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Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands

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Abstract

A novel polymeric complex, [Mn(phen)(pdc)]∞ (phen=1,10-phenanthroline, H2pdc=2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)]∞ is characteristic of an edge-sharing dinuclear MnII structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)(pdc)]∞ indicates antiferromagnetic coupling [J = −2.76(4) cm−1] between the adjacent paramagnetic MnII ions.

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Authors and Affiliations

  1. Department of Material Science and Engineering, Tsinghua University, Beijing, 100084, P.R. China

    You-Wei Yao, Hao-Xiang Lin, Xiao-Dan Sun, Hui-Zhong Kou, Qiang Cai & Heng-De Li

  2. Department of Physical Chemistry, University of Science & Technology Beijing, Beijing, 100083, P.R. China

    Ran-Bo Yu

  3. Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100080, P.R. China

    Dan Wang

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  1. You-Wei Yao
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  2. Hao-Xiang Lin
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Yao, YW., Lin, HX., Sun, XD. et al. Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands. Transition Met Chem 30, 294–298 (2005). https://doi.org/10.1007/s11243-004-4578-6

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  • DOI: https://doi.org/10.1007/s11243-004-4578-6

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