Abstract
Tin (II) sulfide films with tilted nanocolumns have been grown using thermal evaporation method on silver, gold, and platinum substrates. A number of samples were prepared at different vapor flow angles (α = 0°, 35°, and 75°) with respect to the substrate normal for studying the effects of both substrate type and growth angle. Structural and optical properties of the specimens were systematically investigated. Remarkable variations have been concluded in structural properties of the specimens as a result of employing different substrate types and growth angles. The morphological study confirmed the emergence of growth plates in nanoscale thicknesses, which are also altered due to substrate type and their growth angles. Furthermore, according to the Raman spectra of the samples, the presence of active modes characteristics for the SnS and other phases of SnS compound has been verified. The spectral analysis of atomic force microscopy of the specimens revealed the influence of substrate type and growth angle on the average surface roughness of the samples. Finally, the optical band gap of the samples estimated using Kubelka-Munk equation showed how it varies considerably by changing the substrate type and employing different growth angles.
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N. Asim, K. Sopian, S. Ahmadi, K. Saeedfar, M.A. Alghoul, A review on the role of materials science in solar cells. J. Renew. Sustain. Energy Rev. 16(8), 5834–5847 (2012)
H. Dittrich, A. Stadler, D. Topa, H.J. Schimper, A. Basch, Progress in sulfosalt research. J. Phys. Status Solidi A 206, 51034–51041 (2009)
H. Dittrich, A. Bieniok, U. Brendel, M. Grodzicki, D. Topa, Sulfosalts: a new class of compound semiconductors for photovoltaic applications. J. Thin Solid Films 515(15), 5745–5750 (2007)
M. Minbashi, A. Ghobadi, M.H. Ehsani, H.R. Dizaji, N. Memarian, Simulation of high efficiency SnS-based solar cells with SCAPS. Sol. Energy 176, 520–525 (2018)
N.K. Reddy, M. Devika, E.S.R. Gopal, Review on tin (II) sulfide (SnS) material: synthesis, properties, and applications. J. Crit. Rev. Solid State Mater. Sci. 40(6), 359–398 (2015)
Z. Arniza Ghazali, M.Z. Zainal, A. Hussein, Kassim, Cathodic electrodeposition of SnS in the presence of EDTA in aqueous media. Sol. Energy Mater. Sol. Cells 55, 237–249 (1998)
M. Parenteau, C. Carlone, Influence of temperature and pressure on the electronic transitions in SnS and SnSe semiconductors. Phys. Rev. B 41, 5227–5234 (1990)
M.S. Selim, M.E. Gouda, M.G.E. Shaarawy, A.M. Salem, W.A.A. Ghany, Effect of thickness on optical properties of thermally evaporated SnS films. Thin Solid Films 527, 164–169 (2013)
N.K. Reddy, K. Ramesh, R. Ganesan, K.T.R. Reddy, K.R. Gunasekhar, E.S.R. Gopal, Synthesis and characterisation of co-evaporated tin sulphide thin films. J. Appl. Phys. A 83(1), 133–138 (2006)
K. Hartman, J.L. Johnson, M.I. Bertoni, D. Recht, M.J. Aziz, M.A. Scarpull, T. Buonassisi, SnS thin-films by RF sputtering at room temperature. Thin Solid Films 519(21), 7421–7424 (2011)
A. Tanusevskia, D. Poelmanb, Optical and photoconductive properties of SnS thin films prepared by electron beam evaporation. J. Sol. Energy Mater. Sol. Cells 80(3), 297–303 (2003)
P. Sinsermsuksakul, J. Heo, W. Noh, A.S. Hock, R.G. Gordon, Atomic layer deposition of tin monosulfide thin films. J. Adv. Energy Mater. 1(6), 1116–1125 (2011)
N.R. Mathews, C.C. Garci, I.Z. Torres, Effect of annealing on structural, optical and electrical properties of pulse electrodeposited tin sulfide films. J. Mater. Sci. Semcond. Process. 16(1), 29–37 (2013)
