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Adsorption kinetics and thermodynamics of water-insoluble crosslinked β-cyclodextrin polymer for phenol in aqueous solution

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Abstract

A water-insoluble β-cyclodextrin (β-CD) polymer was synthesized by reacting β-CD with hexamethylene diisocyanate, and its adsorption kinetics and thermodynamics for phenol from aqueous solution was investigated. The kinetics of adsorption followed the pseudo-second-order model and the adsorption isotherms could be well fitted by the Freundlich adsorption equation. The values of thermodynamic parameters demonstrated that the adsorption was a physisorption in a spontaneous and exothermic process.

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Authors and Affiliations

  1. School of Chemical Engineering, Ningbo University of Technology, Ningbo, 315016, P. R. China

    Hui Huang, Yifan Fan, Junwei Wang & Haoqi Gao

  2. Division of Engineering, University of Nottingham Ningbo China, Ningbo, 315010, P. R. China

    Shiying Tao

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  1. Hui Huang
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  2. Yifan Fan
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  3. Junwei Wang
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  4. Haoqi Gao
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Correspondence to Hui Huang.

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Huang, H., Fan, Y., Wang, J. et al. Adsorption kinetics and thermodynamics of water-insoluble crosslinked β-cyclodextrin polymer for phenol in aqueous solution. Macromol. Res. 21, 726–731 (2013). https://doi.org/10.1007/s13233-013-1086-6

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  • DOI: https://doi.org/10.1007/s13233-013-1086-6

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