Abstract
We investigate anomalous dispersion in steady-state two-phase flow though a random, artificial porous domain. A natural distribution of trapped wetting-phase fluid was obtained via two-phase lattice Boltzmann drainage simulations. To avoid spurious velocities, accurate inter-pore velocity fields were derived via additional one-phase lattice Boltzmann simulations incorporating slip boundary conditions imposed at various interfaces. The nature of the active dispersion at various timescales was subsequently studied via random walk particle tracking. For our system, results show persistent anomalous dispersion that depends strongly on the assumed molecular diffusivity and the initial positions of tracer particles. Imposing slip versus no-slip boundary conditions on fluid–fluid interfaces made no observable difference to results, indicating that observed anomalous dispersion resulted primarily from the complex flow network induced by the trapped fluid phase.
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Bachu, S.: Sequestration of \(\text{ CO }_2\) in geological media: criteria and approach for site selection in response to climate change. Energy Convers. Manag. 41(9), 953–970 (2000)
Berglund, S., Bosson, E., Selroos, J.O., Sassner, M.: Identification and characterization of potential discharge areas for radionuclide transport by groundwater from a nuclear waste repository in Sweden. Ambio 42(4), 435–446 (2013)
Berkowitz, B., Cortis, A., Dentz, M., Scher, H.: Modeling non-Fickian transport in geological formations as a continuous time random walk. Rev. Geophys. 44(2) (2006). https://doi.org/10.1029/2005RG000178
Berning, T., Djilali, N.: A 3D, multiphase, multicomponent model of the cathode and anode of a PEM fuel cell. J. Electrochem. Soc. 150(12), A1589–A1598 (2003)
Bijeljic, B., Blunt, M.J.: Pore-scale modeling and continuous time random walk analysis of dispersion in porous media. Water Resour. Res. (2006). https://doi.org/10.1029/2005WR004578
Bijeljic, B., Mostaghimi, P., Blunt, M.J.: Insights into non-Fickian solute transport in carbonates. Water Resour. Res. 49(5), 2714–2728 (2013a)
Bijeljic, B., Raeini, A., Mostaghimi, P., Blunt, M.J.: Predictions of non-Fickian solute transport in different classes of porous media using direct simulation on pore-scale images. Phys. Rev. E 87(1), 013011 (2013b)
Bolster, D., Valdés-Parada, F.J., LeBorgne, T., Dentz, M., Carrera, J.: Mixing in confined stratified aquifers. J. Contam. Hydrol. 120, 198–212 (2011)
Bolster, D., Méheust, Y., Le Borgne, T., Bouquain, J., Davy, P.: Modeling preasymptotic transport in flows with significant inertial and trapping effects-the importance of velocity correlations and a spatial Markov model. Adv. Water Resour. 70, 89–103 (2014)
Bouwer, H.: Artificial recharge of groundwater: hydrogeology and engineering. Hydrogeol. J. 10(1), 121–142 (2002)
Brenner, H.: Macrotransport Processes. Elsevier, New York (2013)
Bromly, M., Hinz, C.: Non-Fickian transport in homogeneous unsaturated repacked sand. Water Resour. Res. (2004). https://doi.org/10.1029/2003WR002579
Chen, S., Doolen, G.D.: Lattice Boltzmann method for fluid flows. Annu. Rev. Fluid Mech. 30(1), 329–364 (1998)
Connington, K., Lee, T.: A review of spurious currents in the lattice Boltzmann method for multiphase flows. J. Mech. Sci. Technol. 26(12), 3857–3863 (2012)
Daly, E., Porporato, A.: A review of soil moisture dynamics: from rainfall infiltration to ecosystem response. Environ. Eng. Sci. 22(1), 9–24 (2005)
De Anna, P., Le Borgne, T., Dentz, M., Tartakovsky, A.M., Bolster, D., Davy, P.: Flow intermittency, dispersion, and correlated continuous time random walks in porous media. Phys. Rev. Lett. 110(18), 184502 (2013)
Dentz, M., Le Borgne, T., Englert, A., Bijeljic, B.: Mixing, spreading and reaction in heterogeneous media: a brief review. J. Contam. Hydrol. 120, 1–17 (2011)