A. Ortiz, J.C. Alonso, M. Garcia, J. Toriz, Tin sulphide films deposited by plasma-enhanced chemical vapour deposition. J. Semicond. Sci. Technol. 11, 243–247 (1996)
N.K. Reddy, K.T.R. Reddy, Preparation and characterisation of sprayed tin sulphide films grown at different precursor concentrations. J. Mater. Chem. Phys. 102(1), 13–18 (2007)
M.C. Rodriguez, H. Martinez, A.S. Juarez, J.C. Alvarez, A.T. Silver, M.E. Calixto, Structural, optical, and electrical properties of tin sulfide thin films grown by spray pyrolysis. J. Thin Solid Films 517(7), 2497–2499 (2009)
M. Patel, I. Mukhopadhyay, A. Ray, Annealing influence over structural and optical properties of sprayed SnS thin films. J. Opt. Mater. 35(9), 1693–1699 (2013)
A. Akkaria, C. Guasch, N.K. Turki, Chemically deposited tin sulphide. J. Alloys Compd. 490, 180–183 (2010)
C. Gao, H. Shen, Influence of the deposition parameters on the properties of orthorhombic SnS films by chemical bath deposition. J. Thin Solid Films 520(9), 3523–3527 (2012)
M. Ichimura, K. Takeuchi, Y. Ono, E. Arai, Electrochemical deposition of SnS thin films. J. Thin Solid Films 361, 98–101 (2000)
M.R. Sazideh, H.R. Dizaji, M.H. Ehsani, R.Z. Moghadam, Modification of the morphology and optical properties of SnS films using glancing angle deposition technique. J. Appl. Surf. Sci. 450, 514–520 (2017)
A. Barranco, A. Borras, A.R. Gonzalez-Elipe, A. Palmero, Perspectives on oblique angle deposition of thin films: from fundamentals to devices. J. Prog. Mater. Sci. 76, 59–152 (2016)
S.Z. Rahchamani, H.R. Dizaji, M.H. Ehsani, Study of structural and optical properties of ZnS zigzag nanostructured thin films. J. Appl. Surf. Sci. 356, 1096–1104 (2015)
F.H. Siyanaki, H.R. Dizaji, M.H. Ehsani, S. Khorramabadi, The effect of substrate rotation rate on physical properties of cadmium telluride films prepared by a glancing angle deposition method. Thin Solid Films 577, 128–133 (2015)
M. Molla Ali Ashrafi, H.R. Dizaji, M.H. Ehsani, R.Z. Moghadam, ZnS films properties modification using oblique angle deposition technique. Surf. Rev. Lett. 25, 1850119–1850125 (2018)
M. Devika, N.K. Reddy, K. Ramesh, H.R. Sumana, K.R. Gunasekhar, E.S.R. Gopal, K.T.R. Reddy, The effect of substrate surface on the physical properties of SnS films. J. Semicond. Sci. Technol. 21, 1495–1501 (2006)
M.R. Sazideh, M.H. Ehsani, H. Rezagholipour Dizaji, R. Zarei, Moghadam, Substrate-induced changes of structural and optical properties of SnS films prepared by glancing angle deposition. J. Thin Solid Films 663, 85–92 (2018)
M. Devika, N.K. Reddy, M. Prashantha, K. Ramesh, S. Venkatramana Reddy, Y.B. Hahn, K.R. Gunasekhar, The physical properties of SnS films grown on lattice-matched and amorphous substrates. J. Phys. Status Solidi A 207(8), 1864–1869 (2010)
N. Revathi, S. Bereznev, J. Iljina, M. Safonova, E. Mellikov, O. Volobujeva, PVD grown SnS thin films onto different substrate surfaces. J Mater. Sci. Mater. Electron. 24(12), 4739–4744 (2013)
B.E. Warren, X-ray Diffraction (Dover, New York, 1990)
B. Viswanathan, J. Dharmaraja, J. Balamurugan, Structural parameters and optical constants of CdS nanocrystalline thin films. Nano 6(3), 251–258 (2011)
N.K. Samani, Z.D. Tafti, H.A. Bioki, M.B. Zarandi, S. Shayegh, Annealing effect on structural and optical constants of SnS thin films for solar cells application. Optik 131, 231–241 (2017)
