Abstract
The results of an analysis of variations and linear trends in the column content and vertical distribution of NO2 are presented based on 30-year spectrometric measurements at Zvenigorod Scientific Station, A.M. Obukhov Institute of Atmospheric Physics, located in the western Moscow region. In particular, we derive seasonally dependent estimates of NO2 trends and relationships of NO2 with the quasi-biennial oscillation, the North Atlantic Oscillation, the El Niño–Southern Oscillation, and the 11-year cycle of solar activity.
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REFERENCES
G. P. Brasseur and S. Solomon, Aeronomy of the Middle Atmosphere (Springer, Dordrecht, 2005).
J. Pyle, Th. Shepherd, G. Bodeker, P. Canciani, M. Dameris, P. Forster, A. Gruzdev, R. Müller, N. J. Muthama, G. Pitari, W. Randel, “Ozone and climate: A review of interconnections,” in Safeguarding the Ozone Layer and the Global Climate System. Issues Related to Hydrofluorocarbons and Perfluorocatbons. IPCC Special Report (IPCC, 2005), pp. 83–132.
T. E. Gradeel and J. P. Crutzen, Atmospheric Change. An Earth System Perspective (W.H. Freeman and Company, New York, 1993).
G. P. Brasseur, J. J. Orlando, and G. S. Tyndall, New York (Oxford University Press, New York, 1999).
A. N. Gruzdev, E. P. Kropotkina, S. V. Solomonov, and A. S. Elokhov, “Anomalies of the ozone and nitrogen dioxide contents in the stratosphere over Moscow region as a manifestation of the dynamics of the stratospheric polar vortex,” Dokl. Earth Sci. 468 (4), 602–606 (2016).
A. W. Brewer, C. T. McElroy, and J. J. Kerr, “Nitrogen dioxide concentrations in the atmosphere,” Nature 246, 129–133 (1973).
J. F. Noxon, “Nitrogen dioxide in the stratosphere and troposphere measured by ground-based absorption spectroscopy,” Science 189, 547–549 (1975).
G. I. Kuznetsov and K. S. Nigmatullina, “Determination of nitrogen dioxide content in the atmosphere using optical methods,” Izv. Akad. Nauk SSSR: Fiz. Atmos. Okeana 13 (8), 896–899 (1977).
A. N. Borovskii, A. Ya. Arabov, G. S. Golitsyn, A. N. Gruzdev, N. F. Elanskii, A. S. Elokhov, I. I. Mokhov, V. V. Savinykh, I. A. Senik, and A. V. Timazhev, “Variations of total nitrogen oxide content in the atmosphere over the North Caucasus,” Russ. Meteorol. Hydrol. 41 (2), 93–103 (2016).
A. S. Elokhov and A. N. Gruzdev, “Nitrogen dioxide column content and vertical profile measurements at the Zvenigorod Research Station,” Izv., Atmos. Ocean. Phys. 36 (6), 763–777 (2000).
J. B. Liley, P. V. Johnston, R. L. McKenzie, A. J. Thomas, and I. S. Boyd, “Stratospheric NO2 variations from at Lauder, New Zealand,” J. Geophys. Res. 105 (D9), 11633–11640 (2000).
J. M. Zawodny and M. P. McCormick, “Stratospheric Aerosol and Gas Experiment-II measurements of the quasi-biennial oscillations in ozone and nitrogen dioxide,” J. Geophys. Res 96 (D5), 9371–9377 (1991).
A. N. Gruzdev, “Quasi-biennial variations in the total NO2 content,” Dokl. Earth Sci. 438 (5), 837–841 (2011).
V. Yu. Ageyeva and A. N. Gruzdev, “Seasonal features of quasi-biennial variations of NO2 stratospheric content derived from ground-based measurements,” Izv., Atmos. Ocean. Phys. 53 (1), 65–75 (2017).
P. A. Cook and H. K. Roscoe, “Variability and trends in stratospheric NO2 in Antarctic summer, and implications for stratospheric NOy,” Atmos. Chem. Phys. 9, 2601–3612 (2009).
A. N. Gruzdev, “Accounting for autocorrelation in the linear regression problem by an example of analysis of the atmospheric column NO2 content,” Izv., Atmos. Ocean. Phys. 55 (1), 65–72 (2019).
L. L. Hood and B. E. Soukharev, “Solar induced variations of odd nitrogen: Multiple regression analysis of UARS HALOE data,” Geophys. Res. Lett. 33, L22805 (2006).
A. N. Gruzdev, “Latitudinal dependence of variations in stratospheric NO2 content,” Izv., Atmos. Ocean. Phys. 44 (3), 319–333 (2008).
A. N. Gruzdev, “Latitudinal structure of variations and trends in stratospheric NO2,” Int. J. Remote Sens. 30 (15), 4227–4246 (2009).