Dentz, M., Kang, P.K., Comolli, A., Le Borgne, T., Lester, D.R.: Continuous time random walks for the evolution of Lagrangian velocities. Phys. Rev. Fluids 1(7), 074004 (2016)
de Barros, F.P., Bolster, D., Sanchez-Vila, X., Nowak, W.: A divide and conquer approach to cope with uncertainty, human health risk, and decision making in contaminant hydrology. Water Resour. Res. (2011). https://doi.org/10.1029/2010WR009954
de Barros, F., Fernàndez-Garcia, D., Bolster, D., Sanchez-Vila, X.: A risk-based probabilistic framework to estimate the endpoint of remediation: concentration rebound by rate-limited mass transfer. Water Resour. Res. 49(4), 1929–1942 (2013)
Fernández-Arévalo, T., Lizarralde, I., Grau, P., Ayesa, E.: New systematic methodology for incorporating dynamic heat transfer modelling in multi-phase biochemical reactors. Water Res. 60, 141–155 (2014)
Galliero, G.: Lennard-Jones fluid-fluid interfaces under shear. Phys. Rev. E (2010). https://doi.org/10.1103/PhysRevE.81.056306
Gómez-Hernández, J.J., Butler, J., Fiori, A., Bolster, D., Cvetkovic, V., Dagan, G., Hyndman, D.: Introduction to special section on modeling highly heterogeneous aquifers: lessons learned in the last 30 years from the MADE experiments and others. Water Resour. Res. 53(4), 2581–2584 (2017)
Guillon, V., Fleury, M., Bauer, D., Neel, M.C.: Superdispersion in homogeneous unsaturated porous media using NMR propagators. Phys. Rev. E 87(4), 043007 (2013)
Higdon, J.J.L.: Stokes flow in arbitrary two-dimensional domains: shear flow over ridges and cavities. J. Fluid Mech. 159, 195–226 (1985)
Hu, Y., Zhang, X., Wang, W.: Boundary conditions at the liquid-liquid interface in the presence of surfactants. Langmuir 26(13), 10693–10702 (2010)
Iglauer, S.: Dissolution trapping of carbon dioxide in reservoir formation brine—a carbon storage mechanism. In: Mass Transfer — Advanced Aspects, InTech, pp. 233–262 (2011)
Jiang, F., Tsuji, T.: Estimation of three-phase relative permeability by simulating fluid dynamics directly on rock-microstructure images. Water Resour. Res. 53(1), 11–32 (2017)
Jiang, F., Tsuji, T., Hu, C.: Elucidating the role of interfacial tension for hydrological properties of two-phase flow in natural sandstone by an improved lattice Boltzmann method. Transp. Porous Media 104(1), 205–229 (2014)
Jiménez-Martínez, J., Anna, Pd, Tabuteau, H., Turuban, R., Borgne, T.L., Méheust, Y.: Pore-scale mechanisms for the enhancement of mixing in unsaturated porous media and implications for chemical reactions. Geophys. Res. Lett. 42(13), 5316–5324 (2015)
Jiménez-Martínez, J., Porter, M.L., Hyman, J.D., Carey, J.W., Viswanathan, H.S.: Mixing in a three-phase system: enhanced production of oil-wet reservoirs by \(\text{ CO }_2\) injection. Geophys. Res. Lett. 43(1), 196–205 (2016)
Kang, P.K., Anna, P., Nunes, J.P., Bijeljic, B., Blunt, M.J., Juanes, R.: Pore-scale intermittent velocity structure underpinning anomalous transport through 3-D porous media. Geophys. Res. Lett. 41(17), 6184–6190 (2014)
Kazemifar, F., Blois, G., Kyritsis, D.C., Christensen, K.T.: Quantifying the flow dynamics of supercritical \(\text{ CO }_2\)-water displacement in a 2D porous micromodel using fluorescent microscopy and microscopic PIV. Adv. Water Resour. 95, 352–368 (2016)
Lake, L.W.: Enhanced Oil Recovery. Prentice Hall, Englewood Cliffs (1989)
Latva-Kokko, M., Rothman, D.H.: Static contact angle in lattice Boltzmann models of immiscible fluids. Phys. Rev. E 72, 046701 (2005). https://doi.org/10.1103/PhysRevE.72.046701
Le Borgne, T., Bolster, D., Dentz, M., Anna, P., Tartakovsky, A.: Effective pore-scale dispersion upscaling with a correlated continuous time random walk approach. Water Resour. Res. 47(12) (2011). https://doi.org/10.1029/2011WR010457
Leclaire, S., Reggio, M., Trépanier, J.Y.: Numerical evaluation of two recoloring operators for an immiscible two-phase flow lattice Boltzmann model. Appl. Math. Model. 36(5), 2237–2252 (2012)
