Abstract
PEI imilti-coated PSBF (PEI-M-PSBF) wth high adsorption efficiency and good reusability for Pd(II) recovery was prepared by a PEI multi-coating method. The results of FT-IR and FE-SEM showed that the PEI-M-PSBF was successfully prepared. Batch experiments were conducted to study the adsorption/desorption performance of PEI-M-PSBF to Pd(II). The Langmuir and pseudo-second-order models were well suited for the batch experiment isotherm and kinetic data, respectively. The adsorption capacity of Pd(II) by Langmuir model was 327.14 mg/g, and the initial adsorption rate of 3-PEI-PSBF was 37.19mg/g min. As a resut, the increase in amine groups on the PEI-M-PSBF surface through the PEI multi-coating directly influenced the adsorption amount of the biosorbent. The effects of initial concentration, bed column depth, and flow rate were determined in a column system and the breakthrough curves were detected by Thomas model. In addition, the recycle of the adsorbent was examined by multiple time performing adsorption/desorption cycles up to ten times in a fixed-bed column.
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References
C. Ruan, M. Strømme and J. Lindh, Cellulose, 23, 2627 (2016).
M. H. Morcali and B. Zeytuncu, Int. J. Miner. Process., 137, 52 (2015).
M. Yamada, M. R. Gandhi and A. Shibayama, Sci. Rep., 8, 1 (2018).
A. Ramesh, H. Hasegawa, W. Sugimoto, T. Maki and K. Ueda, Bioresour. Technol., 99, 3801 (2008).
M. Fomina and G. M. Gadd, Bioresour. Technol., 160, 3 (2014).
J. Mao, S. W. Won, K. Viiayaraghavan and Y. S. Yun, Bioresour. Technol., 100, 1463 (2009).
Y. S. Yun, D. Park, J. M. Park and B. Volesky, Environ. Sci. Technol., 35, 4353 (2001).
K. Vijayaraghavan and Y. S. Yun, Biotechnol. Adv., 26, 266 (2008).
C. W. Cho, S. B. Kang, S. Kim, Y. S. Yun and S. W. Won, Chem. Eng. J., 302, 545 (2016).
F. Beolchini, F. Pagnanelli, L. Toro and F. Vegliò, Hydrometallurgy, 70, 101 (2003).
C. Sun, G. Song, L. Chen, X. Ren and C. Chen, J. Colloid Interface Sci., 580, 550 (2020).
F. Zhao, Z. Yang, Z. Wei, R. Spinney, M. Sillanpää, J. Tang, M. Tam and R. Xiao, Chem. Eng. J., 388, 124307 (2020).
J. Kwame, S. Lin, A. Kumar, Y. Zhao, J. W. Choi, M. H. Song, W. Wei, D. H. Kumar, C. W. Cho and Y. S. Yun, J. Clean. Prod., 252, 119389 (2020).
H. A. Choi, H. N. Park and S. W. Won, J. Environ. Manage., 204, 200 (2017).
F. Zhao, E. Repo, Y. Song, D. Yin, S. B. Hammouda, L. Chen, S. Kalliola, J. Tang, K. C. Tam and M. Sillanpää, Green Chem., 19, 4816 (2017).
S. Bo, J. Luo, Q. An, Z. Xiao, H. Wang, W. Cai, S. Zhai and Z. Li, J. Clean. Prod., 250, 119585 (2020).
A. Shahbazi, H. Younesi and A. Badiei, Chem. Eng. J., 168, 505 (2011).
S. Kim, Y. E. Choi and Y. S. Yun, J. Hazard. Mater., 313, 29 (2016).
S. W. Won, J. Park, J. Mao and Y. S. Yun, Bioresour. Technol., 102, 3888 (2011).
S. W. Won, S. Kim, P. Kotte, A. Lim and Y. S. Yun, J. Hazard. Mater., 263, 391 (2013).
K. Fytianos, E. Voudrias and E. Kokkalis, Chemosphere, 40, 3 (2000).
M. R. Gandhi, M. Yamada, Y. Kondo, A. Shibayama and F. Hamada, J. Ind. Eng. Chem., 30, 20 (2015).
T. Vincent, A. Parodi and E. Guibal, React. Funct. Polym., 68, 1159 (2018).
S. Sharma and N. Rajesh, J. Environ. Chem. Eng., 5, 1927 (2017).
S. Sharma, M. Barathi and N. Rajesh, Chem. Eng. J., 259, 457 (2015).
S. Örgül and Ü. Atalay, Hydrometallurgy, 67, 71 (2002).
Z. Hubicki, M. Wawrzkiewicz and A. Wołowicz, Chem. Analityczna, 53, 759 (2008).
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This work; supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2020R1F1A1065937).
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Kang, S.B., Wang, Z. & Won, S.W. Application of polyethylenimine multi-coated adsorbent for Pd(II) recovery from acidic aqueous solution: batch and fixed-bed column studies. Korean J. Chem. Eng. 38, 523–530 (2021). https://doi.org/10.1007/s11814-020-0716-x
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DOI: https://doi.org/10.1007/s11814-020-0716-x