Compos Mater 39(10):881
Tai HJ, Chou HL (2000) Eur Polym J 36:2213
Brauner C, Block TB, Purol H, Herrmann AS (2012) J Compos Mater 46(17):2123
Hong Y, Subodh GM, Ee Hua W (2005) Macromol Rapid Commun 26(18):1483
Zarrelli M, Partridge IK, D’Amore A (2006) Compos Part A 37(4):565
Zarrelli M, Skordos AA, Partridge IK (2002) Plast Rubber Compos 31:377
Yu H, Mhaisalkar SG, Wong EH (2005) J Electron Mater 34(8):1177. doi:10.1007/s11664-005-0248-5
Haider M, Hubert P, Lessard L (2007) Compos Part A 38(3):994
Shah DU, Schubel PJ (2010) Polym Test 29(6):629
Khoun L, Centea T, Hubert P (2010) J Compos Mater 44(11):1397. doi:10.1177/0021998309353960
Cook WD, Forrest M, Goodwin AA (1999) Dent Mater 15(6):447
Shimbo M, Ochi M, Shigeta Y (1981) J Appl Polym Sci 26(7):2265. doi:10.1002/app.1981.070260714
Hoa SV, Ouellette P, Ngo TD (2009) J Compos Mater 43(7):783. doi:10.1177/0021998308102035
Parlevliet PP, Bersee HEN, Beukers A (2010) Polym Test 29(3):291
Antonucci V, Giordano M, Cusano A, Nasser J, Nicolais L (2006) Compos Sci Technol 66(16):3273. doi:10.1016/j.compscitech.2005.07.009
Karalekas D, Cugnoni J, Botsis J (2008) Compos Part A 39(7):1118. doi:10.1016/j.compositesa.2008.04.010
Giordano M, Laudati A, Nasser J, Nicolais L, Cusano A, Cutolo A (2004) Sens Actuators A 113(2):166. doi:10.1016/j.sna.2004.02.033
Vacher S, Molimard J, Gagnaire H, Vautrin A (2003) Polym Polym Compos 12(4):269
Wang Y, Han B, Kim DW, Bar Cohen A, Joseph P (2008) Exp Mech 48(1):107. doi:10.1007/s11340-007-9067-3
Harsch M, Karger-Kocsis J, Herzog F (2007) Polym Lett 1(4):226
Wang Y, Woodworth L, Han B (2011) Exp Mech 51(7):1155. doi:10.1007/s11340-010-9410-y
Othonos A, Kalli K (1999) Fiber Bragg gratings: fundamentals and applications in telecommunications and sensing. Artech House, Norwood
Thomas CL, Bur AJ (1999) Polym Eng Sci 39(9):1619
Fano V, Ortalli I, Pizzi S, Bonanini M (1997) Biomaterials 18(6):467
Ochi M, Yamashita K, Shimbo M (2003) J Appl Polym Sci 43(11):2013
Plepys A, Farris R (1990) Polymer 31(10):1932
Sun J, Eidelman N, Lin-Gibson S (2009) Dent Mater 25(3):314
Sharp LJ, Choi IB, Lee TE, Sy A, Suh BI (2003) J Dent 31(2):97
Russell J (1993) SAMPE Q 24(2):28
Sadeghinia M, Jansen KMB, Ernst LJ (2012) Int J Adhesion Adhesives 32:82. doi:10.1016/j.ijadhadh.2011.10.007
Millischer A, Delaunay D (2001) J Reinf Plast Compos 20(6):495
Prasatya P, McKenna GB, Simon SL (2001) J Compos Mater 35(10):826. doi:10.1177/002199801772662424
Holst M, Schänzlin K, Wenzel M, Xu J, Lellinger D, Alig I (2005) J Polym Sci Part B 43(17):2314
White S, Hahn H (1992) J Compos Mater 26(16):2423
Daniel IM, Wang T-M, Karalekas D, Gotro JT (1990) J Compos Technol Res 12(3):172
Hu G, Luan J-E, Chew S (2009) J Electron Packag 131(1):14466
Zhu WH, Guang L, Wei S, Che FX, Sun A, Wang CK, Tan HB, Zhao BZ, Chin NH (2007) Thermal, mechanical and multi-physics simulation experiments in microelectronics and micro-systems, 2007. EuroSime 2007. International Conference on, 16–18 April 2007, p 1
Ken O, Masumi S (2001) Polym Eng Sci 41(8):1373
Crasto AS, Kim RY, Russell JD (2002) Polym Compos 23(3):454
Sakaguchi RL, Versluis A, Douglas WH (1997) Dent Mater 13(4):233. doi:10.1016/s0109-5641(97)80034-6
Kim YK (2004) J Compos Mater 38(11):959
Murukeshan V, Chan P, Ong L, Seah L (2000) Sens Actuators A 79(2):153
Kalamkarov A, Fitzgerald S, MacDonald D (1999) Compos B Eng 30(2):167
Lawrence CM, Nelson DV, Bennett TE, Spingarn JR (1997) SPIE, p 154
Mulle M, Collombet F, Olivier P, Zitoune R, Huchette C, Laurin F, Grunevald YH (2009) Compos Part A 40(10):1534
Leng JS, Asundi A (2002) Smart Mater Struct 11:249
Olivier PA (2006) Compos Part A 37(4):602
Ersoy N, Tugutlu M (2009) Polym Eng Sci 50(1):84
Garstka T, Ersoy N, Potter K, Wisnom M (2007) Compos Part A 38(12):2517
Ifju PG, Kilday BC, Niu X, Liu S-C (1999) J Compos Mater 33(16):1511. doi:10.1177/002199839903301603
Ifju P, Niu X, Kilday B, Liu S, Ettinger S (2000) Exp Mech 40(1):22
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Nawab, Y., Shahid, S., Boyard, N. et al. Chemical shrinkage characterization techniques for thermoset resins and associated composites. J Mater Sci 48, 5387–5409 (2013). https://doi.org/10.1007/s10853-013-7333-6
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DOI: https://doi.org/10.1007/s10853-013-7333-6