Abstract
In this research, the layered inorganic–organic hybrids materials based on tungsten oxide were synthesized using three amino-hydroxy ligands; 2-(2-aminoethoxy) ethanol (AEE), 2-(2-aminoethylamino) ethanol, and diethylenetriamine, by direct intercalation of these guest ligands. Then, the synthesized hybrids were applied as the novel supercapacitor electrode materials. Various analytical techniques were utilized to investigate the interaction between the inorganic and organic components and to understand how the intercalation of organic guests effects on the electrocapacitive performance of the electrodes. The evaluation of electrodes properties shows the outstanding performance of the [WO3·AEE] hybrid electrode that is annealed at 300 °C, the hybrid with more oxygen donor ligands versus the other ligands that have more amino groups. This hybrid has the highest specific capacitance of 207.27 F/g at the current density of 2 A/g with 100% capacitance retention. Also, this hybrid electrode exhibits a good power density of 1127 Wh kg−1 at the energy density of 1.25 kW kg−1. These results exhibit the outstanding electrocapacitive performance of hybrids revealing from the synergetic effects of organic and inorganic parts in the hybrids that made them more active than pure WO3 electrode. The intercalations of organic guests increase the oxide interlayer space that can accelerate the ion diffusion. Also, the electron donations of organic guests to the tungsten inorganic center can surprisingly increase the kinetics of electron transfer and consequently improve the performance of the electrode.
Similar content being viewed by others
References
A. González, E. Goikolea, J.A. Barrena, R. Mysyk, Renew. Sustain. Energy Rev. 58, 1189 (2016)
P. Simon, Y. Gogotsi, Nanosci. Technol. 320 (2009)
A. Borenstein, O. Hanna, R. Attias, Sh Luski, Th Brousse, D. Aurbach, J. Mater. Chem. A. 5, 12653 (2017)
G. Wang, L. Zhang, J. Zhang, Chem. Soc. Rev. 41, 797 (2012)
P. Simon, Y. Gogotsi, B. Dunn, Science 343, 1210 (2014)
S. Rudra, R. Chakraborty, P.K. Maji, S. Koley, A.K. Nayak, D. Paul, M. Pradhan, Electrochim. Acta 324, 134865 (2019)
S. Rudra, A.K. Nayak, S. Koley, R. Chakraborty, P.K. Maji, M. Pradhan, ACS Sustain. Chem. Eng. 71, 724 (2019)
K.J. Samdani, D.W. Joh, K.T. Lee, J. Alloys Compd. 748, 134 (2018)
B.T. Liu, X.M. Shi, X.Y. Lang, L. Gu, Z. Wen, M. Zhao, Q. Jiang, Nat. Commun. 9, 1 (2018)
X. Guo, G. Zhang, Q. Li, H. Xue, H. Pang, Energy Storage Mater. 15, 171 (2018)
S.C. Sekhar, G. Nagaraju, J.S. Yu, Nano Energy 48, 81 (2018)
L. Li, K.S. Hui, K.N. Hui, T. Zhang, J. Fu, Y.R. Cho, Chem. Eng. J. 348, 338 (2018)
M. Zhang, H. Fan, N. Zhao, H. Peng, X. Ren, W. Wang, H. Li, G. Chen, Y. Zhu, X. Jiang et al., Chem. Eng. J. 347, 291 (2018)
L. Shen, L. Du, S. Tan, Z. Zang, C. Zhao, W. Mai, Chem. Commun. 52, 6296 (2016)
Z.F. Huang, J. Song, L. Pan, X. Zhang, L. Wang, J.J. Zou, Adv. Mater. 27, 5309 (2015)
H. Zheng, J.Z. Ou, M.S. Strano, R.B. Kaner, A. Mitchell, K. Kalantar-Zadeh, Adv. Funct. Mater. 21, 2175 (2011)
