Abstract
The work presented in this paper investigates the effects of gamma radiation on ABS in forms of irradiated 3D-printed parts, and irradiated filament used to later 3D-printed parts, using a cobalt-60 gamma irradiator. Tensile and flexural test samples were fabricated using off-the-shelf FDM 3D printers and irradiated at different dosages. Mechanical properties including elastic and flexure moduli, ultimate and flexural strength, % elongation at break, and surface hardness were evaluated, and results were compared to a control group. Evidence of cross-linking and chain scission and signs of possible oxidation of polymer caused by irradiation were found in both test groups which led to changes in mechanical properties. Moreover, it was found that ABS filament retains its printability after absorbing 15 kGy of gamma radiation and that its mechanical performance is very similar to those of irradiated samples at the same dose. Obtained results show promise for using ABS to fabricate sterile surgical instruments.
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I. Gibson, D. Rosen, and B. Stucker, Additive Manufacturing Technologies: 3D Printing, Rapid Prototyping and Direct Digital Manufacturing, 2nd ed., Springer, Boston, MA, 2015, p 1–2
ASTM International, F2792-12a—Standard Terminology for Additive Manufacturing Technologies, Rapid Manuf. Assoc., 2013, https://doi.org/10.1520/f2792-12a.2
V. Petrovic, J. Vicente Haro Gonzalez, O. Jordá Ferrando, J. Delgado Gordillo, J. Ramón Blasco Puchades, and L. Portolés Griñan, Additive Layered Manufacturing: Sectors of Industrial Application Shown through Case Studies, Int. J. Prod. Res., 2011, 49(4), p 1061–1079
S. Lochner, J. Huissoon, and S. Bedi, Parametric Design of Custom Foot Orthotic Model, Comput. Des., 2012, https://doi.org/10.3722/cadaps.2012.1-11
N. Guo and M.C. Leu, Additive Manufacturing: Technology, Applications and Research Needs, Front. Mech. Eng., 2013, 8, p 215–243
M. Vaezi, H. Seitz, and S. Yang, A Review on 3D Micro-Additive Manufacturing Technologies, Int. J. Adv. Manuf. Technol., 2013, 67, p 1721–1754
O. Ivanova, C. Williams, and T. Campbell, Additive Manufacturing (AM) and Nanotechnology: Promises and Challenges, Rapid Prototyp. J., 2011, 19(5), p 353–364. https://doi.org/10.1108/rpj-12-2011-0127
M.P. Snyder, J.J. Dunn, and E.G. Gonzalez, Effects of Microgravity on Extrusion Based Additive Manufacturing, AIAA SPACE 2013 Conference and Exposition, 2013, p 1–6, https://doi.org/10.2514/6.2013-5439
J.J. Dunn, D.N. Hutchison, A.M. Kemmer, A.Z. Ellsworth, M. Snyder, W.B. White, and B.R. Blair, 3D Printing in Space: Enabling New Markets and Accelerating the Growth of Orbital Infrastructure, Space Manufacturing 14: Critical Technologies for Space Settlement, 2010, p 29–31
A. Owens, S. Do, A. Kurtz, and O. Weck, Benefits of Additive Manufacturing for Human Exploration of Mars, 2015, https://ttu-ir.tdl.org/ttu-ir/handle/2346/64526. Accessed 24 Aug 2016
R. Hoyt, J. Cushing, J. Slostad, and G. Jimmerson, SpiderFab: An Architecture for Self-Fabricating Space Systems, Am. Inst. Aeronaut., 2013, https://doi.org/10.2514/6.2013-5509
T. McGuire, M. Hirsch, and M. Parsons, Design for an in-Space 3D Printer, SPIE Defense+, 2016. http://proceedings.spiedigitallibrary.org/proceeding.aspx?articleid=2523840. Accessed 24 Aug 2016