Mercer, J.W., Cohen, R.M.: A review of immiscible fluids in the subsurface: properties, models, characterization and remediation. J. Contam. Hydrol. 6(2), 107–163 (1990)
Nützmann, G., Maciejewski, S., Joswig, K.: Estimation of water saturation dependence of dispersion in unsaturated porous media: experiments and modelling analysis. Adv. Water Res. 25(5), 565–576 (2002)
Pan, F., Acrivos, A.: Steady flows in rectangular cavities. J. Fluid Mech. 28(4), 643–655 (1967)
Qian, Y., d’Humières, D., Lallemand, P.: Lattice BGK models for Navier—Stokes equation. EPL (Euro. Lett.) 17(6), 479–484 (1992)
Ramstad, T., Idowu, N., Nardi, C., Øren, P.E.: Relative permeability calculations from two-phase flow simulations directly on digital images of porous rocks. Transp. Porous Media 94(2), 487–504 (2012)
Raoof, A., Hassanizadeh, S.: Saturation-dependent solute dispersivity in porous media: pore-scale processes. Water Resour. Res. 49(4), 1943–1951 (2013)
Risken, H.: Fokker–planck equation. In: The Fokker–Planck Equation, Springer, pp 63–95 (1996)
Sato, T., Tanahashi, H., Loáiciga, H.A.: Solute dispersion in a variably saturated sand. Water Resour. Res. (2003). https://doi.org/10.1029/2002WR001649
Schönecker, C., Hardt, S.: Longitudinal and transverse flow over a cavity containing a second immiscible fluid. J. Fluid Mech. 717, 376–394 (2013)
Schumer, R., Benson, D.A., Meerschaert, M.M., Baeumer, B.: Fractal mobile/immobile solute transport. Water Resour. Res. (2003). https://doi.org/10.1029/2003WR002141
Singh, S., Jiang, F., Tsuji, T.: Impact of the kinetic boundary condition on porous media flow in the lattice Boltzmann formulation. Phys. Rev. E 96, 013303 (2017). https://doi.org/10.1103/PhysRevE.96.013303
Singha, K., Day-Lewis, F.D., Lane, J.: Geoelectrical evidence of bicontinuum transport in groundwater. Geophys. Res. Lett. 34(12) (2007). https://doi.org/10.1029/2007GL030019
Sund, N., Bolster, D., Mattis, S., Dawson, C.: Pre-asymptotic transport upscaling in inertial and unsteady flows through porous media. Transp. Porous Media 109(2), 411–432 (2015)
Taylor, G.: Dispersion of soluble matter in solvent flowing slowly through a tube. Proc. R. Soc. Lond. A Math. Phys. Eng. Sci. 219(1137), 186–203 (1953)
Tölke, J.: Lattice Boltzmann simulations of binary fluid flow through porous media. Philos. Transact. R. Soc. Lond. A: Math. Phys. Eng. Sce 360(1792), 535–545 (2002)
Vanderborght, J., Vereecken, H.: Review of dispersivities for transport modeling in soils. Vadose Zone J. 6(1), 29–52 (2007)
Whitaker, S.: The Method of Volume Averaging, vol. 13. Springer, Berlin (2013)
Wildenschild, D., Jensen, K.H.: Laboratory investigations of effective flow behavior in unsaturated heterogeneous sands. Water Resour. Res. 35(1), 17–27 (1999)
Wood, B.D.: Inertial effects in dispersion in porous media. Water Resour. Res. (2007). https://doi.org/10.1029/2006WR005790
Zhang, Y., Benson, D.A.: Lagrangian simulation of multidimensional anomalous transport at the MADE site. Geophys. Res. Lett. (2008). https://doi.org/10.1029/2008GL033222
Acknowledgements
This research was made possible by a Kyushu University, International Institute for Carbon Neutral Energy Research (\(\hbox {I}^{2}\hbox {CNER}\)), Competitive Funding Initiative on Applied Math for Energy Project Grant. We would also like to express thanks for financial support via NSF Grants EAR-1351625, EAR-1446236 and CBET-1803989, as well as a JSPS Grant-in-Aid for Young Scientists (16K18331).
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Triadis, D., Jiang, F. & Bolster, D. Anomalous Dispersion in Pore-Scale Simulations of Two-Phase Flow. Transp Porous Med 126, 337–353 (2019). https://doi.org/10.1007/s11242-018-1155-6
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DOI: https://doi.org/10.1007/s11242-018-1155-6