Effective catalysts of CO2 hydrogenation towards methane were obtained by impregnation of aluminum oxide with cobalt and iron nitrates. The catalysts have been characterized by XRD, SEM-EDX, argon physisorption, and TPD with mass-spectroscopy analysis. It is shown that an increase in the amount of applied Co-Fe active mass in the composition of a nanocomposite catalyst leads to an increase in the CO2 conversion and CH4 yield.
Similar content being viewed by others
References
C. Vogt, M.Monai, G. J. Kramer, and B. M. Weckhuysen, Nat. Catal., 2, 188-197 (2019).
S. Ronsch, J. Schneider, S. Matthischke, et al., Fuel, 166, 276-296 (2016).
A. Malara, P. Frontera, P. Antonucci, and A. Macario, Curr. Opin. Green Sustain. Chem., 26, 100376 (2020).
D. Beierlein, D. Haussermann, M. Pfeifer, et al., Appl. Catal. B., 247, 200-219 (2019).
O. V. Ishchenko, A. G. Dyachenko, A. V. Yatsymyrskiy, et al., E3S Web Conf., 154, 02001 (2020).
M. A. A. Aziz, A. A. Jalil, S. Triwahyono, and A. Ahmad, Green Chem., 17, 2647-2663 (2015).
A. G. Dyachenko, O. V. Ischenko, O. V. Goncharuk, et al., Appl. Nanosci., 12, No. 3, 349-359 (2022).
W. Chaitree, S. Jiemsirilers, and O. Mekasuwandumrong, Catal. Today, 164, No. 1, 302-307 (2011).
T. Das and G. Deo, J. Phys. Chem. C., 116, No. 39, 20812-20819 (2012).
O. V. Ischenko, A. G. Dyachenko, I. Saldan, et al., Int. J. Hydrog. Energy, 46, 37860-37871 (2021).
M. Zhludenko, A. Dyachenko, O. Bieda, et al., Acta Phys. Pol. A., 133, 1084-1087 (2018).
A. S. Sandupatla, A. Banerjee, and G. Deo, Appl. Surf. Sci., 485, 441-449 (2019).
S. Hwang, U. G. Hong, J. Lee, et al., Catal. Lett., 142, 860-868 (2012).
Y. Zhan, Y. Wang, D. Gu, et al., Appl. Surf. Sci., 459, 74-79 (2018).
N. Srisawad, W. Chaitree, and O. Mekasuwandumrong, React. Kinet. Mech. Catal., 107, No. 1, 179-188 (2012).
R. J. Cvetanovic and Y. A. Amenomiya, Catal. Rev., 6, No. 1, 21-48 (1972).
M. W. Roberts and C. S. McKee, Chemistry of the Metal-Gas Interface, Oxford, Oxford University Press (1979).
A. G. Dyachenko, O. V. Ischenko, M. G. Zhludenko, et al., Bul. Chem. Com., 52, No. 3, 342-347 (2020).
B. Miao, S. Ma, X. Wang, et al., Catal. Sci. Technol., 6, 4048-4058 (2016).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 58, No. 2, pp. 119-125, March-April, 2022.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Dyachenko, A.G., Ischenko, O.V., Borysenko, M.V. et al. Co-Fe/Al2O3 Nanocomposite Catalysts of the Process of CO2 Hydrogenation. Theor Exp Chem 58, 134–142 (2022). https://doi.org/10.1007/s11237-022-09731-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11237-022-09731-8