Skip to main content
SpringerLink
Log in

Improved photoluminescence and monodisperse performance of colloidal CdTe quantum dots with Cannula method

  • Materials (Organic, Inorganic, Electronic, Thin Films)
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Colloidal quantum dots are nano semiconductor materials that have been found in many applications, producing multiple exciton generation, unique optical and electronic properties, adjustable in size and bandwidth. Synthesized QDs are expected to exhibit high photoluminescence quantum yield and monodisperse properties according to their application area. Cannula method was adapted together with the organometallic synthesis method for the first time in the literature to increase the photoluminescence quantum yield of organometallic CdTe QD and minimize the full width at half maximum value of the photoluminescence band. Injection of precursors by the Cannula method is much faster than the injecting with the conventional method of using a glass syringe, which limits the size distribution in the solution during synthesis. In addition, the fastest injection method using Cannula method yields the shortest full width half maximum value of 27.20 nm for CdTe QDs in the literature. The photoluminescence quantum yield value of the CdTe QDs synthesized by the classical method was 8.12±2.1%, while the photoluminescence quantum yield of the CdTe QDs synthesized by the Cannula method was increased to 25.66±2.1%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Z. Fang, L. Liu, L. Xu, X. Yin and X. Zhong, Nanotechnology, 19 (2008)

  2. D. Zhou, M. Lin, Z. Chen, H. Sun, H. Zhang, H. Sun and B. Yang, Chem. Mater., 23, 4857 (2011).

    Article  CAS  Google Scholar 

  3. A. Shavel, N. Gaponik and A. Eychmüller, J. Phys. Chem. B., 110, 19280 (2006).

    Article  CAS  PubMed  Google Scholar 

  4. S. F. Wuister, I. Swart, F. van Driel, S. G. Hickey and C. de Mello Donegá, Nano Lett., 3, 503 (2003).

    Article  CAS  Google Scholar 

  5. Y. Yang, C. Zhang, X. Qu, W. Zhang, M. Marus, B. Xu, K. Wang and X. Wei Sun, IEEE Trans. Nanotechnol., 18, 220 (2019).

    Article  CAS  Google Scholar 

  6. Q. Ma and X. Su, Appl. Spectrosc. Rev., 51, 162 (2016).

    Article  Google Scholar 

  7. D. Sharma, R. Jha and S. Kumar, Sol. Energy Mater. Sol. Cells, 155, 294 (2016).

    Article  CAS  Google Scholar 

  8. Y. Kim and J. Y. Chang, Sens. Actuators, B Chem., 234, 122 (2016).

    Article  CAS  Google Scholar 

  9. O. Mashinchian, M. Johari-Ahar, B. Ghaemi, M. Rashidi, J. Barar and Y. Omidi, BioImpacts, 4, 149 (2014).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  10. Z. A. Peng and X. Peng, J. Am. Chem. Soc., 123, 183 (2001).

    Article  CAS  PubMed  Google Scholar 

  11. J. Wang, Y. Long, Y. Zhang, X. Zhong and L. Zhu, ChemPhysChem., 10, 680 (2009).

    Article  CAS  PubMed  Google Scholar 

  12. Y. Wang and S. Liu, J. Chil. Chem. Soc., 57, 1109 (2012).

    Article  CAS  Google Scholar 

  13. J.-J. Shi, S. Wang, T.-T. He, E. S. Abdel-Halim and J.-J. Zhu, Ultrason. Sonochem., 21, 493 (2014).

    Article  CAS  PubMed  Google Scholar 

  14. L. Li, H. Qian and J. Ren, Chem. Commun., 528 (2005).

  15. Y. S. Li, F. L. Jiang, Q. Xiao, R. Li, K. Li, M. F. Zhang, A. Q. Zhang, S. F. Sun and Y. Liu, Appl. Catal. B Environ., 101, 118 (2010).

    Article  CAS  Google Scholar 

  16. R. Kniprath, J. P. Rabe, J. T. McLeskey, D. Wang and S. Kirstein, Thin Solid Films, 518, 295 (2009).

    Article  CAS  Google Scholar 

  17. G.-Y. Lan, Z. Yang, Y.-W. Lin, Z.-H. Lin, H.-Y. Liao and H.-T. Chang, J. Mater. Chem., 19, 2349 (2009).

    Article  CAS  Google Scholar 

  18. R. W. Birkmire and B. E. McCandless, Curr. Opin. Solid State Mater. Sci., 14, 139 (2010).

    Article  CAS  Google Scholar 

  19. C. S. Ferekides, U. Balasubramanian, R. Mamazza, V. Viswanathan, H. Zhao and D. L. Morel, Sol. Energy, 77, 823 (2004).

