Abstract
Copper (Cu) has high electrical conductivity and is widely used for many industrial applications. However, pure Cu is very soft and improving the mechanical properties of Cu comes at the great expense of electrical and thermal conductivity. In this work, high-performance Cu with superior mechanical properties and reasonable electrical/thermal conductivity was fabricated using a scalable two-step method. First, Cu micro-powders with uniformly dispersed tungsten carbide (WC) nanoparticles were created by a molten salt-assisted self-incorporation process. A bulk nanocomposite was then obtained by melting the powders under pressure. The as-solidified Cu with 40 vol% uniformly dispersed WC nanoparticles exhibits high hardness, a yield strength over 1000 MPa, a Young’s modulus of over 250 GPa, and reasonable electrical and thermal conductivity.
Similar content being viewed by others
References
Murashkin MY, Sabirov I, Sauvage X, Valiev RZ (2016) Nanostructured Al and Cu alloys with superior strength and electrical conductivity. J Mater Sci 51:33–49. https://doi.org/10.1007/s10853-015-9354-9
Wang YA, Li JX, Yan Y, Qiao LJ (2012) Effect of electrical current on tribological behavior of copper-impregnated metallized carbon against a Cu–Cr–Zr alloy. Tribol Int 50:26–34
Zawrah MF, Zayed HA, Essawy RA, Nassar AH, Taha MA (2013) Preparation by mechanical alloying, characterization and sintering of Cu–20 wt% Al2O3 nanocomposites. Mater Des 46:485–490
Watanabe H, Kunimine T, Watanabe C, Monzen R, Todaka Y (2018) Tensile deformation characteristics of a Cu–Ni–Si alloy containing trace elements processed by high-pressure torsion with subsequent aging. Mater Sci Eng A 730:10–15
Copper Facts. https://www.copper.org/education/c-facts/. Accessed 6 Mar 2018
Ma J, Huang F, Huang L, Geng Z, Ning H, Han Z (2002) Trends and development of copper alloys for lead frame. J Funct Mater 33:1–4
Ledbetter HM, Naimon ER (1974) Elastic properties of metals and alloys. II. Copper. J Phys Chem Ref Data 3:897–935
Bhaskar MS, Abinandanan TA (2018) Effect of different solute diffusivities on precipitate coarsening in ternary alloys. Comput Mater Sci 146:73–83
Chen X, Jiang F, Jiang J, Xu P, Tong M, Tang Z (2018) Precipitation, recrystallization, and evolution of annealing twins in a Cu–Cr–Zr alloy. Metals 8:227
Fang DR, Tian YZ, Duan QQ, Wu SD, Zhang ZF, Zhao NQ, Li JJ (2011) Effects of equal channel angular pressing on the strength and toughness of Al–Cu alloys. J Mater Sci 46:5002–5008. https://doi.org/10.1007/s10853-011-5419-6
Shaarbaf M, Toroghinejad MR (2008) Nano-grained copper strip produced by accumulative roll bonding process. Mater Sci Eng A 473:28–33
Lu L, Shen Y, Chen X, Qian L, Lu K (2004) Ultrahigh strength and high electrical conductivity in copper. Science 304:422–426
Ellis DL, Michal GM, Orth NW (1990) Production and processing of Cu–Cr–Nb alloys. Scr Metall Mater 24:885–890
Kim JH, Yun JH, Park YH, Cho KM, Choi ID, Park IM (2007) Manufacturing of Cu–TiB2 composites by turbulent in situ mixing process. Mater Sci Eng A 449–451:1018–1021
Chen L-Y, Xu J-Q, Choi H, Pozuelo M, Ma X, Bhowmick S, Yang J-M, Mathaudhu S, Li X-C (2015) Processing and properties of magnesium containing a dense uniform dispersion of nanoparticles. Nature 528:539–543
Pierson HO (1996) Handbook of refractory carbides and nitrides: properties, characteristics, processing and apps. William Andrew, Norwich
Eustathopoulos N, Nicholas MG, Drevet B (1999) Wettability at high temperatures. Elsevier, Amsterdam
Ichikawa K, Achikita M (1993) Electric conductivity and mechanical properties of carbide dispersion-strengthened copper prepared by compocasting. Mater Trans JIM 34:718–724
Yang Y, Lan J, Li X (2004) Study on bulk aluminum matrix nano-composite fabricated by ultrasonic dispersion of nano-sized SiC particles in molten aluminum alloy. Mater Sci Eng A 380:378–383
Stobrawa JP, Rdzawski ZM (2009) Characterisation of nanostructured copper–WC materials. J Achiev Mater Manuf Eng 32:171–178
Akbulut H, Hatipoglu G, Algul H, Tokur M, Kartal M, Uysal M, Cetinkaya T (2015) Co-deposition of Cu/WC/graphene hybrid nanocomposites produced by electrophoretic deposition. Surf Coat Technol 284:344–352
