Skip to main content
SpringerLink
Log in

Co-Fe/Al2O3 Nanocomposite Catalysts of the Process of CO2 Hydrogenation

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Effective catalysts of CO2 hydrogenation towards methane were obtained by impregnation of aluminum oxide with cobalt and iron nitrates. The catalysts have been characterized by XRD, SEM-EDX, argon physisorption, and TPD with mass-spectroscopy analysis. It is shown that an increase in the amount of applied Co-Fe active mass in the composition of a nanocomposite catalyst leads to an increase in the CO2 conversion and CH4 yield.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

References

  1. C. Vogt, M.Monai, G. J. Kramer, and B. M. Weckhuysen, Nat. Catal., 2, 188-197 (2019).

    Article  CAS  Google Scholar 

  2. S. Ronsch, J. Schneider, S. Matthischke, et al., Fuel, 166, 276-296 (2016).

    Article  Google Scholar 

  3. A. Malara, P. Frontera, P. Antonucci, and A. Macario, Curr. Opin. Green Sustain. Chem., 26, 100376 (2020).

  4. D. Beierlein, D. Haussermann, M. Pfeifer, et al., Appl. Catal. B., 247, 200-219 (2019).

    Article  CAS  Google Scholar 

  5. O. V. Ishchenko, A. G. Dyachenko, A. V. Yatsymyrskiy, et al., E3S Web Conf., 154, 02001 (2020).

    Article  CAS  Google Scholar 

  6. M. A. A. Aziz, A. A. Jalil, S. Triwahyono, and A. Ahmad, Green Chem., 17, 2647-2663 (2015).

    Article  CAS  Google Scholar 

  7. A. G. Dyachenko, O. V. Ischenko, O. V. Goncharuk, et al., Appl. Nanosci., 12, No. 3, 349-359 (2022).

    Article  CAS  Google Scholar 

  8. W. Chaitree, S. Jiemsirilers, and O. Mekasuwandumrong, Catal. Today, 164, No. 1, 302-307 (2011).

    Article  CAS  Google Scholar 

  9. T. Das and G. Deo, J. Phys. Chem. C., 116, No. 39, 20812-20819 (2012).

    Article  CAS  Google Scholar 

  10. O. V. Ischenko, A. G. Dyachenko, I. Saldan, et al., Int. J. Hydrog. Energy, 46, 37860-37871 (2021).

    Article  CAS  Google Scholar 

  11. M. Zhludenko, A. Dyachenko, O. Bieda, et al., Acta Phys. Pol. A., 133, 1084-1087 (2018).

    Article  CAS  Google Scholar 

  12. A. S. Sandupatla, A. Banerjee, and G. Deo, Appl. Surf. Sci., 485, 441-449 (2019).

    Article  CAS  Google Scholar 

  13. S. Hwang, U. G. Hong, J. Lee, et al., Catal. Lett., 142, 860-868 (2012).

    Article  CAS  Google Scholar 

  14. Y. Zhan, Y. Wang, D. Gu, et al., Appl. Surf. Sci., 459, 74-79 (2018).

    Article  CAS  Google Scholar 

  15. N. Srisawad, W. Chaitree, and O. Mekasuwandumrong, React. Kinet. Mech. Catal., 107, No. 1, 179-188 (2012).

    Article  CAS  Google Scholar 

  16. R. J. Cvetanovic and Y. A. Amenomiya, Catal. Rev., 6, No. 1, 21-48 (1972).

    Article  CAS  Google Scholar 

  17. M. W. Roberts and C. S. McKee, Chemistry of the Metal-Gas Interface, Oxford, Oxford University Press (1979).

    Google Scholar 

  18. A. G. Dyachenko, O. V. Ischenko, M. G. Zhludenko, et al., Bul. Chem. Com., 52, No. 3, 342-347 (2020).

    Google Scholar 

  19. B. Miao, S. Ma, X. Wang, et al., Catal. Sci. Technol., 6, 4048-4058 (2016).

Download references

Author information

Authors and Affiliations

  1. Taras Shevchenko Kyiv National University, Kyiv, Ukraine

    A. G. Dyachenko, O. V. Ischenko, S. V. Gaidai, A. V. Yatsymyrskyi, G. G. Tsapyuk & O. V. Pryhunova

  2. O. O. Chuiko Institute of Surface Chemistry, NAS of Ukraine, Kyiv, Ukraine

    A. G. Dyachenko & M. V. Borysenko

  3. O. O. Bogomolets National Medical University, Kyiv, Ukraine

    O. O. Kostyrko

  4. Institute of Physical Chemistry of Polish Academy of Sciences, Warsaw, Poland

    A. G. Dyachenko

Authors
  1. A. G. Dyachenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Ischenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Borysenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. V. Gaidai
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Yatsymyrskyi
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. G. Tsapyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. O. V. Pryhunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. O. O. Kostyrko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. G. Dyachenko.

Additional information

Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 58, No. 2, pp. 119-125, March-April, 2022.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dyachenko, A.G., Ischenko, O.V., Borysenko, M.V. et al. Co-Fe/Al2O3 Nanocomposite Catalysts of the Process of CO2 Hydrogenation. Theor Exp Chem 58, 134–142 (2022). https://doi.org/10.1007/s11237-022-09731-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11237-022-09731-8

Keywords

Search

Navigation