E. Kyrölä, J. Tamminen, V. Sofieva, et al., “GOMOS O3, NO2, and NO3 observations in 2002–2008,” Atmos. Chem. Phys. 10 (16), 7723–7738 (2010).
P. V. Johnston, R. L. McKenzie, J. G. Keys, and W. A. Matthews, “Observations of depleted stratospheric NO2 following the Pinatubo volcanic eruption,” Geophys. Res. Lett. 19 (2), 211–213 (1992).
S. Solomon, R. W. Sanders, R. O. Jakoubek, K. H. Arpag, S. L. Stephens, J. G. Keys, and R. R. Garcia, “Visible and near-ultraviolet spectroscopy at McMurdo Station, Antarctica. 10. Reductions of stratospheric NO2 due to Pinatubo serosols 1994,” J. Geophys. Res. 99 (2), 3509–3516 (1994).
M. van Roozendael, C. Hermans, M. de Mazière, and P. C. Simon, “Stratospheric NO2 observations at the Jungfraujoch station between June 1990 and May 1992,” Geophys. Res. Lett. 21 (13), 1383–1386 (1994).
A. S. Elokhov and A. N. Gruzdev, “Estimation of tropospheric and stratospheric NO2 from spectrometric measurements of column NO2 abundances,” Proc. SPIE 2506, 444–454 (1995).
A. S. Elokhov and A. N. Gruzdev, “Measurements of column contents and vertical distribution of NO2 at Zvenigorod Scientific Station,” Proc. SPIE 3583, 547–554 (1998).
A. N. Gruzdev, “Estimate of the effects of Pinatubo eruption in stratospheric O3 and NO2 contents taking into account the variations in the solar activity,” Atmos. Oceanic Opt. 27 (6), 403–411 (2014).
W. J. Randel, F. Wu, J. M. Russell, and J. Waters, “Space–time patterns of trends in stratospheric constituents derived from UARS measurements,” J. Geophys. Res. 104 (D3), 3711–3727 (1999).
F. Hendrick, E. Mahieu, G. E. Bodeker, et al., “Analysis of stratospheric NO2 trends above Jungfraujoch using ground-based UV-visible, FTIR, and satellite nadir observations,” Atmos. Chem. Phys. 12, 8851–8864 (2012).
M. Yela, M. Gil-Ojeda, M. Navarro-Comas, et al., “Hemispheric asymmetry in stratospheric NO2 trends,” Atmos. Chem. Phys. 17, 13373–13389 (2017).
A. N. Gruzdev and A. S. Elokhov, “Validation of ozone monitoring instrument NO2 measurements using ground based NO2 measurements at Zvenigorod, Russia,” Int. J. Remote Sens. 31 (2), 497–511 (2010).
A. N. Gruzdev and A. S. Elokhov, “Variability of stratospheric and tropospheric nitrogen dioxide observed by visible spectrophotometer at Zvenigorod, Russia,” Int. J. Remote Sens. 32 (11), 3115–3127 (2011).
A. N. Gruzdev and A. S. Elokhov, “Validating NO2 measurements in the vertical atmospheric column with the OMI instrument aboard the EOS Aura satellite against ground-based measurements at the Zvenigorod Scientific Station,” Atmos. Ocean. Phys. 45 (4), 444–455 (2009).
A. N. Gruzdev and A. S. Elokhov, “New results from the validation of NO2 content measurement data obtained with the help of OMI instrument from measurement data of the Zvenigorod Scientific Station,” Issled. Zemli Kosmosa, No. 1, 16–27 (2013).
S. M. Kay and S. L. Marple, “Spectrum analysis–A modern perspective,” Proc. IEEE 69 (11), 1380–1419 (1981).
A. N. Gruzdev, “Estimate of the effect of the 11-year solar activity cycle on the ozone content in the stratosphere,” Geomagn. Aeron. (Engl. Transl.) 54 (5), 633–639 (2014).
G. E. Bodeker, I. S. Boyd, and W. A. Matthews, “Trends and variability in vertical ozone and temperature profiles measured by ozonesondes at Lauder, New Zealand: 1986–1996,” J. Geophys. Res. 103 (D22), 28661–28681 (1998).
N. R. P. Harris, B. Hassler, F. Tummon, et al., “Past changes in the vertical distribution of ozone. Part 3: Analysis and interpretation of trends,” Atmos. Chem. Phys. 15, 9965–9982 (2015).
A. N. Gruzdev, “Accounting for long-term serial correlation in a linear regression problem,” IOP Conf. Ser. Earth Environ. Sci. 231, 1–10 (2019). https://iopscience.iop. org/article/10.1088/1755-1315/231/1/012020/meta.
