Skip to main content
SpringerLink
Log in

Green synthesis and characterization of magnetic NiFe2O4@ZnO nanocomposite and its application for photocatalytic degradation of organic dyes

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this work, for the first time, magnetic NiFe2O4@ZnO nanocomposite was synthesized using tragacanth gel by the novel sol–gel method. NiFe2O4@ZnO magnetic nanocomposite was investigated using powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM), Transmission electron microscopy (TEM), Field emission scanning electron microscopy (FESEM) and energy dispersive X-ray analysis (EDX). The NiFe2O4@ZnO MNCs exhibit ferromagnetic behavior at room temperature, with a saturation magnetization of 15.22 emu/g and a coercivity of 150 Oe. XRD results show that NiFe2O4@ZnO nanocomposite corresponds to the hexagonal wurtzite of ZnO and the spinel cubic structure of NiFe2O4. The present magnetic nanocomposite displays high photocatalytic activity for the removal of direct blue 129 dye and reactive blue 21 dye under irradiation with visible light. The results demonstrated that the catalyst can degrade ca. 98% of the direct blue 129 and ca. 96% of the reactive blue 21 dyes. The current nanocomposite can be separated from the reaction mixture using an external permanent magnet and its high performance saved even after recycling fifth times.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. J. Manna, S. Akbayrak, S. Özkar, Appl. Catal. B 208, 104 (2017)

    Article  Google Scholar 

  2. A. Abbasi, D. Ghanbari, M. Salavati-Niasari, M. Hamadanian, J. Mater. Sci. Mater. Electron. 27, 4800 (2016)

    Article  Google Scholar 

  3. F. Davar, A. Majedi, A. Abbasi, J. Mater. Sci. Mater. Electron. 28, 4871 (2017)

    Article  Google Scholar 

  4. S. Laurent, D. Forge, M. Port, A. Roch, C. Robic, L. Vander Elst, R.N. Muller, Chem. Rev. 108, 2064 (2008)

    Article  Google Scholar 

  5. R. Kodama, J. Magn. Magn. Mater. 200, 359 (1999)

    Article  Google Scholar 

  6. J.M. Chan, L. Zhang, K.P. Yuet, G. Liao, J.-W. Rhee, R. Langer, O.C. Farokhzad, Biomaterials 30, 1627 (2009)

    Article  Google Scholar 

  7. X. Gong, S. Peng, W. Wen, P. Sheng, W. Li, Adv. Funct. Mater. 19, 292 (2009)

    Article  Google Scholar 

  8. H. Chen, S. Cao, J. Yao, F. Jiang, J. Taiwan Inst. Chem. Eng. 71, 189 (2017)

    Article  Google Scholar 

  9. C.W. Lai et al., Small 4, 218 (2008)

    Article  Google Scholar 

  10. S. Xuan, L. Hao, W. Jiang, X. Gong, Y. Hu, Z. Chen, Nanotechnology 18, 035602 (2007)

    Article  Google Scholar 

  11. C. Cannas et al., Chem. Mater. 22, 3353 (2010)

    Article  Google Scholar 

  12. X. Liu, D. Geng, Z. Zhang, Appl. Phys. Lett. 92, 243110 (2008)

    Article  Google Scholar 

  13. S. Sun, C. Murray, D. Weller, L. Folks, A. Moser, Science 287, 1989 (2000)

    Article  Google Scholar 

  14. W.S. Seo et al. Nat. Mater. 5, 971 (2006)

    Article  Google Scholar 

  15. S. Xu, W. Shangguan, J. Yuan, M. Chen, J. Shi, Appl. Catal., B 71, 177 (2007)

    Article  Google Scholar 

  16. S. Akbar Hoseini, S. Khademolhoseini, J. Mater. Sci. Mater. Electron. 27, 5943 (2016)

    Article  Google Scholar 

  17. J. Patil, D. Nadargi, J. Gurav, I. Mulla, S. Suryavanshi, Mater. Lett. 124, 144 (2014)

    Article  Google Scholar 

  18. D. Wang, T. Xie, Y. Li, Nano Res. 2, 30 (2009)

    Article  Google Scholar 

  19. A. Umar, M. Chauhan, S. Chauhan, R. Kumar, G. Kumar, S. Al-Sayari, S. Hwang, A. Al-Hajry, J. Colloid Interface Sci. 363, 521 (2011)

    Article  Google Scholar 

  20. M. Sorbiun, E. Shayegan Mehr, A. Ramazani, S. Taghavi Fardood, Int. J. Environ. Res. 12, 29 (2018)

    Article  Google Scholar 

  21. I. Malagurski, S. Levic, M. Pantic, D. Matijasevic, M. Mitric, V. Pavlovic, S. Dimitrijevic-Brankovic, Carbohydr. Polym. 165, 313 (2017)

    Article  Google Scholar 

  22. A. Ali, S. Ambreen, Q. Maqbool, S. Naz, M.F. Shams, M. Ahmad, A.R. Phull, M. Zia, J. Phys. Chem. Solids 98, 174 (2016)

