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Effect of the Composition of Oxide Layers Formed by Plasma Electrolytic Oxidation on the Mechanism of Peroxide Oxidative Desulfurization

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Abstract

The peroxide oxidation of thiophene, thioanisole, and dibenzothiophene in the presence of Ce, Zr, Ce + Zr, W, and W + Zn oxide layers formed by plasma electrolytic oxidation on the titanium surface was studied. The composition of the resulting composites was found to affect the activity and conversion of the organosulfur substrates. It was shown by the radical inhibition method that the composites differed in the mechanism of their catalytic action.

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Funding

This study was partially financially supported by the Far East program (grant no. 18-3-034) and the Russian Foundation for Basic Research (grant no. 19-33-90024).

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. A. Bryzhin & I. G. Tarkhanova

  2. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    V. S. Rudnev, I. V. Lukiyanchuk & M. S. Vasilyeva

  3. Far Eastern Federal University, 690090, Vladivostok, Russia

    V. S. Rudnev & M. S. Vasilyeva

Authors
  1. A. A. Bryzhin
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  2. V. S. Rudnev
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  3. I. V. Lukiyanchuk
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  4. M. S. Vasilyeva
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  5. I. G. Tarkhanova
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Corresponding author

Correspondence to I. G. Tarkhanova.

Additional information

Translated by L. Smolina

Abbreviations: PEO, plasma electrolytic oxidation.

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Bryzhin, A.A., Rudnev, V.S., Lukiyanchuk, I.V. et al. Effect of the Composition of Oxide Layers Formed by Plasma Electrolytic Oxidation on the Mechanism of Peroxide Oxidative Desulfurization. Kinet Catal 61, 283–290 (2020). https://doi.org/10.1134/S0023158420020020

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