C. A. McLinden, S. C. Olsen, M. J. Prather, and J. B. Liley, “Understanding trends in stratospheric NOy and NO2,” J. Geophys. Res. 106 (D21), 27787–27793 (2001).
A. N. Gruzdev, “Sensitivity of stratospheric ozone to long-term changes in nitrogen oxide and hydrogen chloride,” Dokl. Earth Sci. 427 (3), 975–978 (2009).
A. Hilboll, A. Richter, and J. P. Burrows, “Long-term changes of tropospheric NO2 over megacities derived from multiple satellite instruments,” Atmos. Chem. Phys. 13, 4145–4169 (2013).
P. Schneider, W. A. Lahoz, and R. van der A, “Recent satellite-based trends of tropospheric nitrogen dioxide over large urban agglomerations worldwide,” Atmos. Chem. Phys. 15, 1205–1220 (2015).
M. H. P. Ambaum and B. J. Hoskins, “The NAO troposphere–stratosphere connection,” J. Clim. 15, 19679–1978 (2002).
J. F. Noxon, “Stratospheric NO2. 2. Global behavior,” J. Geophys. Res. 84 (C8), 5067–5076 (1979).
A. N. Gruzdev, E. P. Kropotkina, S. V. Solomonov, and A. S. Elokhov, “Winter–spring anomalies in stratospheric O3 and NO2 contents over the Moscow region in 2010 and 2011,” Izv., Atmos. Ocean. Phys. 53 (2), 195–203 (2017).
V. Yu. Ageyeva, A. N. Gruzdev, A. S. Elokhov, I. I. Mokhov, and N. E. Zueva, “Sudden stratospheric warmings: statistical characteristics and influence on NO2 and O3 total contents,” Atmos. Ocean. Phys. 53 (5), 477–486 (2017).
D. V. Domeisen, C. I. Garfinkel, and A. H. Butler, “The teleconnection of El Niño Southern Oscillation to the stratosphere,” Rev. Geophys. 57, 5–47 (2019).
K. Song and S.-W. Son, “Revisiting the ENSO–SSW relationship,” J. Clim. 31, 2133–2143 (2018).
M. Iza, N. Calvo, and E. Manzini, “The stratospheric pathway of La Niña,” J. Clim. 29, 8899–8914 (2016).
C. P. Rinsland, M. R. Gunson, M. C. Abrams, L. L. Lowes, R. Zander, E. Mahieu, A. Goldman, M. K. W. Ko, J. M. Rodriguez, and N. D. Sze, “Heterogeneous conversion of N2O5 to HNO3 in the post-Mount Pinatubo eruption stratosphere,” J. Geophys. Res. 99 (D4), 8213–8219 (1994).
M. Koike, N. B. Jones, W. A. Matthews, P. V. Johnston, R. L. McKenzie, D. Kinnison, and J. Rodriguez, “Impact of Pinatubo aerosols on the partitioning between NO2 and HNO3,” Geophys. Res. Lett. 21 (7), 597–600 (1994).
J. J. Bauman, P. B. Russell, M. A. Geller, and P. Hamill, “A stratospheric aerosol climatology from SAGE II and CLAES measurements: 2. Results and comparison, 1984–1999,” J. Geophys. Res. 108 (D13), 4383 (2003).
A. N. Gruzdev, V. Yu. Ageyeva, and A. S. Elokhov, “Changes in vertical distribution and column content of NO2 under the influence of sudden stratospheric warmings,” Izv., Atmos. Ocean. Phys. 54 (4), 354–363 (2018).
ACKNOWLEDGMENTS
The measurement data of the column content of NO2 and the NO2 content in the surface layer of the atmosphere are archived by the NDACC. The data of the F10.7 solar activity index are freely provided by the NOAA National Center for Environmental Information and Natural Resources, Canada. The data of the zonal velocity of equatorial stratospheric wind are prepared by the Free University of Berlin (Freie Universität Berlin). The Niño3.4 index is provided by the NOAA Physical Science Laboratory. The NAO index data are provided by the Climatic Research Unit, University of East Anglia. The data of the aerosol optical depth were prepared by the NASA Goddard Institute for Space Studies.
We are grateful to a reviewer and the member of the editorial board for helpful comments.
Funding
This work was supported by the Russian Foundation for Basic Research, project no. 20-05-00274.
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Translated by A. Nikol’skii
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Gruzdev, A.N., Elokhov, A.S. Changes in the Column Content and Vertical Distribution of NO2 According to the Results of 30-Year Measurements at the Zvenigorod Scientific Station of the A. M. Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences. Izv. Atmos. Ocean. Phys. 57, 91–103 (2021). https://doi.org/10.1134/S0001433821010084
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DOI: https://doi.org/10.1134/S0001433821010084