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Synthesis of Schiff bases and benzylamino derivatives containing [1-B10H9NH3]− anion

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Abstract

Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]− with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr]− (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corresponding benzylamino derivatives [1-B10H9NH2CH2Ar]−.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. B. Sivaev, V. I. Bragin & V. I. Bregadze

  2. M. V. Lomonosov Moscow Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 117571, Moscow, Russian Federation

    V. I. Bragin & N. A. Votinova

  3. Department of Chemistry, Organic Chemistry, Uppsala University, P.O. Box 599, Uppsala, S-75124, Sweden

    S. Sjoberg

Authors
  1. I. B. Sivaev
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  2. V. I. Bragin
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  3. V. I. Bregadze
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  4. N. A. Votinova
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  5. S. Sjoberg
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2004–2007, September, 2004.

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Sivaev, I.B., Bragin, V.I., Bregadze, V.I. et al. Synthesis of Schiff bases and benzylamino derivatives containing [1-B10H9NH3]− anion. Russ Chem Bull 53, 2092–2095 (2004). https://doi.org/10.1007/s11172-005-0079-9

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  • DOI: https://doi.org/10.1007/s11172-005-0079-9

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