D.W. Hutmacher, Scaffolds in Tissue Engineering Bone and Cartilage, Biomaterials, 2000, 21(24), p 2529–2543. https://doi.org/10.1016/S0142-9612(00)00121-6
D.W. Hutmacher, T. Schantz, I. Zein, K.W. Ng, S.H. Teoh, and K.C. Tan, Mechanical Properties and Cell Cultural Response of Polycaprolactone Scaffolds Designed and Fabricated via Fused Deposition Modeling, J. Biomed. Mater. Res., 2001, 55(2), p 203–216. 10.1002/1097-4636(200105)55:2<203::aid-jbm1007>3.0.co;2-7
D. Espalin, K. Arcaute, D. Rodriguez, F. Medina, M. Posner, and R. Wicker, Fused Deposition Modeling of Patient-specific Polymethylmethacrylate Implants, Rapid Prototyp. J., 2010, 16(3), p 164–173. https://doi.org/10.1108/13552541011034825
G.I. Salentijn, P.E. Oomen, M. Grajewski, and E. Verpoorte, Fused Deposition Modeling 3D Printing for (Bio)analytical Device Fabrication: Procedures, Materials, and Applications, Chem. Anal., 2017, https://doi.org/10.1021/acs.analchem.7b00828
H.N. Chia and B.M. Wu, Recent Advances in 3D Printing of Biomaterials, J. Biol. Eng., 2015, 9(1), p 4. https://doi.org/10.1186/s13036-015-0001-4
F. Ning, W. Cong, J. Qiu, J. Wei, and S. Wang, Additive Manufacturing of Carbon Fiber Reinforced Thermoplastic Composites Using Fused Deposition Modeling, Compos. Part B Eng., 2015, 80, p 369–378. https://doi.org/10.1016/j.compositesb.2015.06.013
R. Singh, S. Singh, and F. Fraternali, Development of in-House Composite Wire Based Feed Stock Filaments of Fused Deposition Modelling for Wear-Resistant Materials and Structures, Compos. Part B Eng., 2016, 98, p 244–249. https://doi.org/10.1016/j.compositesb.2016.05.038
C. Esposito Corcione, F. Gervaso, F. Scalera, F. Montagna, A. Sannino, and A. Maffezzoli, The Feasibility of Printing Polylactic Acid???nanohydroxyapatite Composites Using a Low-Cost Fused Deposition Modeling 3D Printer, J. Appl. Polym. Sci., 2017, https://doi.org/10.1002/app.44656
S. Keating and N. Oxman, Compound Fabrication: A Multi-Functional Robotic Platform for Digital Design and Fabrication, Robot. Comput. Integr. Manuf., 2013, 29(6), p 439–448. https://doi.org/10.1016/j.rcim.2013.05.001
X. Song, Y. Pan, and Y. Chen, Development of a Low-Cost Parallel Kinematic Machine for Multidirectional Additive Manufacturing, J. Manuf. Sci. Eng., 2015, 137(2), p 5. https://doi.org/10.1115/1.4028897
S. Ahn, M. Montero, D. Odell, S. Roundy, and P.K. Wright, Anisotropic Material Properties of Fused Deposition Modeling ABS, Rapid Prototyp. J., 2002, 8(4), p 248–257. https://doi.org/10.1108/13552540210441166
A. Bellini and S. Güçeri, Mechanical Characterization of Parts Fabricated Using Fused Deposition Modeling, Rapid Prototyp. J., 2003, 9(4), p 252–264. https://doi.org/10.1108/13552540310489631
R. Anitha, S. Arunachalam, and P. Radhakrishnan, Critical Parameters Influencing the Quality of Prototypes in Fused Deposition Modelling, J. Mater. Process. Technol., 2001, https://doi.org/10.1016/s0924-0136(01)00980-3
Q. Sun, G.M. Rizvi, C.T. Bellehumeur, and P. Gu, Effect of Processing Conditions on the Bonding Quality of FDM Polymer Filaments, Rapid Prototyp. J., 2008, 14(2), p 72–80. https://doi.org/10.1108/13552540810862028
A.K. Sood, R.K. Ohdar, and S.S. Mahapatra, Parametric Appraisal of Mechanical Property of Fused Deposition Modelling Processed Parts, Mater. Des., 2010, 31(1), p 287–295. https://doi.org/10.1016/j.matdes.2009.06.016