C. Di Valentin, G. Pacchioni, Acc. Chem. Res. 47, 3233 (2014)
Wang, J. Li, X. Cao, G. Pang, S. Feng, Chem. Commun. 46, 7718 (2010)
S. Yoon, E. Kang, J.K. Kim, C.W. Lee, J. Lee, Chem. Commun. 47, 1021 (2011)
S. Yoon, C. Jo, S.Y. Noh, C.W. Lee, J.H. Song, J. Lee, Phys. Chem. Chem. Phys. 13, 11060 (2011)
H. Peng, G. Ma, K. Sun, J. Mu, M. Luo, Z. Lei, Electrochim. Acta 147, 54 (2014)
Y. Zhou, S. Ko, C.W. Lee, S.G. Pyo, S.K. Kim, S. Yoon, J. Power Sources 244, 777 (2013)
Y.-H. Wang, C.-C. Wang, W.-Y. Cheng, S.-Y. Lu, Carbon 69, 287 (2014)
L.N. Gao, X.F. Wang, Z. Xie, W.F. Song, L.J. Wang, X. Wu, F.Y. Qu, D. Chen, G.Z. Shen, J. Mater. Chem. A. 1, 7167 (2013)
C.R. Raj, S. Bag, J. Mater. Chem. A. 2, 17848 (2014)
P. Gornez-Romero, M. Lira-Cantu, Adv. Matter. 9, 144 (1997)
M. Lira-Cantú, P. Gómez-Romero, Chem. Mater. 10, 698 (1998)
P. Gómez-Romero, M. Chojak, K. Cuentas-Gallegos, J.A. Asensio, P.J. Kulesza, N. Casañ-Pastor, M. Lira-Cantú, Electrochem. Commun. 5, 149 (2003)
ChA Nwanya, C.J. Jaftab, P.M. Ejikem, P.E. Ugwuoke, M.V. Reddy, R.U. Osuji, K.I. Ozoemen, F.I. Ezem, Electrochim. Acta 128, 218 (2014)
V. Ruiz, J. Suárez-Guevara, P. Gomez-Romero, ECS Trans. 50, 117 (2013)
M. Afsharpour, A.R. Mahjoub, M.M. Amini, A.A. Khodadadi, Curr. Nanosci. 6, 82 (2010)
M. Afsharpour, A. Mahjoub, M.M. Amini, J. Inorg. Organomet. Polym. Mater. 19, 298 (2009)
Y. Jing, Q. Pan, Z. Cheng, X. Dong, Y. Xiang, Sci. Eng. B Solid State Mater. Adv. Technol. 138, 55 (2007)
O.Y. Posudievsky, S.A. Biskulova, V.D. Pokhodenko, J. Mater. Chem. 12, 1446 (2002)
M. Afsharpour, A. Mahjoub, M.M. Amini, J. Inorg. Organomet. Polym. Mater. 18, 472 (2008)
R.F. De Farias, Mater. Chem. Phys. 90, 302 (2005)
M.I. Schukoor, H.A. Therese, L. Gorgishvili, G. Glasser, U. Kolb, W. Tremel, Chem. Mater. 18, 2144 (2006)
Cheng, Y. Yang, Y. Luo, Ch. Fang, J. Xiong, Electrochim. Acta. 176, 1343 (2015)
Y.W. Li, J.H. Yao, C.J. Liu, W.M. Zhao, W.X. Deng, S.K. Zhong, Int. J. Hydrogen. Energy. 35, 2539 (2010)
Y. Wang, Y. Song, Y. Xia, Chem. Soc. Rev. 45, 5925 (2016)
L.L. Xing, K.J. Huang, L.X. Fang, Dalt. Trans. 45, 17439 (2016)
A.K. Cuentas-Gallegos, M. Lira-Cantú, N. Casañ-Pastor, P. Gómez-Romero, Adv. Funct. Mater. 15, 1125 (2005)
D. Mandal, P. Routh, A.K. Nandi, Small 14, 1 (2018)
C.C. Tu, L.Y. Lin, B.C. Xiao, Y.S. Chen, J. Power Source. 320, 78 (2016)
I. Yang, S.G. Kim, S.H. Kwon, M.S. Kim, J.C. Jung, Electrochim. Acta 223, 21 (2017)
K. Eloot, F. Debuyck, M. Moors, A.P. Van Peteghem, J. Appl. Electrochem. 25, 326 (1995)
H. Keiser, K.D. Beccu, M.A. Gutjahr, Electrochim. Acta 21, 539 (1976)
Acknowledgements
Support of this investigation by CCERCI is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Afsharpour, M., Bayatpour, S. & Seifikar Gomi, L. Inorganic–Organic Hybrids of Tungsten Oxide as the High Performance Intercalation Supercapacitor Electrodes. J Inorg Organomet Polym 30, 2406–2417 (2020). https://doi.org/10.1007/s10904-019-01422-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-019-01422-7