    Article  Google Scholar 

  23. X. Liu, J. Jiang, D. Geng, B. Li, Z. Han, W. Liu, Z. Zhang, Appl. Phys. Lett. 94, 053119 (2009)

    Article  Google Scholar 

  24. M.-S. Cao, X.-L. Shi, X.-Y. Fang, H.-B. Jin, Z.-L. Hou, W. Zhou, Y.-J. Chen, Appl. Phys. Lett. 91, 203110 (2007)

    Article  Google Scholar 

  25. R. Ghosh Chaudhuri, S. Paria, Chem. Rev. 112, 2373 (2011)

    Article  Google Scholar 

  26. X.-F. Wu, H.-Y. Song, J.-M. Yoon, Y.-T. Yu, Y.-F. Chen, Langmuir 25, 6438 (2009)

    Article  Google Scholar 

  27. J. Cao et al. Mater. Sci. Eng., B 175, 56 (2010)

    Article  Google Scholar 

  28. Y.A. Barnakov, M.H. Yu, Z. Rosenzweig, Langmuir 21, 7524 (2005)

    Article  Google Scholar 

  29. S. Taghavi Fardood, A. Ramazani, Z. Golfar, S.W. Joo, J. Appl. Chem. Res. 11, 19 (2017)

    Google Scholar 

  30. S. Taghavi Fardood, K. Atrak, A. Ramazani, J. Mater. Sci. Mater. Electron. 28, 10739 (2017)

    Article  Google Scholar 

  31. K. Atrak, A. Ramazani, S. Taghavi Fardood, J. Mater. Sci. Mater. Electron. 29, 6702 (2018)

    Article  Google Scholar 

  32. H. Sun, L. Cao, L. Lu, Nano Res. 4, 550 (2011)

    Article  Google Scholar 

  33. M. Sorbiun, E. Shayegan Mehr, A. Ramazani, S. Taghavi Fardood, J. Mater. Sci. Mater. Electron. 29, 2806 (2018)

    Article  Google Scholar 

  34. E. Shayegan Mehr, M. Sorbiun, A. Ramazani, S. Taghavi Fardood, J. Mater. Sci. Mater. Electron. 29, 1333 (2018)

    Article  Google Scholar 

  35. H.A. Alhassani, M.A. Rauf, S.S. Ashraf, Dyes Pigm. 75, 395 (2007)

    Article  Google Scholar 

  36. H. Chen, J. Motuzas, W. Martens, J.C. Diniz da Costa. Appl. Catal., B 221, 691 (2018)

    Article  Google Scholar 

  37. M.C. Silva, A.D. Corrêa, M.T.S.P. Amorim, P. Parpot, J.A. Torres, P.M.B. Chagas, J. Mol. Catal. B 77, 9 (2012)

    Article  Google Scholar 

  38. T. Kanagaraj, S. Thiripuranthagan, Appl. Catal. B 207, 218 (2017)

    Article  Google Scholar 

  39. K. Klemola, Kuopio Univ Publ C Nat Environ Sci 241, 1 (2008)

    Google Scholar 

  40. Y. Zhang, F. Gao, B. Wanjala, Z. Li, G. Cernigliaro, Z. Gu, Appl. Catal. B 199, 504 (2016)

    Article  Google Scholar 

  41. S. Taghavi Fardood, A. Ramazani, S.W. Joo, J. Appl. Chem. Res. 12, 8 (2018)

    Google Scholar 

  42. S. Taghavi Fardood, A. Ramazani, S. Moradi, Chem. J. Mold. 12, 115 (2017)

    Article  Google Scholar 

  43. M. Zohuriaan, F. Shokrolahi, Polym. Test. 23, 575 (2004)

    Article  Google Scholar 

  44. S. Taghavi Fardood, Z. Golfar, A. Ramazani, J. Mater. Sci. Mater. Electron. 28, 17002 (2017)

    Article  Google Scholar 

  45. A. Hasanpour, M. Niyaifar, M. Asan, J. Amighian, J. Magn. Magn. Mater. 334, 41 (2013)

    Article  Google Scholar 

  46. H. Liu, J. Wu, J.H. Min, X. Zhang, Y.K. Kim, Mater. Res. Bull. 48, 551 (2013)

    Article  Google Scholar 

  47. S. Farhadi, K. Pourzare, S. Sadeghinejad, J. Nanostruct. Chem. 3, 16 (2013)

    Article  Google Scholar 

  48. H.-Y. Zhu, R. Jiang, Y.-Q. Fu, R.-R. Li, J. Yao, S.-T. Jiang, Appl. Surf. Sci. 369, 1 (2016)

    Article  Google Scholar 

  49. D. Lv, D. Zhang, X. Liu, Z. Liu, L. Hu, X. Pu, H. Ma, D. Li, J. Dou, Sep. Purif. Technol. 158, 302 (2016)

    Article  Google Scholar 

  50. H.S. Kim, D. Kim, B.S. Kwak, G.B. Han, M.-H. Um, M. Kang, Chem. Eng. J. 243, 272 (2014)

    Article  Google Scholar 

  51. S. Duangjam, K. Wetchakun, S. Phanichphant, N. Wetchakun, Mater. Lett. 181, 86 (2016)

    Article  Google Scholar 

  52. J. Zheng, X. Song, X. Liu, W. Chen, Y. Li, J. Guo, Mater. Lett. 73, 143 (2012)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran

    Sajjad Moradi, Saeid Taghavi Fardood & Ali Ramazani

  2. Research Institute of Modern Biological Techniques (RIMBT), University of Zanjan, P O Box 45195-313, Zanjan, Iran

    Ali Ramazani

Authors
  1. Sajjad Moradi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Saeid Taghavi Fardood
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ali Ramazani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ali Ramazani.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Moradi, S., Taghavi Fardood, S. & Ramazani, A. Green synthesis and characterization of magnetic NiFe2O4@ZnO nanocomposite and its application for photocatalytic degradation of organic dyes. J Mater Sci: Mater Electron 29, 14151–14160 (2018). https://doi.org/10.1007/s10854-018-9548-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-9548-4

Search

Navigation