J.F. Rodríguez, J.P. Thomas, and J.E. Renaud, Design of Fused-Deposition ABS Components for Stiffness and Strength, J. Mech. Des., 2003, 125(3), p 545. https://doi.org/10.1115/1.1582499
B.H. Lee, J. Abdullah, and Z.A. Khan, Optimization of Rapid Prototyping Parameters for Production of Flexible ABS Object, J. Mater. Process. Technol., 2005, 169(1), p 54–61. https://doi.org/10.1016/j.jmatprotec.2005.02.259
B. Rankouhi, S. Javadpour, F. Delfanian, and T. Letcher, Failure Analysis and Mechanical Characterization of 3D Printed ABS With Respect to Layer Thickness and Orientation, J. Fail. Anal. Prev., 2016, 16(3), p 467–481. https://doi.org/10.1007/s11668-016-0113-2
T. Letcher, B. Rankouhi, and S. Javadpour, Experimental Study of Mechanical Properties of Additively Manufactured ABS Plastic as a Function of Layer Parameters, Proceedings of the ASME 2015 International Mechanical Engineering Congress and Exposition, Houston, TX, 2015, p 1–8
M. Fernandez-Vicente, W. Calle, S. Ferrandiz, and A. Conejero, Effect of Infill Parameters on Tensile Mechanical Behavior in Desktop 3D Printing, 3D Print, Addit. Manuf., 2016, 3(3), p 183–192. https://doi.org/10.1089/3dp.2015.0036
A.R. Torrado and D.A. Roberson, Failure Analysis and Anisotropy Evaluation of 3D-Printed Tensile Test Specimens of Different Geometries and Print Raster Patterns, J. Fail. Anal. Prev., 2016, 16(1), p 154–164. https://doi.org/10.1007/s11668-016-0067-4
O.A. Mohamed, S.H. Masood, J.L. Bhowmik, M. Nikzad, and J. Azadmanjiri, Effect of Process Parameters on Dynamic Mechanical Performance of FDM PC/ABS Printed Parts Through Design of Experiment, J. Mater. Eng. Perform., 2016, 25(7), p 2922–2935. https://doi.org/10.1007/s11665-016-2157-6
C. Koch, L. Van Hulle, and N. Rudolph, Investigation of Mechanical Anisotropy of the Fused Filament Fabrication Process via Customized Tool Path Generation, Addit. Manuf., 2017, 16, p 138–145. https://doi.org/10.1016/j.addma.2017.06.003
C.S. Davis, K.E. Hillgartner, S.H. Han, and J.E. Seppala, Mechanical Strength of Welding Zones Produced by Material Extrusion Additive Manufacturing †, Addit. Manuf., 2017, 16, p 162–166. https://doi.org/10.1016/j.addma.2017.06.006
D. Croccolo, M. De Agostinis, and G. Olmi, Experimental Characterization and Analytical Modelling of the Mechanical Behaviour of Fused Deposition Processed Parts Made of ABS-M30, Comput. Mater. Sci., 2013, 79, p 506–518. https://doi.org/10.1016/j.commatsci.2013.06.041
T. Letcher and M. Waytashek, Material Property Testing of 3D-Printed Specimen in PLA on an Entry-Level 3D Printer, Volume 2A: Advanced Manufacturing, ASME, 2014, p V02AT02A014, https://doi.org/10.1115/imece2014-39379
B.M. Tymrak, M. Kreiger, and J.M. Pearce, Mechanical Properties of Components Fabricated with Open-Source 3-D Printers under Realistic Environmental Conditions, Mater. Des., 2014, 58, p 242–246. https://doi.org/10.1016/j.matdes.2014.02.038
E. Ulu, E. Korkmaz, K. Yay, O. Burak Ozdoganlar, and L. Burak Kara, Enhancing the Structural Performance of Additively Manufactured Objects Through Build Orientation Optimization, J. Mech. Des., 2015, 137(11), p 111410. https://doi.org/10.1115/1.4030998
M. Spoerk, F. Arbeiter, H. Cajner, J. Sapkota, and C. Holzer, Parametric Optimization of Intra-and Inter-Layer Strengths in Parts Produced by Extrusion-Based Additive Manufacturing of Poly(lactic Acid), J. Appl. Polym. Sci., 2017, 134, p 45401. https://doi.org/10.1002/app.45401
