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Chromatographic separation of americium from europium using bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine

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Abstract

The separation of americium(III) from europium(III) was achieved utilizing a bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP) chromatographic resin. The extraction chromatographic materials were prepared using various concentrations of CA-BTP. This new, hydrolytically stable extractant was impregnated on an inert polymeric support at 40% loading. The uptake of Am(III) and Eu(III) by this material from 0.1 to 4.0 M aqueous HNO3 solutions was measured. The resulting dry weight distribution ratios, D w , indicated a strong preference for Am(III) with little affinity for Eu(III). These results are similar to recently reported solvent extraction studies indicating a maximum uptake of Am(III) in the 0.5–1.0 M HNO3 range. The resin preparation, performance, and characterization of the Am/Eu separation are reported herein.

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References

  1. Mathur J, Murali M, Nash K (2001) Actinide partitioning—a review. Solvent Extr Ion Exch 19:357–390

    Article  CAS  Google Scholar 

  2. Nash K, Madic C, Mathur J, Lacquement J (2007) Actinide separation science and technology. In: Bond AH, Dietz ML, Rogers RD (eds) The chemistry of the actinide and the transactinide elements, vol 4. Springer, Dordrecht, pp 2622–2798

    Google Scholar 

  3. Strategy for the management and disposal of used nuclear fuel and high-level radioactive waste. Department of Energy. January 2013

  4. Magill J, Berthou V, Haas D, Galy J, Schenkel R, Wiese H-W, Heusener G, Thommasi J, Youinou G (2003) Impact limits of partitioning and transmutation scenarios on the radiotoxicity of actinides in radioactive waste. Nucl Energy 42:263–277

    CAS  Google Scholar 

  5. Mayer K, Wallenius M, Ray I (2005) Nuclear forensics—a methodology providing clues on the origin of illicitly trafficked nuclear materials. Analyst 130:433–441

    Article  CAS  Google Scholar 

  6. Panak P, Geist A (2013) Complexation and extraction of trivalent actinides by triazinylpyridine N-donor ligands. Chem Rev 113:1199–1236

    Article  CAS  Google Scholar 

  7. Musikas C, Le Marois G, Fitoussi R, Cuillerdier C (1980) Properties and uses of nitrogen and sulfur donors ligands in actinide separations. ACS Symposium Series. American Chemical Society, Washington, DC

    Book  Google Scholar 

  8. Kurosaki H, Clark SB (2011) Chromatographic separation of Am and Cm. Radiochim Acta 99:65–69

    Article  CAS  Google Scholar 

  9. Kolarik Z, Müllich U, Gassner F (1999) Selective extraction of Am(III) over Eu(III) by 2,6-ditriazolyl- and 2,6-ditriazinylpyridines. Solvent Extr Ion Exch 17:23–32

    Article  CAS  Google Scholar 

  10. Kolarik Z, Müllich U, Gassner F (1999) Extraction of Am(III) and Eu(III) nitrates by 2-6-di-(5,6-dipropyl-1,2,4-triazin-3-yl)pyridines. Solvent Extr Ion Exch 17:1155–1170

    Article  CAS  Google Scholar 

  11. Muraview D, Ghantous L, Valiente M (1998) Stabilization of solvent-impregnated resin capacities by different techniques. React Funct Polym 38:259–268

    Article  Google Scholar 

  12. Tevepaugh K, Carrick J, Tai S, Coonce JG, Delmau LH, Ensor DD (2016) Separation of americium from europium using camphor-bistriazinyl pyridine: a fundamental study. Solvent Extr Ion Exch 34(1):13–25

    Article  CAS  Google Scholar 

  13. Wei Y-Z, Hoshi H, Kumagai M, Asakura T, Morita Y (2004) Separation of Am(III) and Cm(III) from trivalent lanthanides by 2,6-bistriazinylpyridine extraction chromatography for radioactive waste management. J Alloys Compd 374:447–450

    Article  CAS  Google Scholar 

  14. Deepika P, Sabharwal KN, Srinivasan TG, Vasudeva Rao PR (2012) Studies on separation of minor actinides from lanthanides from high level waste by extraction chromatography using 2,6-bistriazinylpyridine. Nucl Technol 179:407–416

    Article  CAS  Google Scholar 

  15. Klug C, Sudowe R (2013) A novel extraction chromatography resin for trivalent actinides using 2,6-bis(5,6-diisobutyl-1,2,4-triazine-3-yl)pyridine. Sep Sci Technol 48(17):2567–2575

    Article  CAS  Google Scholar 

  16. Hill C, Guillaneux D, Berthon L, Madic CJ (2002) Sanex-BTP process development studies. Nucl Sci Technol 39(Suppl. 3):309–312

