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Kinetics of the Sodium Chlorate Formation in Electrolysis of Chloride Solutions with Use of Dimensionally Stable Anodes

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Abstract

The kinetics of the formation of sodium chlorate during electrolysis of chloride solutions with use of dimensionally stable anodes is studied. An analysis and calculations suggest that the experimental results are well described by the proposed set of differential equations under the assumption that the homogeneous chemical reaction of chlorate formation has second, rather than third, order by active chlorine.

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REFERENCES

  1. Evdokimov, S.V., Elektrokhimiya, 1999, vol. 35, p. 366.

    Google Scholar 

  2. Evdokimov, S.V., Elektrokhimiya, 1999, vol. 35, p. 202.

    Google Scholar 

  3. Kokoulina, D.V. and Krishtalik, L.I., Elektrokhimiya, 1971, vol. 7, p. 346.

    Google Scholar 

  4. Kheifets, L.I., Gol'dberg, A.B., and Mazanko, A.F., Itogi Nauki Tekh., Ser.: Elektrokhimiya, 1983, p. 244.

  5. Yakimenko, L.M. and Seryshev, G.A., Elektrokhimicheskii sintez neorganicheskikh soedinenii (The Inorganic Electrosynthesis), Moscow: Khimiya, 1984, p. 35.

    Google Scholar 

  6. Vetter, K., Elektrochemische Kinetik, Berlin: Springer, 1961.

    Google Scholar 

  7. Damaskin, B.B. and Petrii, O.A., Vvedenie v elektrokhimicheskuyu kinetiku (Electrochemical Kinetics: An Introduction), Moscow: Vysshaya Shkola, 1975, p. 319.

    Google Scholar 

  8. Bagotzky, V.S., Osnovy elektrokhimii (Fundamentals of Electrochemistry), Moscow: Khimiya, 1988, p. 272.

    Google Scholar 

  9. Antropov, L.I., Teoreticheskaya electrokhimiya (Theoretical Electrochemistry), Moscow: Vysshaya Shkola, 1984, p. 324.

    Google Scholar 

  10. Rotinyan, A.L., Tikhonov, K.I., and Shoshina, I.A., Teoreticheskaya elektrokhimiya (Theoretical Electrochemistry), Leningrad: Khimiya, 1981, pp. 268, 302.

    Google Scholar 

  11. Evdokimov, S.V., Elektrokhimiya, 2001, vol. 37, p. 420.

    Google Scholar 

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Authors and Affiliations

  1. Russian Federation Scientific Center, “Karpov Research Institute of Physical Chemistry,”, ul. Vorontsovo Pole 10, Moscow, 103064, Russia

    S. V. Evdokimov

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  1. S. V. Evdokimov
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Evdokimov, S.V. Kinetics of the Sodium Chlorate Formation in Electrolysis of Chloride Solutions with Use of Dimensionally Stable Anodes. Russian Journal of Electrochemistry 37, 786–791 (2001). https://doi.org/10.1023/A:1016774717213

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  • DOI: https://doi.org/10.1023/A:1016774717213

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