Gu D, Shen Y (2007) Influence of reinforcement weight fraction on microstructure and properties of submicron WC–Co p/Cu bulk MMCs prepared by direct laser sintering. J Alloys Compd 431:112–120
Ma C, Zhao J, Cao C, Lin T-C, Li X (2016) Fundamental study on laser interactions with nanoparticles-reinforced metals—part I: effect of nanoparticles on optical reflectivity, specific heat, and thermal conductivity. J Manuf Sci Eng 138:121001–121007
Xu J, Chen L, Choi H, Konish H, Li X (2013) Assembly of metals and nanoparticles into novel nanocomposite superstructures. Sci Rep 3:1730
Liu W, Cao C, Xu J, Wang X, Li X (2016) Molten salt assisted solidification nanoprocessing of Al–TiC nanocomposites. Mater Lett 185:392–395
Ma C, Zhao J, Cao C, Lin T-C, Li X (2016) Fundamental study on laser interactions with nanoparticles-reinforced metals—part II: effect of nanoparticles on surface tension, viscosity, and laser melting. J Manuf Sci Eng 138:121002–121006
Yao GC, Mei QS, Li JY, Li CL, Ma Y, Chen F, Liu M (2016) Cu/C composites with a good combination of hardness and electrical conductivity fabricated from Cu and graphite by accumulative roll-bonding. Mater Des 110:124–129
Cao G, Choi H, Konishi H, Kou S, Lakes R, Li X (2008) Mg–6Zn/1.5%SiC nanocomposites fabricated by ultrasonic cavitation-based solidification processing. J Mater Sci 43:5521. https://doi.org/10.1007/s10853-008-2785-9
Davis JR (2001) Copper and copper alloys. ASM International, New York
Mills KC, Su YC (2006) Review of surface tension data for metallic elements and alloys: part 1—pure metals. Int Mater Rev 51:329–351
Xu JQ, Chen LY, Choi H, Li XC (2012) Theoretical study and pathways for nanoparticle capture during solidification of metal melt. J Phys Condens Matter 24:255304
Israelachvili JN (2011) Intermolecular and surface forces. Academic Press, Burlington
Zhou D, Wang X, Zeng W, Yang C, Pan H, Li C, Liu Y, Zhang D (2018) Doping Ti to achieve microstructural refinement and strength enhancement in a high volume fraction Y2O3 dispersion strengthened Cu. J Alloys Compd 753:18–27
Li M, Chen F, Si X, Wang J, Du S, Huang Q (2018) Copper–SiC whiskers composites with interface optimized by Ti3SiC2. J Mater Sci 53:9806–9815. https://doi.org/10.1007/s10853-018-2255-y
Casati R, Vedani M (2014) Metal matrix composites reinforced by nano-particles—a review. Metals 4:65–83
Zhou D, Geng H, Zeng W, Sha G, Kong C, Quadir Z, Munroe P, Torrens R, Trimby P, Zhang D (2018) Effect of extrusion temperature on microstructure and properties of an ultrafine-grained Cu matrix nanocomposite fabricated by powder compact extrusion. J Mater Sci 53:5389–5401. https://doi.org/10.1007/s10853-017-1952-2
Girish BM, Basawaraj BR, Satish BM, Somashekar DR (2012) Electrical resistivity and mechanical properties of tungsten carbide reinforced copper alloy composites. Int J Compos Mater 2:37–42
da Costa FA, da Silva AGP, Gomes UU (2003) The influence of the dispersion technique on the characteristics of the W–Cu powders and on the sintering behavior. Powder Technol 134:123–132
Stobrawa J, Rdzawski Z (2007) Dispersion–strengthened nanocrystalline copper. J Achiev Mater Manuf Eng 24:35–42
Zauter R, Kudashov DV (2006) Precipitation hardened high copper alloys for connector pins made of wire. In: Proceedings of ICEC2006/Sendai, pp 257–261
CuMg0.5. http://www.conductivity-app.org/alloy-sheet/11. Accessed 6 May 2018
Zhao N, Li J, Yang X (2004) Influence of the P/M process on the microstructure and properties of WC reinforced copper matrix composite. J Mater Sci 39:4829–4834. https://doi.org/10.1023/B:JMSC.0000035321.65140.14
Tsakiris V, Enescu E, Radulian A, Lucaci M, Lungu M, Mocioi N, Leonat L, Cirstea D, Caramitu A (2016) WC–Cu electrical contacts developed by spark plasma sintering process. In: 2016 international symposium on fundamentals of electrical engineering (ISFEE)
Acknowledgements
This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors. We thank C. Linsley at University of California, Los Angeles for proofreading the manuscript.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
All authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Yao, G., Cao, C., Pan, S. et al. High-performance copper reinforced with dispersed nanoparticles. J Mater Sci 54, 4423–4432 (2019). https://doi.org/10.1007/s10853-018-3152-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-018-3152-0