Abstract
The effect of the addition of cerium acetylacetonate on the solvothermal synthesis of zinc oxide nanopowder, a promising receptor material for chemical gas sensors, was studied. The obtained products were characterized by DSC/TGA, X-ray powder diffraction analysis, Raman spectroscopy, and scanning and transmission electron microscopy. It was found that an increase in the content of the cerium acetylacetonate additive causes a shift of the maximum of the exothermic event in the DSC curves toward lower temperatures (from 323 to 277°C). The produced ZnO powders have a hexagonal crystal structure of the wurtzite type; no cerium-containing phases were observed. The unit cell parameters of ZnO nanopowders were calculated by the full-profile X-ray phase analysis. It was shown that an increase in the [Ce(O2C5H7)2] leads to noticeable changes in the microstructure of the products.
Similar content being viewed by others
REFERENCES
A. B. Djurišić, X. Chen, Y. H. Leung, et al., J. Mater. Chem. 22, 6526 (2012). https://doi.org/10.1039/c2jm15548f
Z. L. Wang, J. Phys. Condens. Matter 16, R829 (2004). https://doi.org/10.1088/0953-8984/16/25/R01
R. Ahmad, S. M. Majhi, X. Zhang, et al., Adv. Colloid Interface Sci. 270, 1 (2019). https://doi.org/10.1016/j.cis.2019.05.006
A. B. Djurišić, A. M. C. Ng, and X. Y. Chen, Prog. Quantum Electron. 34, 191 (2010). https://doi.org/10.1016/j.pquantelec.2010.04.001
J. Lv, C. Li, and Z. Chai, J. Lumin. 208, 225 (2019). https://doi.org/10.1016/j.jlumin.2018.12.050
S. Xu and Z. L. Wang, Nano Res. 4, 1013 (2011). https://doi.org/10.1007/s12274-011-0160-7
S. K. Arya, S. Saha, J. E. Ramirez-Vick, et al., Anal. Chim. Acta 737, 1 (2012). https://doi.org/10.1016/j.aca.2012.05.048
Y. Deng, Semiconducting Metal Oxides for Gas Sensing (Springer, Singapore, 2019). https://doi.org/10.1007/978-981-13-5853-1
S. Y. Jeong, J. S. Kim, and J. H. Lee, Adv. Mater. 32, 2002075 (2020). https://doi.org/10.1002/adma.202002075
M. Zinkevich, D. Djurovic, and F. Aldinger, Solid State Ionics 177, 989 (2006). https://doi.org/10.1016/j.ssi.2006.02.044
T. Montini, M. Melchionna, M. Monai, et al., Chem. Rev. 116, 5987 (2016). https://doi.org/10.1021/acs.chemrev.5b00603
F. Charbgoo, M. Ramezani, and M. Darroudi, Biosens. Bioelectron. 96, 33 (2017). https://doi.org/10.1016/j.bios.2017.04.037
C. Sun, H. Li, and L. Chen, Energy Environ. Sci. 5, 8475 (2012). https://doi.org/10.1039/c2ee22310d
K. S. Lin and S. Chowdhury, Int. J. Mol. Sci. 11, 3226 (2010). https://doi.org/10.3390/ijms11093226
C. E. Barrios, M. A. Baltanas, M. V. Bosco, et al., Catal. Lett. 148, 2233 (2018). https://doi.org/10.1007/s10562-018-2441-1
Anushree, S. Kumar, and C. Sharma, Appl. Nanosci. 7, 567 (2017). https://doi.org/10.1007/s13204-017-0596-5
F. Ghayour, M. R. M. Shafiee, and M. Ghashang, Main Gr. Met. Chem. 41, 21 (2018). https://doi.org/10.1515/mgmc-2017-0038