    Article  CAS  Google Scholar 

  20. F. L. Xue, J. Y. Chen, J. Guo, C. C. Wang, W. L. Yang, P. N. Wang and D. R. Lu, J. Fluoresc., 17, 149 (2007).

    Article  CAS  PubMed  Google Scholar 

  21. Y. F. Liu and J. S. Yu, J. Colloid Interface Sci., 351, 1 (2010).

    Article  CAS  PubMed  Google Scholar 

  22. B. Jai Kumar and H. M. Mahesh, Superlattices Microstruct., 104, 118 (2017).

    Article  CAS  Google Scholar 

  23. J. Lee, H. Chen, K. Koh, C. L. Chang, C. M. Kim and S. H. Kim, Korean J. Chem. Eng., 26, 417 (2009).

    Article  CAS  Google Scholar 

  24. K. Ruan, Y. Guo, Y. Tang, Y. Zhang, J. Zhang, M. He, J. Kong and J. Gu, Compos. Commun., 10, 68 (2018).

    Article  Google Scholar 

  25. Y. Huangfu, C. Liang, Y. Han, H. Qiu, P. Song, L. Wang, J. Kong and J. Gu, Compos. Sci. Technol., 169, 70 (2019).

    Article  CAS  Google Scholar 

  26. X. Yang, F. Ren, Y. Wang, T. Ding, H. Sun, D. Ma and X. W. Sun, Sci. Rep., 7 (2017).

  27. R. C. Somers, M. G. Bawendi and D. G. Nocera, Chem. Soc. Rev., 36, 579 (2007).

    Article  CAS  PubMed  Google Scholar 

  28. I. Hwang, M. Seol, H. Kim and K. Yong, Appl. Phys. Lett., 103 (2013).

  29. R. C. Page, D. Espinobarro-Velazquez, M. A. Leontiadou, C. Smith, E. A. Lewis, S. J. Haigh, C. Li, H. Radtke, A. Pengpad, F. Bondino, E. Magnano, I. Pis, W. R. Flavell, P. O’Brien and D. J. Binks, Small, 11, 1548 (2015).

    Article  CAS  PubMed  Google Scholar 

  30. C. B. Murray, C. R. Kagan and M. G. Bawendi, Annu. Rev. Mater. Sci., 30, 545 (2000).

    Article  CAS  Google Scholar 

  31. D. V. Talapin, S. Haubold, A. L. Rogach, A. Kornowski, M. Haase and H. Weller, J. Phys. Chem. B., 105, 2260 (2001).

    Article  CAS  Google Scholar 

  32. N. Gaponik, D. V. Talapin, A. L. Rogach, K. Hoppe, E. V. Shevchenko, A. Kornowski, A. Eychmuller and H. Weller, J. Phys. Chem. B., 106, 7177 (2002).

    Article  CAS  Google Scholar 

  33. L. Li, H. Qian, N. Fang and J. Ren, J. Lumin., 116, 59 (2006).

    Article  CAS  Google Scholar 

  34. C. Ge, M. Xu, J. Liu, J. Lei and H. Ju, Chem. Commun., 450 (2008).

  35. J. Tian, R. Liu, Y. Zhao, Q. Xu and S. Zhao, J. Colloid Interface Sci., 336, 504 (2009).

    Article  CAS  PubMed  Google Scholar 

  36. E. Elibol, M. Cadırcı and N. Tutkun, Synthesising Highly Luminescent CdTe Quantum Dots Using Cannula Hot Injection Method, in: Int. Conf. Quantum Dots (ICQD 2017), France/Paris (2017).

  37. L. C. Frenette and T. D. Krauss, Nat. Commun., 8 (2017).

  38. M. Planells, L. X. Reynolds, U. Bansode, S. Chhatre, S. Ogale, N. Robertson and S. A. Haque, Phys. Chem. Chem. Phys., 15, 7679 (2013).

    Article  CAS  PubMed  Google Scholar 

  39. O. Pitois, P. Moucheront and X. Chateau, J. Colloid Interface Sci., 231, 26 (2000).

    Article  CAS  PubMed  Google Scholar 

  40. M. W. Allen, Measurement of Fluorescence Quantum Yields, Thermo Sci., 1 (2010).

  41. X. F. Ding, L. J. Wen, X. Zhou, Y. Y. Ding, X. C. Ye, L. Zhou, M. C. Liu, H. Cai and J. Cao, Chinese Phys. C., 39 (2015).