A.R. Torrado Perez, D.A. Roberson, and R.B. Wicker, Fracture Surface Analysis of 3D-Printed Tensile Specimens of Novel ABS-Based Materials, J. Fail. Anal. Prev., 2014, https://doi.org/10.1007/s11668-014-9803-9
A.R. Torrado, C.M. Shemelya, J.D. English, Y. Lin, R.B. Wicker, and D.A. Roberson, Characterizing the Effect of Additives to ABS on the Mechanical Property Anisotropy of Specimens Fabricated by Material Extrusion 3D Printing, Addit. Manuf., 2015, 6, p 16–29. https://doi.org/10.1016/j.addma.2015.02.001
N.P. Levenhagen and M.D. Dadmun, Bimodal Molecular Weight Samples Improve the Isotropy of 3D Printed Polymeric Samples, Polymer (Guildf), 2017, 122, p 232–241. https://doi.org/10.1016/j.polymer.2017.06.057
J.T. Belter and A.M. Dollar, Strengthening of 3D Printed Fused Deposition Manufactured Parts Using the Fill Compositing Technique, PLoS ONE, 2015, 10(4), p e0122915. https://doi.org/10.1371/journal.pone.0122915
C.B. Sweeney, B.A. Lackey, M.J. Pospisil, T.C. Achee, V.K. Hicks, A.G. Moran, B.R. Teipel, M.A. Saed, and M.J. Green, Welding of 3D-Printed Carbon Nanotube–polymer Composites by Locally Induced Microwave Heating, Adv. Sci., 2017, https://doi.org/10.1126/sciadv.1700262
A.B. AlAli, M.F. Griffin, and P.E. Butler, Three-Dimensional Printing Surgical Applications, Eplasty, 2015, 15, p e37
N. Martelli, C. Serrano, H. Van Den Brink, J. Pineau, P. Prognon, I. Borget, and S. El Batti, Advantages and Disadvantages of 3-Dimensional Printing in Surgery: A Systematic Review, Surgery (United States), 2016, https://doi.org/10.1016/j.surg.2015.12.017
M.P. Chae, W.M. Rozen, P.G. McMenamin, M.W. Findlay, R.T. Spychal, and D.J. Hunter-Smith, Emerging Applications of Bedside 3D Printing in Plastic Surgery, Front. Surg., 2015, 2, p 25. https://doi.org/10.3389/fsurg.2015.00025
H.H. Malik, A.R.J. Darwood, S. Shaunak, P. Kulatilake, A.A. El-Hilly, O. Mulki, and A. Baskaradas, Three-Dimensional Printing in Surgery: A Review of Current Surgical Applications, J. Surg. Res., 2015, https://doi.org/10.1016/j.jss.2015.06.051
T.M. Rankin, N.A. Giovinco, D.J. Cucher, G. Watts, B. Hurwitz, and D.G. Armstrong, Three-Dimensional Printing Surgical Instruments: Are We There Yet?, J. Surg. Res., 2014, 189(2), p 193–197. https://doi.org/10.1016/j.jss.2014.02.020
S.M. Fuller, D.R. Butz, C.B. Vevang, and M.V. Makhlouf, Application of 3-Dimensional Printing in Hand Surgery for Production of a Novel Bone Reduction Clamp, J. Hand Surg., 2014, https://doi.org/10.1016/j.jhsa.2014.06.009
J.Y. Wong and A.C. Pfahnl, 3D Printing of Surgical Instruments for Long-Duration Space Missions, Aviat. Sp. Environ. Med., 2014, 85(7), p 758–763
S. Kondor, C.G. Grant, P. Liacouras, M.J.R. Schmid, L. Michael Parsons, V.K. Rastogi, L.S. Smith, B. Macy, B. Sabart, and C. Macedonia, On Demand Additive Manufacturing of a Basic Surgical Kit, J. Med. Devices, 2013, 7(3), p 030916. https://doi.org/10.1115/1.4024490
K.A. da Silva Aquino, Sterilization by Gamma Irradiation, Gamma Radiat., 2012, https://doi.org/10.5772/34901
J. O’Donnell and N. Rahman, Evidence of Crosslinking and Chain Scission in the Degradation of Poly (Tert-butyl Crotonate) by Γ-irradiation, J. Polym., 1977, https://doi.org/10.1002/pol.1977.170150113/abstract