T.S. Reddy, M.C.S. Kumar, Co-evaporated SnS thin films for visible light photodetector applications. J. RSC Adv. 6, 95680–95692 (2016)
H.R. Chandrasekhar, R.G. Humphreys, U. Zwick, M. Cardona, Infrared and Raman spectra of the IV-VI compounds SnS and SnSe. J. Phys. Rev. B 15(4), 2177–2183 (1977)
B.H. Baby, D.B. Mohan, The formation of α-phase SnS nanostructure from a hybrid, multi-layered S/Sn/S/Sn/S thin films: phase stability, surface morphology and optical studies. J. Appl. Surf. Sci. 423, 1111–1123 (2017)
A. Voznyi, V. Kosyak, P. Onufrijevs, L. Grase, J. Vecstaudža, A. Opanasyuk, A. Medvid, Laser-induced SnS2-SnS phase transition and surface modification in SnS2 thin films. J. Alloys Compd. 688, 130–139 (2016)
Ch. Wang, K. Tang, Q. Yang, Y. Qian, Raman scattering, far infrared spectrum and photoluminescence of SnS2 nanocrystallites. J. Chem. Phys. Lett. 357, 371–375 (2002)
B. Li, T. Xing, M. Zhong, L. Huang, N. Lei, J. Zhang, J. Li, Z. Wei, A two-dimensional Fe-doped SnS2 magnetic semiconductor. J. Nat. Commun. 8(1), 1958 (2017)
Y. Liu, D. Hou, G. Wang, Synthesis and characterization of SnS nanowires in cetyltrimethylammonium bromide (CTAB) aqueous solution. J. Chem. Phys. Lett. 379(1–2), 67–73 (2003)
X.L. Gou, J. Chen, P.W. Shen, Synthesis, characterization and application of SnSx (x = 1, 2) nanoparticles. J. Mater. Chem. Phys. 93, 557–566 (2005)
R.R.L. De Oliveira, D.A.C. Albuquerque, T.G.S. Cruz, F.M. Yamaji, F.L. Leite, Measurement of the Nanoscale Roughness by Atomic Force Microscopy: Basic Principles and Applications. J. Measuring and Manipulating Surfaces at the Atomic Scale (IntechOpen, London, 2012), pp. 147–174
T. Karabacak, Thin-film growth dynamics with shadowing and re-emission effects. J. Nanophoton. 5(1), 052501 (2011)
R.B. Tokas, S. Jena, P. Sarkar, S.R. Polaki, S. Thakur, S. Basu, N.K. Sahoo, Oblique angle deposition of HfO2 thin films: quantitative assessment of indentation modulus and micro structural properties. J. Mater. Res. Express 2, 035010 (2015)
R.B. Tokas, S. Jena, S. Thakur, N.K. Sahoo, Effect of angle of deposition on micro-roughness parameters and optical properties of HfO2 thin films deposited by reactive electron beam evaporation. J. Thin Solid Films 609, 42–48 (2016)
F.C. Akkari, M. Kanzari, B. Rezig, Nanocolumnar CuInS2 thin films by glancing angle depositio. J. Phys. E 40(7), 2577–2582 (2008)
B. Aslibeiki, P. Kameli, M.H. Ehsani, MnFe2O4 bulk, nanoparticles and film: A comparative study of structural and magnetic properties. J. Ceram. Int. 42(11), 12789–12795 (2016)
N. Sato, M. Ichimura, E. Arai, Y. Yamazaki., J. Sol, Characterization of electrical properties and photosensitivity of SnS thin films prepared by the electrochemical deposition method. Sol. Energy Mater. Sol. Cells. 85(2), 153–165 (2005)
A.A. Christy a, O.M. Kvalheim, R.A. Velapoldi, Quantitative analysis in diffuse reflectance spectrometry: a modified Kubelka-Munk equation. J. Vib. Spec. 9, 19–27 (1995)
T. Sall, M. Mollar, B. Marı, Substrate influences on the properties of SnS thin films deposited by chemical, spray pyrolysis technique for photovoltaic applications. J. Mater. Sci. 51, 7607–7613 (2016)
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Shahidi, M.M., Ehsani, M.H., Rezagholipour Dizaji, H. et al. Effect of silver, gold, and platinum substrates on structural and optical properties of tilted nanocolumnar SnS films. J Mater Sci: Mater Electron 31, 2030–2039 (2020). https://doi.org/10.1007/s10854-019-02722-x
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DOI: https://doi.org/10.1007/s10854-019-02722-x