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Sulfur Containing Compounds as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution

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Abstract

The role of Sulfur containing compounds namely: Thiobarbituric acid (TBA) and Thiourea (TH) as corrosion inhibitors for mild steel in 1 M HCl has been studied using potentiodynamic anodic polarization, electrochemical impedance spectroscopy, atomic force microscopy and scanning electron microscopy techniques. Polarization results showed that all the compounds studied are mixed type inhibitors. Electrochemical impedance studies showed that the presence of these compounds decreases the double-layer capacitance and increases the charge transfer resistance. Quantum chemical calculation was further applied to reveal the adsorption structure and explain the experimental results. The results of calculations showed superior inhibition efficiency of TH in comparison to TBA.

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Acknowledgments

The authors wish to acknowledge the financial support of the Office of Vice Chancellor of Research of their corresponding universities. We are grateful to the office of scientific research projects of Cumhuriyet University (Project No.: F-372) for financial supports. The numerical calculations reported in this paper are performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA Resources).

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Authors and Affiliations

  1. Abadan Faculty of Petroleum Engineering, Petroleum University of Technology, Abadan, Iran

    Hojat Jafari

  2. Department of Chemistry, Institute of Science, Cumhuriyet University, 58140, Sivas, Turkey

    Koray Sayin

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  1. Hojat Jafari
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  2. Koray Sayin
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Correspondence to Hojat Jafari.

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Jafari, H., Sayin, K. Sulfur Containing Compounds as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution. Trans Indian Inst Met 69, 805–815 (2016). https://doi.org/10.1007/s12666-015-0556-2

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  • DOI: https://doi.org/10.1007/s12666-015-0556-2

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