Abstract
The interaction of the [B10H9O2C4H8]−, [B10H9OC4H8]−, and [B10H9OC5H10]− anions with negatively charged N-nucleophiles has been studied. It has been shown that such reactions yield doubly charged substituted closo-decaborates with a nitrogen-containing group attached to the cluster through an alkoxyl spacer. Compounds with pendant NO2 −, N3 −, N(CO)2C6H4 −, and NHC6H5 groups have been synthesized.
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Original Russian Text © E.Yu. Matveev, V.M. Retivov, G.A. Razgonyaeva, K.Yu. Zhizhin, N.T. Kuznetsov, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 10, pp. 1628–1633.
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Matveev, E.Y., Retivov, V.M., Razgonyaeva, G.A. et al. Cleavage of the cyclic substituent in the [B10H9O2C4H8]−, [B10H9OC4H8]−, and [B10H9OC5H10]− anions upon the interaction with negatively charged N-nucleophiles. Russ. J. Inorg. Chem. 56, 1549–1554 (2011). https://doi.org/10.1134/S0036023611100160
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DOI: https://doi.org/10.1134/S0036023611100160