Abstract
The temperature dependences of nickel, iron, chromium, molybdenum, and tungsten solubility in a liquid Sn–20% Li alloy are calculated with the thermodynamic simulation method based on information on the excess Gibbs mixing energies for a liquid phase in the form of polynomial Redlich–Kister expansion for corresponding binary systems. A thermodynamic estimation of the stability of a series of binary and ternary oxides in a liquid Li20Sn80 alloy at temperatures of 500 and 800°C is also performed.
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Notes
Superscript SER represents “standard element reference.”
Atoms in the melt constantly move; therefore, it makes sense to consider a short-lived atomic configuration averaged for some time t. For these configurations, a reasonable estimate of the averaging time is in the range of τ0 < t < τD (τ0 is the atomic vibration period in the equilibrium position and τD is the settled life time of the atom [32]). According to the data of [32], \({{\tau }_{{\text{0}}}} \approx {\text{1}}{{{\text{0}}}^{{ - {\text{13}}}}}\,\,{\text{s}}\) and \({{\tau }_{{\text{D}}}} \approx {\text{1}}{{{\text{0}}}^{{ - {\text{11}}}}}\,\,{\text{s}}{\text{.}}\)
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This study was performed within the basic part of a State assignment for the Moscow Polytechnic University, project no. FZRR-2020-0027.
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Krasin, V.P., Soyustova, S.I. Thermodynamic Estimation of the Stability of Metal and Ceramic Materials in the Binary Sn–20% Li Melt. High Temp 58, 342–351 (2020). https://doi.org/10.1134/S0018151X20030104
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DOI: https://doi.org/10.1134/S0018151X20030104