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Batch and continuous fixed-bed column biosorption of thorium(IV) from aqueous solutions: equilibrium and dynamic modeling

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Abstract

Biosorption of thorium(IV) from aqueous solution by Cystoseira indica alga was investigated in batch and fixed-bed column experiments. In the batch study the effects of pH and initial concentration were investigated. The optimum pH for Th(IV) biosorption was found to be 3.5. The experimental isotherms obtained at different pH conditions were analyzed using three two-parameter models and three three-parameter models. Among the two-parameter models the Langmuir model and among the three-parameter models the Redlich–Peterson model vividly described the equilibrium data. The results showed that C. indica alga is a homogeneous biosorbent and Th(IV) biosorption is a favorable and physical process. The maximum biosorption capacity from the Langmuir model was 151.3, 195.7 and 120.6 mg/g at pH 2.5, 3.5 and 4.5, respectively. The continuous isotherm obtained from the column data was modeled by the Langmuir model and the maximum biosorption capacity was 283.8 mg/g. The experimental data were fitted by the use of an analytical and a numerical model, namely Clark and mass transfer models. The results showed that the mass transfer model adequately described the experimental data. Sensitivity analysis revealed that the value of k in has more effect than the axial dispersion coefficient (D z) on the shape of breakthrough curve.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran

    Masoud Riazi & Mohammad Ali Moosavian

  2. Nuclear Fuel Cycle School, Nuclear Science and Technology Research Institute, Tehran, Iran

    Ali Reza Keshtkar

Authors
  1. Masoud Riazi
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  2. Ali Reza Keshtkar
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  3. Mohammad Ali Moosavian
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Correspondence to Ali Reza Keshtkar.

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Riazi, M., Keshtkar, A.R. & Moosavian, M.A. Batch and continuous fixed-bed column biosorption of thorium(IV) from aqueous solutions: equilibrium and dynamic modeling. J Radioanal Nucl Chem 301, 493–503 (2014). https://doi.org/10.1007/s10967-014-3129-7

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  • DOI: https://doi.org/10.1007/s10967-014-3129-7

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