Abstract
This study explores the roles of Fe2O3 (3–5 wt%) and/or MgO (0.6–2.4 wt%) on the crystallization behaviour, microstructure, sinterability and mechanical properties of 17.02CaO-7.04Al2O3-58.84SiO2 (CAS, wt%) glass-ceramics. With increasing Fe2O3 and/or MgO contents, the peak temperature of glass crystallization decreased, and the main crystal phase (wollastonite) was suppressed, while the secondary phases of hardystonite and diopside were crystallized and promoted. Wollastonite crystals grew larger, and their distribution became scattered as Fe2O3 and/or MgO contents increased. The concentrations of elemental Fe and Zn in the glass matrix influence the formation of hardystonite (Ca2ZnSi2O7), and Mg2+ can participate in the formation of diopside and melilite-type solid solution Ca2ZnSi2O7-Ca2MgSi2O7. Vickers hardness was decreased by the increasing amount of glass matrix while density was increased. The optimum heat treatment temperature range of the CAS glass-ceramics was narrowed by the addition of Fe2O3 and/or MgO due to rapid crystallization and a degree of fusion or overburning.
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References
Höland, W., Beall, G.H.: Glass Ceramic Technology, 2nd edn. Wiley, Hoboken (2012)
Zanotto, E.D.: A bright future for glass-ceramics. Am. Ceram. Soc. Bull. 8, 19–27 (2010)
Karamanov, A., Gutzow, I., Penkov, I., Andreev, J., Bogdanov, B.: Diopside marble-like sintered glass-ceramics. Glastech. Ber. Glass Sci. Technol. 67, 202–206 (1994)
Lu, Z.Y., Lu, J.S., Li, X.B., Shao, G.Q.: Effect of MgO addition on sinterability, crystallization kinetics, and flexural strength of glass-ceramics from waste materials. Ceram. Int. 42, 3452–3459 (2016)
Ren, X.Z., Zhang, W., Zhang, Y., Zhang, P.X., Liu, J.H.: Effects of Fe2O3 content on microstructure and mechanical properties of CaO-Al2O3-SiO2 system. Trans. Nonferrous Met. Soc. China. 25, 137–145 (2015)
Yang Z.J., Li Y., Cang D.Q., Diao M. L., Guo W.B.: The influence of Fe2+ and Fe3+ on crystallization of CaO-Al2O3-SiO2-MgO system glass-ceramics. Mater. Sci. Technol. 2, 45-51, 60 (2012)
Yu, Q.C., Yan, C.P., Deng, Y., Feng, Y.B., Liu, D.C., Yang, B.: Effect of Fe2O3 on non-isothermal crystallization of CaO-MgO-Al2O3-SiO2 glass. Trans. Nonferrous Met. Soc. China. 25, 2279–2284 (2015)
Wang, Z.J., Ni, W., Li, K.Q., Huang, X.Y., Zhu, L.P.: Crystallization characteristics of iron-rich glass ceramics prepared from nickel slag and blast furnace slag. Int. J. Miner. Metall. Mater. 4, 455–459 (2011)
He, D.F., Gao, C., Pan, J.T., Xu, A.J.: Preparation of glass-ceramics with diopside as the main crystalline phase from low and medium titanium-bearing blast furnace slag. Ceram. Int. 44, 1384–1393 (2018)
Francis, A.A.: Non-isothermal crystallization kinetics of a blast furnace slag glass. J. Am. Ceram. Soc. 7, 1859–1863 (2005)
Zhao, Y., Chen, D.F., Bi, Y.Y., Long, M.J.: Preparation of low cost glass-ceramics from molten blast furnace slag. Ceram. Int. 38, 2495–2500 (2012)
Khater, G.A., Abdel-Motelib, A., El Manawi, A.W.: Glass-ceramic materials from basaltic rocks and some industrial waste. J. Non-Cryst. Solids. 358, 1128–1134 (2012)
Barbieri, L., Ferrari, A.M., Lancellotti, I., Leonelli, C.: Crystallization of (Na2O-MgO)-CaO-Al2O3-SiO2 glassy systems formulated from waste products. J. Am. Ceram. Soc. 10, 2515–2520 (2000)
