We investigate the atomic structure of tin-based solders by X-ray diffraction methods and the reverse Monte Carlo method. Total and partial structural factors and pair correlation functions are calculated. It is shown that Sn0.987Cu0.013 , Sn0.962Ag0.038 , and Sn0.949Ag0.038Cu0.013 liquid alloys are characterized by a microinhomogeneous structure with Cu(Ag)–Sn clusters distributed in the tin-based matrix.
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P. P. Arsent’ev and L. A. Koledov, Metallic Melts and Their Properties [in Russian], Metallurgiya, Moscow (1976).
P. S. Popel, M. Calvo-Dahlborg, and U. Dahlborg, “Metastable microheterogeneity of melts in eutectic and monotectic systems and its influence on the properties of the solidified alloy,” J. Non-Crystal. Solids., 353, 3243–3253 (2007).
I. Kaban, W. Hoyer, A. Il’inskii, et al., “Short range order in liquid silver–tin alloys,” J. Non-Crystal. Solids., 331, 254–262 (2007).
S. Gruner, I. Kaban, R. Kleinhempel, et al., “Short-range order and atomic clusters in liquid Cu–Sn alloys,” Non-Crystal. Solids., 351, 3490–3496 (2005).
R. L. McGreevy and L. Pusztai, “Reverse Monte Carlo simulation: a new technique for the determination of disordered structures,” Mol. Simul., No. 1, 359–367 (1988).
J. M. Ziman, “A theory of the electric properties of liquid metals. I: The monovalent metals,” Philos. Mag., 6, 1013–1034 (1961).
D. M. Kheiker and L. S. Zevin, X-ray Diffractometry [in Russian], Fizmatgiz (1963).
D. T. Cromer and J. T. Waber, “Scattering factors computed from relativistic Dirac–Slater wave function,” Acta Cryst., 18, 104–109 (1965).
J. Krogh-Moe, “A method for converting experimental X-ray intensities to an absolute scale,” Acta Cryst., 9, 951–953 (1965).
Yu. Plevachuk and V. Sklyarchuk, “Electrophysical measurements for strongly aggressive liquid semiconductors,” Meas. Sci. Technol., 12, 23–26 (2001).
R. L. McGreevy, M. A. Howe, D. A. Keen, and K. N. Clausen, “Reverse Monte Carlo (RMC) simulation: modeling structural disorder in crystals, glasses and liquids from diffraction data,” IOP Conf. Ser., 107,165–184 (1990).
N. W. Ashcroft, “Electron–ion pseudopotentials in metals,” Phys. Lett., 23, 48–50 (1966).
J. G. Gasser, J. L. Bretonnet, and A. Bruson, “Temperature dependence of the liquid tin resistivity,” Phys. Status Solidi (b), 128, 789–796 (1985).
A. M. Vora, “Electric transport properties of some liquid metals,” High Temperat., 46, 800–810 (2008).
A. M. Vora, “Electric transport properties of some liquid metals,” Phys. Chem. Liquids, 46, 442–453 (2008).
P. Vashishta and K. S. Singwi, “Electron correlations at metallic densities,” Phys. Rev. B., 6, 875–887 (1972).
Z. Moser, W. Gasior, and J. Pstrus, “Surface tension of liquid Ag-Sn alloys: experiment versus modeling,” J. Phase Equil., 22, 254–258 (2001).
Z. Moser, W. Gasior, K. Bukat, et al. “Pb-free solders: Part1. Wettability testing of Sn–Ag–Cu alloys with Bi additions,” J. Phase Equil. Diffus., 27, 113–139 (2006).
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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 46, No. 4, pp. 35–41, July–August, 2010.
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Mudryi, S.I., Shtablavyi, I.I., Sklyarchuk, V.M. et al. Structure and electric resistance of Sn–Cu(Ag) solders in the precrystallization temperature range. Mater Sci 46, 464–472 (2011). https://doi.org/10.1007/s11003-011-9313-9
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DOI: https://doi.org/10.1007/s11003-011-9313-9