Abstract
Seven homo- and hetero-bimetallic macromolecular complexes (BMCs) were prepared via an in-situ multi-step complexation reaction of CuII, NiII and FeIII metal centers with imine- oxime π-conjugated ditropic spacer (1,4-phenylene-bis(2,3-butanedeimineoxime, L2−). The structures of the obtained [M-L2-M]x, [M`-L2-M`]x, [M-L2-M`]x and their μ-oxo-[M-L2-Fe]x BMCs (M = CuII, NiII; M` = FeIII) were elucidated using different spectroscopic (UV–Vis, FT-IR), powder X-ray diffraction (p-XRD) and microscopic (SEM) techniques. The SEM images indicate that the obtained BMCs exhibit nano/micro globular and rod-like textures. The electrical and magnetic characteristics of the obtained BMCs can be described as magneto-semiconducting materials. The structural, electrical, and magnetic properties inherited in the prepared regime demonstrate that the examined semiconducting π-spacer has clear ability to semi-conduct electron transport and delocalize spin leading to antiferromagnetic coupling, thus offering a favorable magnetic exchange pathway between the paramagnetic metal sites. However, ferromagnetic enhancement is observed in the μ-oxo-[M-L2-Fe]x BMCs where the μ-oxo-bridge overplays the role of the π-spacer. A magnetic responsive thin film was conveniently obtained by solvent casting of the μ-oxo-[Ni-L2-Fe]x BMC in a transparent poly(methamethylacrylate) matrix.
Similar content being viewed by others
References
Y. Wang, D. Astruc, A.S. Abd-El-Aziz, Chem. Soc. Rev. 48, 558 (2019)
J.M. Seco, I. Oyarzabal, S.P. Yáñez, J. Cepeda, A.R. Diéguez, Inorg. Chem. 55(21), 11230 (2016)
S.M. Jansze, K. Severin, Acc. Chem. Res. 51(9), 2139 (2018)
K.S. Mali, N. Pearce, S.D. Feyter, N.R. Champness, Chem. Soc. Rev. 46, 2520 (2017)
C. Bizzarri, E. Spuling, D.M. Knoll, D. Volz, S. Bräse, Coord. Chem. Rev. 373, 49 (2018)
C. Rüttiger, H. Hübner, S. Schöttner, T. Winter, G. Cherkashinin, B. Kuttich, B. Stühn, M. Gallei, A.C.S. Appl, Mater. Interfaces 10(4), 4018 (2018)
M.P. Suh, Y.E. Cheon, E.Y. Lee, Coord. Chem. Rev. 252, 1007 (2008)
J. Zhou, G.R. Whittell, I. Manners, Macromolecules 47(11), 3529 (2014)
A.A.G. Valdivia, S.P. Yáñez, J.A. García, B. Fernández, J. Cepeda, A.R. Diéguez, Sci. Rep. (2020). https://doi.org/10.1038/s41598-020-65687-6
B. Wang, M. Jacquet, K. Wang, K. Xiong, M. Yan, J. Courtois, G. Royal, New J. Chem. 42, 7823 (2018)
R.M. Clarke, T. Storr, Dalton Trans. 43(25), 9380 (2014)
Z. Shao, X. Han, Y. Liu, W. Xu, Q. Wu, Q. Xie, Y. Zhao, H. Hou, Dalton Trans. 48, 6191 (2019)
X. Pan, X. Wang, X. Wang, Y. Li, G. Liu, H. Lin, CrystEngComm 21, 6472 (2019)
C.D. Mekuimemba, F. Conan, A.J. Mota, M.A. Palacios, E. Colacio, Inorg. Chem. 57(4), 2184 (2018)
J.L. Wang, Y. Bai, H. Pan, G.S. Zheng, D.B. Dang, Dalton Trans. 46, 12771 (2017)
B. Belhadji, L. Bergqvist, R. Zeller, P.H. Dederichs, K. Sato, H.K. Yoshida, J. Phys. 19, 436227 (2007)
M.A. Halcrow, Spin Crossover Materials: Properties and Applications (John Wiley & Sons Ltd, Oxford, UK, 2013)
G. Fornasieri, A. Bordage, A. Bleuzen, Eur. J. Inorg. Chem. 259, 1322 (2018)
X. Li, X. Wu, Z. Li, J. Yang, J.G. Hou, Nanoscale 4, 5680 (2012)
V. R-Giménez, S. Tatay, C. M-Gastaldo 2020 Chem. Soc. Rev. DOI. 10.1039/C9CS00594C
L. Sun, C.H. Hendon, S.S. Park, Y. Tulchinsky, R. Wan, F. Wang, A. Walsh, M. Dincă, Chem. Sci. 8(6), 4450 (2017)
C. Mathonière, Eur. J. Inorg. Chem. 3(4), 248 (2018)
P. Blake, J. St. Onge, T-C. Chen, A. Langlois, A. Younus, I J. Hai, B-H Lin, Y-C Chiu, S. R-Gagné 2020 J. Mater. Chem. C. 8, 24, 8213
I. Arafa, H. El-Ghanem, S. Nemrat 2007 In Recent Developments in Polymer Research, A.V. Hopper (eds) Nova Science Publishers Inc., New York, pp 1–28.
