Skip to main content
Log in

A low-cost (Mg1-xCax)3B2O6 (0 ≤ x ≤ 1.0 mol.%) ceramic with enhanced microwave dielectric properties

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

A low-cost (Mg1-xCax)3B2O6 (0 ≤ x ≤ 1.0 mol.%) (MCxB) microwave dielectric ceramic was prepared by solid-state method. X-ray diffraction, scanning electron microscope, and vector network analyzer were adopted to characterize the phase composition, microstructure, and microwave dielectric properties of the as-fabricated MCxB ceramics. All the MCxB (x = 0–1.0 mol.%) ceramic samples exhibit the singe orthorhombic structure corresponding to Mg3B2O6 (JCPDS 75–1807). Excellent microwave dielectric properties (εr = 6.8, Q × f = 103,556 GHz, τf = − 34.5 ppm/°C at 12.6 GHz) were obtained in the MC0.002B (x = 0.2 mol.%) ceramic sintered at 1250 °C for 3 h, making it a prospective candidate for the practical application in portable terminal and wireless communications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. H. Zhang, J. Li, D. Liu, S. Min, T.H. Chang, K. Xiong, S.H. Park, J. Kim, Y.H. Jung, J. Park, J. Lee, J. Han, L. Katehi, Z. Cai, S. Gong, Z. Ma, Nat. Commun. 11, 3118 (2020)

    CAS  Google Scholar 

  2. H.B. Bafrooei, B. Liu, W. Su, K.X. Song, Mater. Lett. 263, 127248 (2020)

    CAS  Google Scholar 

  3. M. Ma, Y. Wang, M. Navarro-Cia, F. Liu, F. Zhang, Z. Li, Y. Li, S.M. Hanham, Z. Hao, J. Eur. Ceram. Soc. 39, 4424 (2019)

    CAS  Google Scholar 

  4. H. Zhou, C. Lu, S. Li, J. Deng, K. Wang, Mater. Lett. 263, 127240 (2020)

    CAS  Google Scholar 

  5. X. Zhou, H. Zhou, Q. Wu, X. Luan, S. Hu, J. Deng, S. Li, K. Wang, X. Chen, J. Mater. Sci.-Mater. Electron. 31, 10819 (2020)

    CAS  Google Scholar 

  6. Y.J. Gu, L.W. Lei, J.L. Huang, X.H. Yang, Q. Li, L.H. Li, X.L. Li, B.H. Kim, J. Eur. Ceram. Soc. 39, 1137 (2019)

    CAS  Google Scholar 

  7. L.C. Chang, B.S. Chiou, J. Electroceram. 13, 829 (2004)

    CAS  Google Scholar 

  8. B.J. Kim, M.H. Kim, S. Nahm, H.T. Kim, J.H. Kim, J.H. Paik, H. Ryu, H.J. Lee, J. Eur. Ceram. Soc. 27, 1065 (2007)

    CAS  Google Scholar 

  9. T. Mutluer, M. Timucin, J. Am. Ceram. Soc. 58, 196 (1975)

    CAS  Google Scholar 

  10. J. Zhang, Y.M. Zhao, Acta Physico-Chim. Sin. 22, 110 (2006)

    CAS  Google Scholar 

  11. A. Obut, J. Alloy. Compd. 457, 86 (2008)

    CAS  Google Scholar 

  12. A.M. Chen, J. Li, P. Gu, J. Hu, Powder Technol. 267, 54 (2014)

    CAS  Google Scholar 

  13. B. Xu, T. Li, Y. Zhang, Z. Zhang, X. Liu, J. Zhao, Cryst. Growth Des. 8, 1218 (2008)

    CAS  Google Scholar 

  14. A. Mitra, B.C. Yearwood, T.S. Keizer, D.A. Atwood, Main Group Chem. 9, 193 (2010)

    CAS  Google Scholar 

  15. E.M. Elssfah, A. Elsanousi, J. Zhang, H.S. Song, C. Tang, Mater. Lett. 61, 4358 (2007)

    CAS  Google Scholar 

  16. Y. Zeng, H. Yang, W. Fu, L. Qiao, L. Chang, J. Chen, H. Zhu, M. Li, G. Zou, Mater. Res. Bull. 43, 2239 (2008)

    CAS  Google Scholar 

  17. X. Tao, X. Li, Nano Lett. 8, 505 (2008)

    CAS  Google Scholar 

  18. N. Mori, Y. Sugimoto, J. Harada, Y. Higuchi, J. Eur. Ceram. Soc. 26, 1925 (2006)

    CAS  Google Scholar 

  19. Y.J. Gu, X.B. Ding, W. Hu, J.L. Huang, Q. Li, L.H. Li, X.L. Li, X.H. Yang, M. Chen, B.H. Kim, Ceram. Int. (2020). https://doi.org/10.1016/j.ceramint.2020.07.073