P. Rosha, S. K. Mohapatra, S. K. Mahla, et al., Biomass Bioenergy 125, 70 (2019). https://doi.org/10.1016/j.biombioe.2019.04.013
P. Challa, M. V. Rao, P. Nagaiah, et al., J. Chem. Sci. 131, Article no. 86 (2019). https://doi.org/10.1007/s12039-019-1651-4
M. K. Gnanamani, R. Garcia, G. Jacobs, et al., Appl. Catal. A Gen. 602, 117722 (2020). https://doi.org/10.1016/j.apcata.2020.117722
N. Enjamuri, S. Hassan, A. Auroux, et al., Appl. Catal. A Gen. 523, 21 (2016). https://doi.org/10.1016/j.apcata.2016.05.003
V. Kumari, S. Yadav, A. Mittal, et al., J. Mater. Sci. Mater. Electron. 31, 5227 (2020). https://doi.org/10.1007/s10854-020-03083-6
S. R. Ardekani, A. S. R. Aghdam, M. Nazari, et al., Sol. Energy Mater. Sol. Cells 203, 110195 (2019). https://doi.org/10.1016/j.solmat.2019.110195
M. Sharma, A. Kumar, R. K. Gautam, et al., J. Nanosci. Nanotechnol. 18, 3532 (2017). https://doi.org/10.1166/jnn.2018.14675
R. Mueen, A. Morlando, H. Qutaish, et al., J. Mater. Sci. 55, 6834 (2020). https://doi.org/10.1007/s10853-020-04493-x
S. Rajendran, M. M. Khan, F. Gracia, et al., Sci. Rep. 6, Article no. 31641 (2016). https://doi.org/10.1038/srep31641
E. Cerrato, N. Paulo, F. Gonçalves, et al., Catalysts 10, 1222 (2020). https://doi.org/10.3390/catal10101222
A. Das, M. Patra, P. M. Kumar, et al., J. Alloys Compd., 40, 157730 (2020). https://doi.org/10.1016/j.jallcom.2020.157730
P. Velusamy and G. Lakshmi, Appl. Water Sci. 7, 4025 (2017). https://doi.org/10.1007/s13201-017-0554-0
S. Stefa, M. Lykaki, V. Binas, et al., Appl. Sci. 10, 7605 (2020). https://doi.org/10.3390/app10217605
S. Lan, X. Sheng, Y. Lu, et al., Colloids Interface Sci. Commun. 26, 32 (2018). https://doi.org/10.1016/j.colcom.2018.08.002
Z. Shu, Y. Zhang, J. Ouyang, et al., Appl. Surf. Sci. 420, 833 (2017). https://doi.org/10.1016/j.apsusc.2017.05.219
D. Y. Wang, Z. F. Lin, X. B. Li, et al., Surf. Eng. 32, 32 (2016). https://doi.org/10.1179/1743294414Y.0000000337
M. Ismail, I. Talib, A. M. Rana, et al., Nanoscale Res. Lett. 13, Article no. 318 (2018). https://doi.org/10.1186/s11671-018-2738-4
S. Arunpandiyan, S. Bharathi, A. Pandikumar, et al., Mater. Sci. Semicond. Process 106, 104765 (2020). https://doi.org/10.1016/j.mssp.2019.104765
F. S. Sangsefidi, M. Salavati-Niasari, M. Ghasemifard, et al., Int. J. Hydrogen Energy 43, 22955 (2018). https://doi.org/10.1016/j.ijhydene.2018.10.082
Q. Diao, Y. Yin, X. Zhang, et al., Funct. Mater. Lett. 13, 2 (2020). https://doi.org/10.1142/S1793604720500137
D. Wang, Y. Yin, P. Xu, et al., J. Mater. Chem. A 8, 11188 (2020). https://doi.org/10.1039/d0ta01708f
J. Qian, Y. Wang, J. Pan, et al., Mater. Chem. Phys. 239, 122051 (2020). https://doi.org/10.1016/j.matchemphys.2019.122051
Y. Zhang, Y. Liu, L. Zhou, et al., Sens. Actuators, B: Chem. 273, 991 (2018). https://doi.org/10.1016/j.snb.2018.05.167
L. Zhu, H. Li, P. Xia, et al., ACS Appl. Mater. Interfaces 10, 39679 (2018). https://doi.org/10.1021/acsami.8b13782