J. Odonnell, Chemistry of Radiation Degradation of Polymers, Radiat. Eff. Polym., 1990, 475, p 402–413. https://doi.org/10.1021/bk-1991-0475.ch024
M. Al-Sheikhly and A. Christou, How Radiation Affects Polymeric Materials, IEEE Trans. Reliab., 1994, 43(4), p 551–556. https://doi.org/10.1109/24.370227
T. Sasuga, N. Hayakawa, and K. Yoshida, Degradation in Tensile Properties of Aromatic Polymers by Electron Beam Irradiation, Polymer (Guildf), 1985, 26, p 1039–1045
A. Bhattacharya, Radiation and Industrial Polymers, Prog. Polym. Sci., 2000, 25(3), p 371–401. https://doi.org/10.1016/S0079-6700(00)00009-5
R.S. Benson, Use of Radiation in Biomaterials Science, Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, 2002, p 752–757
S. Shaffer, K. Yang, J. Vargas, M.A. Di Prima, and W. Voit, On Reducing Anisotropy in 3D Printed Polymers via Ionizing Radiation, Polymer (United Kingdom), 2014, 55(23), p 5969–5979. https://doi.org/10.1016/j.polymer.2014.07.054
C. Shemelya, A. Rivera, A. Perez, and C. Rocha, Mechanical, Electromagnetic, and X-Ray Shielding Characterization of a 3D Printable Tungsten-Polycarbonate Polymer Matrix Composite for Space-Based, J. Electron., 2015, https://doi.org/10.1007/s11664-015-3687-7
A.M. Schmalzer, C.M. Cady, D. Geller, D. Ortiz-Acosta, A.T. Zocco, J. Stull, and A. Labouriau, Gamma Radiation Effects on Siloxane-Based Additive Manufactured Structures, Radiat. Phys. Chem., 2017, 130, p 103–111. https://doi.org/10.1016/j.radphyschem.2016.07.020
ASTM, ASTM D638-14: Standard Test Method for Tensile Properties of Plastics, ASTM Stand., 2014, 08(01), p 1–15
ASTM, ASTM D790-15e2, Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Electrical Insulating Materials, ASTM Stand., 2015, 08(01), p 1–11
ASTM, ASTM D2240-15, Standard Test Method for Rubber Property—Durometer Hardness, ASTM Stand., 2015, 09(1), p 1–13
Sterilization of Health Care products—Radiation—Part 2: Establishing the Sterilization Dose, ANSI/AAMI/ISO 11137-2, Association for the Advancement of Medical Instrumentation, June 2013
J. Cassidy, S. Nesaei, R. McTaggart, and F. Delfanian, Mechanical Response of High Density Polyethylene to Gamma Radiation from a Cobalt-60 Irradiator, Polym. Test., 2016, 52, p 111–116
K. Rojdev, M. O’Rourke, C. Hill, and S. Nutt, In-Situ Strain Analysis of Potential Habitat Composites Exposed to a Simulated Long-Term Lunar Radiation Exposure, Radiat. Phys., 2013, 84, p 235–241
Acknowledgment
The authors would like to thank Kostas Kaounas for performing the gamma irradiation and 3M Corporations for providing the cobalt-60 irradiator. The experiments presented in this study were performed in Material Evaluation and Testing Laboratory (METLAB) in Mechanical Engineering Department at South Dakota State University (SDSU). Financial support for this paper was provided by Advanced Manufacturing Process Technology Transition & Training Center (AMPTEC), under Contract Number 3S6674.
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Rankouhi, B., Javadpour, S., Delfanian, F. et al. Experimental Investigation of Mechanical Performance and Printability of Gamma-Irradiated Additively Manufactured ABS. J. of Materi Eng and Perform 27, 3643–3654 (2018). https://doi.org/10.1007/s11665-018-3463-y
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DOI: https://doi.org/10.1007/s11665-018-3463-y