    Article  Google Scholar 

  20. M. Nishizuka, H. Ogawa, A. Kan, M. Sumino, Ferroelectrics 388, 101 (2009)

    CAS  Google Scholar 

  21. U. Dosler, M.M. Krzmanc, B. Jancar, D. Suvorov, J. Am. Ceram. Soc. 93, 3788 (2010)

    CAS  Google Scholar 

  22. U. Dosler, M.M. Krzmanc, D. Suvorov, J. Eur. Ceram. Soc. 30, 413 (2010)

    CAS  Google Scholar 

  23. D.X. Zhou, F. Sun, Y.X. Hu, Q.Y. Fu, G. Dou, J. Mater. Sci.-Mater. Electron. 23, 981 (2012)

    CAS  Google Scholar 

  24. G. Dou, M. Guo, Y. Li, J. Lin, J. Mater. Sci.-Mater. Electron. 26, 4207 (2015)

    CAS  Google Scholar 

  25. H. Du, C.C. Li, F.L. Liu, Y.W. Zhang, L.F. Cui, J.X. Bi, H.T. Wu, J. Mater. Sci.-Mater. Electron. 28, 8304 (2017)

    CAS  Google Scholar 

  26. S. Peng, C. Zhao, G. Huang, S. Wang, J. Xu, X. Li, S. Yu, J. Mater. Sci.-Mater. Electron. 29, 17047 (2018)

    CAS  Google Scholar 

  27. C.H. Yang, C.F. Xing, L. Zhao, J.X. Bi, H.T. Wu, Ceram. Int. 44, 7286 (2018)

    CAS  Google Scholar 

  28. P. Zhang, K. Sun, L. Liu, M. Xiao, J. Alloy. Compd. 765, 1209 (2018)

    CAS  Google Scholar 

  29. H. Wang, P. Liu, J. Wei, S. Wu, K. Song, J. Chin. Ceram. Soc. 43, 1203 (2015)

    CAS  Google Scholar 

  30. I. Hameed, B. Liu, L. Li, X.Q. Liu, X.M. Chen, Int. J. Appl. Ceram. Tech. 16, 2040 (2019)

    CAS  Google Scholar 

  31. N. Najafvandzadeh, R. Vali, Physica B-Condens. Matter. 572, 266 (2019)

    CAS  Google Scholar 

  32. Q. Dai, R. Zuo, Y. Xu, L. He, J. Eur. Ceram. Soc. 40, 376 (2020)

    CAS  Google Scholar 

  33. R.D. Shannon, J. Appl. Phys. 73, 348 (1993)

    CAS  Google Scholar 

  34. Y.J. Gu, X.H. Yang, X. Wang, J.L. Huang, Q. Li, L.H. Li, X.L. Li, B.H. Kim, J. Mater. Sci.-Mater. Electron. 30, 18025 (2019)

