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Phosphonic acids aid composition adjustment in the synthesis of Cu2+x Zn1−x SnSe4−y nanoparticles

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Abstract

The functional properties of quaternary I2–II–IV–VI4 nanomaterials, with potential interest in various technological fields, are highly sensitive to compositional variations, which is a challenging parameter to adjust. Here we demonstrate the presence of phosphonic acids to aid controlling the reactivity of the II element monomer to be incorporated in quaternary Cu2ZnSnSe4 nanoparticles and thus to provide a more reliable way to adjust the final nanoparticle metal ratios. Furthermore, we demonstrate the composition control in such multivalence nanoparticles to allow modifying charge carrier concentrations in nanomaterials produced from the assembly of these building blocks.

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Acknowledgments

At IREC, work was supported by European Regional Development Funds and the Framework 7 program under project UNION (FP7-NMP 310250). M.I. Thanks AGAUR for her Beatriu i Pinós post-doctoral Grant.

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Authors and Affiliations

  1. Catalonia Institute for Energy Research (IREC), Sant Adrià de Besós, 08930, Barcelona, Spain

    Maria Ibáñez, Taisiia Berestok, Oleksandr Dobrozhan, Victor Izquierdo-Roca, Alexey Shavel, Alejandro Pérez-Rodríguez & Andreu Cabot

  2. Materials Science, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA, 91125, USA

    Aaron LaLonde & G. Jeffrey Snyder

  3. Departament d’Electrònica, IN2UB, Universitat de Barcelona, C. Martí i Franquès 1, 08028, Barcelona, Spain

    Alejandro Pérez-Rodríguez

  4. Materials Science and Engineering, Northwestern University, Evanston, USA

    G. Jeffrey Snyder

  5. Institució Catalana de Recerca i Estudis Avançats (ICREA), Pg. Lluís Companys 23, 08010, Barcelona, Spain

    Andreu Cabot

Authors
  1. Maria Ibáñez
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  2. Taisiia Berestok
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  7. Alejandro Pérez-Rodríguez
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  8. G. Jeffrey Snyder
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  9. Andreu Cabot
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Correspondence to Andreu Cabot.

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Ibáñez, M., Berestok, T., Dobrozhan, O. et al. Phosphonic acids aid composition adjustment in the synthesis of Cu2+x Zn1−x SnSe4−y nanoparticles. J Nanopart Res 18, 226 (2016). https://doi.org/10.1007/s11051-016-3545-4

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  • DOI: https://doi.org/10.1007/s11051-016-3545-4

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