  42. H. Forster, Mol. Sieves, 4, 337 (2004).

    Google Scholar 

  43. V. I. Klimov, Science (80-.), 290, 314 (2000).

    Article  CAS  Google Scholar 

  44. A. D. Guclu, P. Potasz and P. Hawrylak, Phys. Rev. B - Condens. Matter Mater. Phys., 82 (2010).

  45. W. W. Yu, Y. A. Wang and X. Peng, Chem. Mater., 15, 4300 (2003).

    Article  CAS  Google Scholar 

  46. Z. Lu, C. X. Guo, H. Bin Yang, Y. Qiao, J. Guo and C. M. Li, J. Colloid Interface Sci., 353, 588 (2011).

    Article  CAS  PubMed  Google Scholar 

  47. J. Zhu, S. N. Wang, J. J. Li and J. W. Zhao, J. Lumin., 199, 216 (2018).

    Article  CAS  Google Scholar 

  48. W. Shockley and H. J. Queisser, J. Appl. Phys., 32, 510 (1961).

    Article  CAS  Google Scholar 

  49. A. Kalnaitytė, S. Bagdonas and R. Rotomskis, J. Lumin., 201, 434 (2018).

    Article  CAS  Google Scholar 

  50. Z. Yu, J. Li, D. B. O’Connor, L. W. Wang and P. F. Barbara, J. Phys. Chem. B., 107, 5670 (2003).

    Article  CAS  Google Scholar 

  51. J. S. Steckel, R. Colby, W. Liu, K. Hutchinson, C. Breen, J. Ritter and S. Coe-Sullivan, Dig. Tech. Pap. - SID Int. Symp., 44, 943 (2013).

    Article  CAS  Google Scholar 

  52. F. Li, L. You, H. Li, X. Gu, J. Wei, X. Jin, C. Nie, Q. Zhang and Q. Li, J. Lumin., 192, 867 (2017).

    Article  CAS  Google Scholar 

  53. Y. Zhang, J. Lumin., 192, 1015 (2017).

    Article  CAS  Google Scholar 

  54. M. Amelia, C. Lincheneau, S. Silvi and A. Credi, Chem. Soc. Rev., 41, 5728 (2012).

    Article  CAS  PubMed  Google Scholar 

  55. R. He, X. You, H. Tian, F. Gao and D. Cui, Front. Chem. China., 3, 325 (2008).

    Article  Google Scholar 

  56. A. Arivarasan, S. Bharathi, V. Vijayaraj, G. Sasikala and R. Jayavel, J. Inorg. Organomet. Polym. Mater., 28, 1263 (2018).

    Article  CAS  Google Scholar 

  57. A. Ayyaswamy, S. Ganapathy, A. Alsalme, A. Alghamdi and J. Ramasamy, Superlattices Microstruct., 88, 634 (2015).

    Article  CAS  Google Scholar 

  58. D. S. M. Ribeiro, G. C. S. de Souza, A. Melo, J. X. Soares, S. S. M. Rodrigues, A. N. Araujo, M. C. B. S. M. Montenegro and J. L. M. Santos, J. Mater. Sci., 52, 3208 (2017).

    Article  CAS  Google Scholar 

  59. H. Bao, E. Wang and S. Dong, Small, 2, 476 (2006).

    Article  CAS  PubMed  Google Scholar 

  60. V. Lesnyak, S. V. Voitekhovich, P. N. Gaponik, N. Gaponik and A. Eychmuller, ACS Nano., 4, 4090 (2010).

    Article  CAS  PubMed  Google Scholar 

  61. A. L. Rogach, T. Franzl, T. A. Klar, J. Feldmann, N. Gaponik, V. Lesnyak, A. Shavel, A. Eychmüller, Y. P. Rakovich and J. F. J. Phys. Chem. C., 111, 14628 (2007).

    Article  CAS  Google Scholar 

  62. S. Kiprotich, M. O. Onani and F. B. Dejene, Phys. B Condens. Matter., 535, 202 (2018).

    Article  CAS  Google Scholar 

  63. R. E. Bailey and S. Nie, J. Am. Chem. Soc., 125, 7100 (2003).

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dept. of Electrical & Electronics Engineering, Duzce University, Duzce, Turkey

    Erdem Elibol & Musa Çadırcı

  2. Dept. of Environmental Engineering, Duzce University, Duzce, Turkey

    Pınar Sevim Elibol

  3. Dept. of Electrical & Electronics Engineering, Istanbul Aydın University, Istanbul, Turkey

    Nedim Tutkun

Authors
  1. Erdem Elibol
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pınar Sevim Elibol
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Musa Çadırcı
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Nedim Tutkun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Erdem Elibol.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Elibol, E., Elibol, P.S., Çadırcı, M. et al. Improved photoluminescence and monodisperse performance of colloidal CdTe quantum dots with Cannula method. Korean J. Chem. Eng. 36, 625–634 (2019). https://doi.org/10.1007/s11814-019-0243-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-019-0243-9

Keywords

Search

Navigation