Abstract
The cooling rate-dependent modification effect of Mn on the formation of Fe-containing intermetallic phases during solidification of Al-Si-Mg secondary cast aluminum alloys [containing 0.5 to 1 pct Fe (All compositions are in wt pct unless otherwise stated.)] was investigated by CALculation of PHAse Diagrams (CALPHAD) modeling and solidification experiments. The critical Mn concentration required to prevent the formation of detrimental β-Al5FeSi was found to be dependent on both the alloy composition (particularly the Fe/Mn ratio) and the cooling rate. A map of Fe/Mn ratio vs cooling rate was created, to summarize the metallurgical conditions of Fe-rich intermetallic phase formation. By understanding such formation conditions, the microstructure of aluminum castings can be controlled to create low-cost secondary alloys with high Fe content.
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A.I. Taub and A.A. Luo: MRS Bull., 2015, vol. 40, pp. 1045–54.
J.G. Kaufman and E.L. Rooy: Aluminium Alloy Castings: Properties, Processes, and Applications, ASM International, Cleveland 2004.
M.E. Schlesinger: Aluminum Recycling, 2nd edn., CRC Press, Boca Raton, FL, 2013.
W.J. Joost: JOM, 2012, vol. 64, pp. 1032–8.
G. Gaustad, E. Olivetti, and R. Kirchain: Resour. Conserv. Recycl., 2012, vol. 58, pp. 79–87.
K. Nakajima, O. Takeda, T. Miki, K. Matsubae, S. Nakamura, and T. Nagasaka: Environ. Sci. Technol., 2010, vol. 44, pp. 5594–600.
A. Couture: AFS Int. Cast Met. J., 1981, vol. 6, pp. 9–17.
P.N. Crepeau: Trans. Am. Foundrymen’s Soc., 1995, vol. 103, pp. 361–6.
J.A. Taylor: Procedia Mater. Sci., 2012, vol. 1, pp. 19–33.
S. Terzi, J.A. Taylor, Y.H. Cho, L. Salvo, M. Suéry, E. Boller, and A.K. Dahle: Acta Mater., 2010, vol. 58, pp. 5370–80.
C.M. Dinnis, J.A. Taylor, and A.K. Dahle: Scr. Mater., 2005, vol. 53, pp. 955–8.
C. Puncreobutr, A.B. Phillion, J.L. Fife, P. Rockett, A.P. Horsfield, and P.D. Lee: Acta Mater., 2014, vol. 79, pp. 292–303.
S. Seifeddine, S. Johansson, and I.L. Svensson: Mater. Sci. Eng. A, 2008, vol. 490, pp. 385–90.
J.Y. Hwang, H.W. Doty, and M.J. Kaufman: Mater. Sci. Eng. A, 2008, vol. 488, pp. 496–504.
D. Bösch, S. Pogatscher, M. Hummel, W. Fragner, P. Uggowitzer, M. Göken, and H. Höppel: Metall. Mater. Trans. A, 2015, vol. 46, pp. 1035–45.
A. Gorny, J. Manickaraj, Z. Cai, and S. Shankar: J. Alloys Compd., 2013, vol. 577, pp. 103–24.
Y. Awano and Y. Shimizu: AFS Trans., 1990, vol. 98, pp. 889–95.
M. V Kral: Mater. Lett., 2005, vol. 59, pp. 2271–6.
L.A. Narayanan, F.H. Samuel, and J.E. Gruzleski: Metall. Mater. Trans. A, 1994, vol. 25, pp. 1761–73.
C.M. Dinnis, J.A. Taylor, and A.K. Dahle: Metall. Mater. Trans. A, 2006, vol. 37, pp. 3283–91.
S.G. Shabestari: Mater. Sci. Eng. A, 2004, vol. 383, pp. 289–98.
K. Liu, X. Cao, and X.G. Chen: Metall. Mater. Trans. B, 2012, vol. 43, pp. 1231–40.
S. Ji, W. Yang, F. Gao, D. Watson, and Z. Fan: Mater. Sci. Eng. A, 2013, vol. 564, pp. 130–9.
R. Schmid-Fetzer and F. Zhang: Calphad, 2018, vol. 61, pp. 246–63.
X. Cao and J. Campbell: Metall. Mater. Trans. A, 2004, vol. 35, pp. 1425–35.
N. Isono, P. Smith, D. Turnbull, and M.J. Aziz: Metall. Mater. Trans. A, 1996, vol. 27, pp. 725–30.
Acknowledgments
The authors would like to acknowledge the National Science Foundation for supporting this work (Award CMMI-1432688). Dr. Yeou-Li Chu and Mr. Patrick Cheng of Ryobi Die Casting are also acknowledged for helpful discussions.
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Manuscript submitted June 21, 2019.
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Cinkilic, E., Ridgeway, C.D., Yan, X. et al. A Formation Map of Iron-Containing Intermetallic Phases in Recycled Cast Aluminum Alloys. Metall Mater Trans A 50, 5945–5956 (2019). https://doi.org/10.1007/s11661-019-05469-6
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DOI: https://doi.org/10.1007/s11661-019-05469-6