I.M. Arafa, H. El-Ghanem, R. Al-Shalabi, J. Inorg. Organomet. Polym. 13, 69 (2003)
W. Plass, Coord. Chem. Rev. 253, 2286 (2009)
S. Ross, T. Weyhermüller, E. Bill, E. Bothe, U. Flörke, K. Wieghardt, P. Chaudhuri, Eur. J. Inorg. Chem. 5, 984 (2004)
B.J. Holliday, T.M. Swager, Chem. Commun. 23(36), 23 (2005)
T.A. Shestimerova, A.V. Shevelkov, Russ. Chem. Rev. 87, 28 (2018)
X. Ma, E.A. Suturina, S. De, P. Négrier, M. Rouzières, R. Clérac, P. Dechambenoit, Angew. Chem. 57(26), 7841 (2018)
S. Gupta, M. Fátima, C.G. da-Silva, A.J.L. Pombeiro, Heliyon 5(5), e01623 (2019)
C.I. Yang, Z.Z. Zhang, S.B. Lin, Coord. Chem. Rev. 289, 289–290 (2015)
D.S. Bolotin, N.A. Bokach, VYu. Kukushkin, Coord. Chem. Rev. 313, 62 (2016)
J.W. Maciel, L.H.G. Kalinke, A.K. Valdo, F.T. Martins, R. Rabelo, N. Moliner, J. Cano, M. Julve, F. Lloret, D. Cangussu, J. Braz. Chem. Soc. 30(11), 2413 (2019)
C. Gatti, G. Macetti, L.L. Presti, Acta. Cryst. B73, 565 (2017)
D.J.R. Brook, C. Fleming, D. Chung, C. Richardson, S. Ponce, R. Das, H. Srikanth, R. Heindl, B.C. Noll, Dalton Trans. 47, 6351 (2018)
J.R. Kumpfer, S.J. Rowan, J. Am. Chem. Soc. 133, 12866 (2011)
M.B. Zakaria, A.A. Belik, T. Nagata, T. Takei, S. Tominaka, T. Chikyow, J. Mag. Mag. Mater. 486, 165276 (2019)
P. Borys, Z.J. Grzywna, J. Memb. Sci. 445, 107 (2013)
A. Sohail, M. Fatima, R. Ellahi, K.B. Akram, J. Molecular Liquids 285, 47 (2019)
Acknowledgements
The financial support from the Jordan University of Science and Technology is deeply appreciated (Grant No. 116/2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Arafa, I.M., Shatnawi, M.Y. & Al-Equr, R.M. Electrical, and Magnetic Characteristics of Homo- and Hetero-Bimetallic Macromolecular Complexes with π-Conjugated Imine-oxime Backbone. J Inorg Organomet Polym 31, 1323–1335 (2021). https://doi.org/10.1007/s10904-020-01805-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-020-01805-1