    CAS  Google Scholar 

  35. H. Zhou, X. Tan, X. Liu, K. Wang, S. Li, X. Chen, J. Mater. Sci.-Mater. Electron. 29, 18486 (2018)

    CAS  Google Scholar 

  36. Y. Zhang, Y. Zhang, B. Fu, M. Hong, M. Xiang, Z. Liu, J. Leng, J. Mater. Sci.-Mater. Electron. 25, 5475 (2014)

    CAS  Google Scholar 

  37. A. Kan, H. Ogawa, M. Sumino, M. Nishizuka, E. Suzuki, Jpn. J. Appl. Phys. 48, 09KE03 (2009)

    Google Scholar 

  38. H.P. Sun, Q.L. Zhang, H. Yang, J.L. Zou, Mater. Sci. Eng. B 138, 46 (2007)

    CAS  Google Scholar 

  39. Y. Guo, H. Ohsato, K.I. Kakimoto, J. Eur. Ceram. Soc. 26, 1827 (2006)

    CAS  Google Scholar 

  40. T. Sugiyama, T. Tsunooka, K.I. Kakimoto, H. Ohsato, J. Eur. Ceram. Soc. 26, 2097 (2006)

    CAS  Google Scholar 

  41. N.H. Nguyen, J.B. Lim, S. Nahm, J.H. Paik, J.H. Kim, J. Am. Ceram. Soc. 90, 3127 (2007)

    CAS  Google Scholar 

  42. M.E. Song, J.S. Kim, M.R. Joung, S. Nahm, Y.S. Kim, J.H. Paik, B.H. Choi, J. Am. Ceram. Soc. 91, 2747 (2008)

    CAS  Google Scholar 

  43. X.G. Wu, H. Wang, Y.-H. Chen, D. Zhou, J. Am. Ceram. Soc. 95, 1793 (2012)

    CAS  Google Scholar 

  44. I. Kagomiya, I. Suzuki, H. Ohsato, Jpn. J. Appl. Phys. 48, 09KE02 (2009)

    Google Scholar 

  45. G.Q. Zhang, J. Guo, L. He, D. Zhou, H. Wang, J. Koruza, M. Kosec, J. Am. Ceram. Soc. 97, 241 (2014)

    CAS  Google Scholar 

  46. J.J. Bian, D.W. Kim, K.S. Hong, Mater. Res. Bull. 40, 2120 (2005)

    CAS  Google Scholar 

  47. M.M. Krzmanc, M. Valant, D. Suvorov, J. Eur. Ceram. Soc. 27, 1181 (2007)

    CAS  Google Scholar 

  48. A. Yokoi, H. Ogawa, A. Kan, Y. Nakamura, J. Eur. Ceram. Soc. 27, 2989 (2007)

    CAS  Google Scholar 

  49. K.M. Manu, T. Joseph, M.T. Sebastian, Mater. Chem. Phys. 133, 21 (2012)

    CAS  Google Scholar 

  50. B.K. Choi, G.N. Sun, E.S. Kim, Ceram. Int. 39, S677 (2013)

    CAS  Google Scholar 

  51. S. Wu, Q. Ma, J. Alloy. Compd. 567, 40 (2013)

    CAS  Google Scholar 

  52. Y.J. Gu, C. Li, J.L. Huang, Q. Li, L.H. Li, X.L. Li, J. Eur. Ceram. Soc. 37, 4673 (2017)

    CAS  Google Scholar 

  53. M.H. Kim, J.B. Lim, J.C. Kim, S. Nahm, J.H. Paik, J.H. Kim, K.S. Park, J. Am. Ceram. Soc. 89, 3124 (2006)

    CAS  Google Scholar 

  54. C.L. Huang, C.L. Pan, J.F. Hsu, Mater. Res. Bull. 37, 2483 (2002)

    CAS  Google Scholar 

  55. H. Ohsato, T. Tsunooka, M. Ando, Y. Ohishi, Y. Miyauchi, K.I. Kakimoto, J. Korean Ceram. Soc. 4, 350 (2003)

    Google Scholar 

  56. D.J. Kim, J.W. Hahn, G.P. Han, S.S. Lee, T.G. Choy, J. Am. Ceram. Soc. 83, 1010 (2000)

    CAS  Google Scholar 

  57. H. Ohsato, A. Komura, Y. Takagi, S. Nishigaki, T. Okuda, Jpn. J. Appl. Phys. 37, 5357 (1998)

    CAS  Google Scholar 

Download references

Acknowledgements

The authors are acknowledged for the support by Henan Key Laboratory of Research for Central Plains Ancient Ceramics, Pingdingshan University (ZYGTCXW2018-02, ZYGTCKF201902, ZYGTCKF201903).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yong-jun Gu, Xing-hua Yang or Min Chen.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gu, Yj., Yang, Xh., Ding, Xb. et al. A low-cost (Mg1-xCax)3B2O6 (0 ≤ x ≤ 1.0 mol.%) ceramic with enhanced microwave dielectric properties. J Mater Sci: Mater Electron 31, 18289–18296 (2020). https://doi.org/10.1007/s10854-020-04376-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-020-04376-6

Navigation