W. Lu, D. Zhu, and X. Xiang, J. Mater. Sci. Mater. Electron. 28, 18929 (2017). https://doi.org/10.1007/s10854-017-7846-x
W. Li, S. Ma, G. Yang, et al., Mater. Lett. 138, 188 (2015). https://doi.org/10.1016/j.matlet.2014.09.130
O. Sachuk, V. Zazhigalov, L. Kuznetsova, et al., Adsorpt. Sci. Technol. 35, 845 (2017). https://doi.org/10.1177/0263617417719823
M. Hasanpoor, M. Aliofkhazraei, and M. Hosseinali, J. Am. Ceram. Soc. 100, 901 (2017). https://doi.org/10.1111/jace.14625
H. M. Chenari, L. Riasvand, and S. Khalili, Ceram. Int. 45, 14223 (2019). https://doi.org/10.1016/j.ceramint.2019.04.130
K. Kaviyarasu, X. Fuku, G. T. Mola, et al., Mater. Lett. 183, 351 (2016). https://doi.org/10.1016/j.matlet.2016.07.143
A. Sivakumar, B. Murugesan, A. Loganathan, et al., J. Taiwan Inst. Chem. Eng. 78, 462 (2017). https://doi.org/10.1016/j.jtice.2017.05.030
C. A. Schneider, W. S. Rasband, and K. W. Eliceiri, Nat. Methods 9, 671 (2012). https://doi.org/10.1038/nmeth.2089
M. Šćepanović, M. Grujić-Brojčin, K. Vojisavljević, et al., J. Raman Spectrosc. 41, 914 (2010). https://doi.org/10.1002/jrs.2546
Ü. Özgür, Y. I. Alivov, C. Liu, et al., J. Appl. Phys. 98, 1 (2005). https://doi.org/10.1063/1.1992666
V. Russo, M. Ghidelli, P. Gondoni, et al., J. Appl. Phys. 115, 073508 (2014). https://doi.org/10.1063/1.4866322
A. Hammouda, A. Canizarès, P. Simon, et al., Vib. Spectrosc. 62, 217 (2012). https://doi.org/10.1016/j.vibspec.2012.07.004
H. F. Liu, A. Huang, S. Tripathy, et al., J. Raman Spectrosc. 42, 2179 (2011). https://doi.org/10.1002/jrs.2991
F. Güell, P. R. Martínez-Alanis, S. Khachadorian, et al., Phys. Status Solidi Basic Res. 253, 883 (2016). https://doi.org/10.1002/pssb.201552651
R. Thangavel, R. S. Moirangthem, W.-S. Lee, et al., J. Raman Spectrosc. 41, 1594 (2010). https://doi.org/10.1002/jrs.2599
R. Sreedharan, R. Vinodkumar, I. Navas, et al., JOM 68, 341 (2016). https://doi.org/10.1007/s11837-015-1632-0
K. A. Alim, V. A. Fonoberov, M. Shamsa, et al., J. Appl. Phys. 97, 124313` (2005). https://doi.org/10.1063/1.1944222
E. Alarcón-Lladó, J. Ibáñez, R. Cuscó, et al., J. Raman Spectrosc. 42, 153 (2011). https://doi.org/10.1002/jrs.2664
T. L. Simonenko, N. P. Simonenko, A. S. Mokrushin, et al., Ceram. Int. 46, 121 (2020). https://doi.org/10.1016/j.ceramint.2019.08.241
A. S. Mokrushin, E. P. Simonenko, N. P. Simonenko, et al., J. Alloys Compd. 773, 1023 (2019). https://doi.org/10.1016/j.jallcom.2018.09.274
Funding
This work was supported by the Russian Science Foundation (project no. 20-73-00309).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by V. Glyanchenko
Rights and permissions
About this article
Cite this article
Mokrushin, A.S., Nagornov, I.A., Averin, A.A. et al. Effect of the Addition of Cerium Acetylacetonate on the Synthesis of ZnO Nanopowder. Russ. J. Inorg. Chem. 66, 638–644 (2021). https://doi.org/10.1134/S0036023621050119
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023621050119