    Article  Google Scholar 

  17. Kolarik Z (2008) Complexation and separation of lanthanides(III) and actinides(III) by heterocyclic N-donors in solution. Chem Rev 108:4208–4252

    Article  CAS  Google Scholar 

  18. Hudson MJ, Boucher CE, Braekers D, Desreux JF, Drew MGB, Foreman MRS, Harwood LM, Hill C, Madic C, Marken F, Youngs TGA (2006) New bis(triazinyl) pyridines for selective extraction of americium(III). New J Chem 30:1171–1183

    Article  CAS  Google Scholar 

  19. Deepika P, Sabharwal KN, Srinivasan TG, Vasudeva Rao PR (2013) Studies on bis annulated triazinyl pyridine (BATP) using extraction chromatography. Sep Sci Technol 48(13):2020–2027

    Article  CAS  Google Scholar 

  20. Madic C, Testard F, Liljenzin J-O, Christiansen B, Ferrando M, Facchini A, Geist A, Modolo G, Espartero AG, De Mendoza J (2004) PARTNEW—new solvent extraction process for minor actinides; CEA-R-6066. Commissariat à l’Energie Atomique, Paris

    Google Scholar 

  21. Geist A, Hill C, Modolo G, Foreman MRS, Weigl M, Gompper K, Hudson MJ, Madic C (2006) 6,6’-Bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-benzo[1,2,4]triazin-3-yl)[2,2’]bipyridine, an effective extracting agent for the separation of americium(III) and curium(III) from the lanthanides. Solvent Extr Ion Exch 24:463–483

    Article  CAS  Google Scholar 

  22. Trumm S, Geist A, Panak P, Fanghänel T (2011) An improved hydrolytically-stable bis-triazinyl-pyridine (BTP) for selective actinide extraction. Solvent Extr Ion Exch 29:213–229

    Article  CAS  Google Scholar 

  23. Ning S, Zou Q, Wang X, Liu R, Wei Y, Zhao Y, Ding Y (2016) Evalution study on silica/polymer-based CA-BTP adsorbent for the separation of minor actinides from simulated high-level liquid wastes. J Radioanal Nucl Chem 307:993–999

    Article  CAS  Google Scholar 

  24. Horwitz EP, Dietz ML, Nelson DM, LaRosa JJ, Fairman WD (1990) Concentration and separation of actinides from urine using a supported bifunctional organophosphorus extractant. Anal Chim Acta 238:263–271

    Article  CAS  Google Scholar 

  25. Horwitz EP, Dietz ML, Fisher DE (1991) Separation and preconcentration of strontium from biological, environmental, and nuclear waste samples by extraction chromatography using a crown ether. Anal Chem 63:522–525

    Article  CAS  Google Scholar 

  26. Tai S, Williams NJ, Carrick JD (2016) Synthesis of bis-1,2,4-triazines via telescoped condensation of [1,10]-phenanthroline-2,9-dicarbonitrile with aromatic 1,2-dicarbonyls. J Heterocycl Chem 53:307–312

    Article  CAS  Google Scholar 

  27. Hill TG, Chin AL, Tai S, Carrick JD, Ensor D, Delmau LH (2017) Separation of americium from europium using 3,3′-dimethoxy-phenyl-bis-1,2,4-triazinyl-2,6-pyridine. Sep Sci Technol. doi:10.1080/01496395.2017.1304419

    Google Scholar 

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Acknowledgements

This research was sponsored by the Office of Nuclear Energy, U.S. Department of Energy. One author (K.T.) would like to thank the Tennessee Technological University Student Research Grant Program for support. Thank you to Melissa Friedrich for her helpful edits.

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Authors and Affiliations

  1. Department of Chemistry, Tennessee Technological University, 1 William L Jones Dr, Cookeville, TN, 38505, USA

    Kayron N. Tevepaugh, Janet Coonce, Serene Tai, Jesse D. Carrick & Dale D. Ensor

  2. Chemical Separations Group, Oak Ridge National Laboratory, 1 Bethel Valley Rd, Oak Ridge, TN, 37830, USA

    Kayron N. Tevepaugh & Lætitia H. Delmau

Authors
  1. Kayron N. Tevepaugh
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  2. Janet Coonce
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  3. Serene Tai
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  4. Lætitia H. Delmau
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  5. Jesse D. Carrick
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  6. Dale D. Ensor
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Correspondence to Kayron N. Tevepaugh.

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Tevepaugh, K.N., Coonce, J., Tai, S. et al. Chromatographic separation of americium from europium using bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine. J Radioanal Nucl Chem 314, 371–376 (2017). https://doi.org/10.1007/s10967-017-5365-0

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  • DOI: https://doi.org/10.1007/s10967-017-5365-0

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