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Improved Synthesis, Structure, and Solution Characterization of the Cyclic 48-Tungsto-8-Arsenate(V), [H4As8W48O184]36−

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Abstract

We report on an improved synthesis and structural characterization of the cyclic 48-tungsto–8-arsenate(V) [H4As8W48O184]36− (1). The mixed lithium–potassium salt of this polyanion, K26.5Li9.5[H4As8W48O184]·90H2O (KLi-1), has been studied in the solid state by IR, single-crystal X-ray diffraction, and elemental analysis, and in solution by 183W NMR spectroscopy.

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Acknowledgments

This work was supported by the Centre National de la Recherche Scientifique (UMR 8180, UMR 8000), the University of Versailles, the University of Paris-Sud, the German Science Foundation (DFG KO 2288/3-1, KO 2288/3-2), and Jacobs University. We thank Dr. Travis M. Anderson (Sandia National Laboratories, USA) for participating in the preliminary stages of this project. Figure 1 was generated by Diamond Version 3.2g (copyright Crystal Impact GbR).

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Authors and Affiliations

  1. Institut Lavoisier de Versailles, UMR 8180, CNRS, Université de Versailles St. Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035, Versailles Cedex, France

    Israël-Martyr Mbomekallé, Mohamed Haouas & Francis Taulelle

  2. School of Engineering and Science, Jacobs University, P.O. Box 750 561, 28725, Bremen, Germany

    Bassem S. Bassil, Andreas Suchopar & Ulrich Kortz

  3. Laboratoire de Chimie Physique, UMR 8000, CNRS, Equipe d’Electrochimie et de Photoelectrochimie, Université Paris-Sud, Bâtiment 350, 91405, Orsay Cedex, France

    Israël-Martyr Mbomekallé, Bineta Keita, Louis Nadjo & Malika Ammam

Authors
  1. Israël-Martyr Mbomekallé
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  2. Bassem S. Bassil
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  3. Andreas Suchopar
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  4. Bineta Keita
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  5. Louis Nadjo
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  6. Malika Ammam
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  7. Mohamed Haouas
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  8. Francis Taulelle
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  9. Ulrich Kortz
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Corresponding authors

Correspondence to Israël-Martyr Mbomekallé or Ulrich Kortz.

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Louis Nadjo has deceased before publication of this work.

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Mbomekallé, IM., Bassil, B.S., Suchopar, A. et al. Improved Synthesis, Structure, and Solution Characterization of the Cyclic 48-Tungsto-8-Arsenate(V), [H4As8W48O184]36− . J Clust Sci 25, 277–285 (2014). https://doi.org/10.1007/s10876-013-0656-2

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