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Preparation and characterization of polyacrylate composite and its application in superhydrophobic coating based on silicone-modified ZnO

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Abstract

In this paper, a kind of silicone containing double bond and hydrogen bond has been synthesized via telomerization. In order to disperse and incorporate ZnO into the polymer matrix, ZnO was modified with silicone. Finally, ZnO/polyacrylate and silicone/polyacrylate composites were prepared using modified ZnO and silicone. The present study reports synthesis and characterization of ZnO/polyacrylate and silicone/polyacrylate nanocomposites by in situ emulsion polymerization. The effects of ZnO and silicone on the morphological structure and thermal properties of composites were systematically studied. The composites were characterized using FTIR, XRD, SEM, TEM, TGA, particle size analysis, UV, and WCA. It could be seen that the thermal degradation temperature of the composites increased significantly with the addition of ZnO and silicone. SEM analysis showed that the films were evenly distributed with the surface-modified ZnO nanoparticles. Then, the modified ZnO/polyacrylate superhydrophobic composite coating was prepared using modified ZnO and silicone/polyacrylate emulsion. The coating has excellent self-cleaning and oil–water separation properties.

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Acknowledgments

The research was supported by the National Natural Science Foundation of China (51568048).

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Authors and Affiliations

  1. Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education, School of Resources Environmental and Chemical Engineering, Nanchang University, Nanchang, 330031, China

    Changpo Ma, Yongzan Li, Jian Zhang, Feng Ning, Minxia Kang, Hui Li & Zumin Qiu

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  1. Changpo Ma
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Correspondence to Zumin Qiu.

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Ma, C., Li, Y., Zhang, J. et al. Preparation and characterization of polyacrylate composite and its application in superhydrophobic coating based on silicone-modified ZnO. J Coat Technol Res 18, 415–433 (2021). https://doi.org/10.1007/s11998-020-00411-7

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