Cheng, J.S., Tang, F.Y., Lou, X.C., Kang, J.F., Qian, S.Y.: Effect of MgO on crystallization and properties of glass-ceramics prepared from granite tailings. Journal of Wuhan University of Technology. 10, 11–14 (2014)
Cetin, S., Marangoni, M., Bernardo, E.: Lightweight glass-ceramic tiles from the sintering of mining tailings. Ceram. Int. 41, 5294–5300 (2015)
Bernardo, E., Esposito, L., Rambaldi, E., Tucci, A., Hreglich, S.: Recycle of waste glass into glass-ceramic stoneware. J. Am. Ceram. Soc. 91, 2156–2162 (2008)
Goel, A., Pascual, M.J., Ferreira, J.M.F.: Stable glass-ceramic sealants for solid oxide fuel cells: influence of Bi2O3 doping. Int. J. Hydrogen Energy. 35, 6911–6923 (2010)
Serbena, F.C., Soares, V.O., Peitl, O., Pinto, H., Muccillo, R., Zanotto, E.D.: Internal residual stresses in sintered and commercial low expansion Li2O-Al2O3-SiO2 glass-ceramics. J. Am. Ceram. Soc. 94, 1206–1214 (2011)
Dittmer, M., Ritzberger, C., Schweiger, M., Rheinberger, V., Wörle, M., Höland, W.: Phase and microstructure formation and their influence on the strength of two types of glass-ceramics. J. Non-Cryst. Solids. 384, 55–60 (2014)
Liu, H.P., Huang, X.F., Ma, L.P., Chen, D.L., Shang, Z.B., Jiang, M.: Effects of Fe2O3 on the crystallization behaviour of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag. Int. J. of Miner. Metall. Mater. 3, 316–323 (2017)
Dai, C.L., Yang, Y., Yang, M.: Function and influence of magnesium on the architectural ceramic body, glaze and glass-ceramics. Foshan Ceramics. 9, 37–42 (2010)
Karamanov, A., Pelino, M.: Crystallization phenomena in iron-rich glasses. J. Non-Cryst. Solids. 282, 139–151 (2001)
Păcurariu, C., Lazău, I.: Non-isothermal crystallization kinetics of some glass-ceramics with pyroxene structure. J. Non-Cryst. Solids. 358, 3332–3337 (2012)
Becker, P., Libowitzky, E., Bohaty, L., Liebertz, J., Rhee, H., Eichler, H.-J., Kaminski, A.A.: Temperature-dependent thermo-mechanical and Raman spectroscopy study of the SRS-active melilite-type crystal Ca2ZnSi2O7 (hardystonite) at its incommensurate-commensurate phase transition. Phys. Status Solidi A. 2, 327–334 (2012)
Pei, F.J., Guo, H.W., Li, P., Yan, B.J., Li, J., Yang, P., Zhu, G.H.: Influence of low magnesia content on the CaO-Al2O3-SiO2 glass-ceramics: its crystallization behaviour, microstructure and physical properties. Ceram. Int. 44, 20132–20139 (2018)
Dai, C.L., Yang, Y., Yang, M.: Function and influence of Fe, Co. Ni on the glaze and glass-ceramics. Foshan Ceramics. 9, 43–46 (2011)
Tian, Y.L.: New Glass Technology. China Light Industry Press, Beijing (2013)
Bernardo, E.: Fast sinter-crystallization of a glass from waste materials. J. Non-Cryst. Solids. 354, 3486–3490 (2008)
Bernardo, E., Scarinci, G.: Fast sinter-crystallization of waste glasses. Adv. Appl. Ceram. 107, 344–349 (2008)
Acknowledgements
The authors thank Soochow University and China University of Petroleum for their support with the analysis.
Funding
This work was financially supported by the National Natural Science Foundation of China (No. 51704202, 51604169, 51604178) and the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No. 17KJB450002).
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Pei, F., Zhu, G., Li, P. et al. Effect of Fe2O3 and MgO on the crystallization behaviour, sinterability and properties of the CaO-Al2O3-SiO2 glass-ceramics. J Aust Ceram Soc 56, 979–986 (2020). https://doi.org/10.1007/s41779-019-00423-6
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DOI: https://doi.org/10.1007/s41779-019-00423-6