Abstract
The paper reports results of an experimental study of amphibole crystallization from the highly magnesian andesite melt of Shiveluch volcano, Kamchatka. The experiments were carried out in IHPV at 300 MPa and 940–980°С in iron-saturated platinum capsules, using rapid quenching and temperature oscillations (in some experiments). The redox state of iron in the system was measured before and after the experiments using Mössbauer spectroscopy. The maximum size of the experimental amphibole crystals (up to 200 μm) was close to those of natural amphibole phenocrysts in the volcanic rocks of Shiveluch volcano. The experimental data show that the content of octahedrally coordinated Al (Al6) in the amphibole considerably varies with small variations in the intensive parameters (P, T, and \(f{{{\text{O}}}_{2}}\)) and composition of the melt, and the maximum Al6 concentration can be evaluated only by using a reasonably large dataset of amphibole analyses. A modified 13eCNK method is suggested to calculate the values of Al6 and Fe3+/Fe2+ with regard for the Ti concentration and the probable partial transfer of Mg into site B in high-Mg amphibole. Calculations with this modified technique yield lower Fe3+/Fe2+ and higher Al6 values. Our experimental data show that the temperature of amphibole liquidus crystallization decreases from about 990°C to 960°C when the oxygen fugacity drops from NNO + 1.5 to NNO + 0.4. In view of this, the transition from amphibole-bearing to anhydrous mineral assemblage in the magmas of Shiveluch volcano might have been caused by variations of the oxygen fugacity but not water. The application of our geobarometer to amphiboles from Shiveluch volcano (extrusions Krasnaya and Karan) yields the highest pressure estimate of above 1 GPa, corresponding to the P–T conditions of the melting of garnet-bearing amphibolite in the lower crust.
Similar content being viewed by others
REFERENCES
Adam, J., Oberti, R., Cámara, F., and Green, T.H., An electron microprobe, LAM-ICP-MS and single-crystal X‑ray structure refinement study of the effects of pressure, melt–H2O concentration and fO2 on experimentally produced basaltic amphiboles, Eur. J. Mineral, 2007, vol. 19, pp. 641–655.
Almeev, R.R., Holtz, F., Ariskin, A.A., and Kimura, J.-I., Storage conditions of Bezymianny volcano parental magmas: results of phase equilibria experiments at 100 and 700 MPa, Contrib. Mineral. Petrol., 2013, vol. 166, pp. 1389–1414. https://doi.org/10.1007/s00410-013-0934-x
Anderson, J.L. and Smith, D.R., The effects of temperature and fO2 on the Al-in-hornblende barometer, Am. Mineral., 1995, vol. 80, pp. 549–559.
Balesta, S.T., Zubin, M.M., Kargopol’tsev, A.A., and Fedorchenko, I.A., Deep structure of eruption region, Bol’shoe Tolbachinskoe izverzhenie, Kamchatka 1975–1976 gg (Great Tolbachik Fissure Eruption, 1975–1976), Moscow: Nauka, 1984, pp. 514–536.
Berndt, J., Liebske, C., Holtz, F., et al., A combined rapid-quench and H2-membrane setup for internally heated pressure vessels: description and application for water solubility in basaltic melts, Am. Mineral., 2002, vol. 87, pp. 1717–1726.
Bogolepov, M.I. and Epel’baum, M.B., Melting in the fluid–silicate system and modeling granitizaion, Ocherki fiz.-khim. petrologii (Essays of Physicochemical Petrology), 1991, vol. 16, pp. 6–15.
Chekhmir, A.S., Simakin, A.G., and Epel’baum, M.B., Dinamicheskie yavleniya vo flyuidno-magmaticheskikh sistemakh (Dynamic Phenomena in Fluid-Magmatic Systems), Moscow: Nauka, 1991.
Coldwell, B., Clemens, J., and Petford, N., Deep crustal melting in the Peruvian Andes: felsic magma generation during delamination and uplift, Lithos, 2011, vol. 125, pp. 272–286.
Cottrell, E. and Kelley, K.A., The oxidation state of Fe in MORB glasses and the oxygen fugacity of the upper mantle, Chem. Geol., 2009, vol. 268, pp. 167–179.
Cottrell, E., Gardner, J.E., and Rutherford, M.J., Petrologic and experimental evidence for the movement and heating of the pre-eruptive Minoan rhyodacite (Santorini, Greece), Contrib. Mineral. Petrol., 1999, vol. 135, pp. 315–331.
Davidson, J., Turner, S., Handley, H., et al., Amphibole “sponge” in arc crust?, Geology, 2007, vol. 35, no. 9, pp. 787–790.
Della, Ventura, G., Redhammer, G.J., Iezzi, G., et al., A Mossbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite–ferri-clinoholmquistite join, Phys. Chem. Mineral., 2005, vol. 32, no. 2, pp. 103–113.
Epel’baum, M.B., Silikatnye rasplavy s letuchimi komponentami (Silicate Melts with Volatile Components), Moscow: Nauka, 1980.
Fedotov, S.A., Zharinov, N.A., and Gontovaya, L.I., The magmatic system of the Klyuchevskaya group of volcanoes inferred from data on its eruptions, earthquakes, deformation, and deep structure, J. Volcanol. Seismol., 2010, vol. 4, no. 1, pp. 1–33.
Ford, C.E., Platinum-iron alloy sample containers for melting experiments on iron-bearing rocks, minerals, and related systems, Mineral. Mag., 1978, vol. 42, pp. 271–275.
Ghiorso, M.S. and Gualda, G.A.R., An H2O–CO2 mixed fluid saturation model compatible with rhyolite-melts, Contrib. Mineral. Petrol., 2015, vol. 168, no. 6, p. 53.
Gilbert, M.C., Synthesis and stability relations of the hornblende ferropargasite, Am. J. Sci., 1966, vol. 9, pp. 698–742. https://doi.org/10.2475/ajs.264.9.698
Gorbach, N.V. and Portnyagin, M.V., Geology and petrology of the lava complex of young Shiveluch Volcano, Kamchatka, Petrology, 2011, vol. 19, no. 2, pp. 134–166.
Grove, T.L., Elkins-Tanton, L.T., Parman, S.W., et al., Fractional crystallization and mantle-melting controls on calc-alkaline differentiation trends, Contrib. Mineral. Petrol., 2003, vol. 145, pp. 515–533. https://doi.org/10.1007/s00410-003-0448-z
Gualda, G.A.R. and Vlach, S.R.F., Stoichiometry-based estimates of ferric iron in calcic, sodic-calcic and sodic amphiboles: a comparison of various methods, An. Acad. Brasil. Ciencias, 2005, vol. 77, no. 3, pp. 521–534.
Hauser, N., Matteini, M., Omarini, R.H., and Pimentel, M.M., Constraints on metasomatized mantle under central South America: evidence from Jurassic alkaline lamprophyre dykes from the eastern Cordillera, NM Argentina, Mineral. Petrol., 2010, vol. 100, pp. 153–184.
Hawthorne, F.C., Oberti, R., Zanetti, A., and Czamanske, G.K., The role of Ti in hydrogendeficient amphiboles: sodic-calcic and sodic amphiboles from Coyote Peak, California, Can. Mineral., 1998, vol. 36, pp. 1253–1265.
Ivanov, B.V., Andesites of Kamchatka, Spravochnik khimicheskikh analizov vulkanitov i osnovnykh porodoobrazuyushchikh mineralov (A Handbook of Chemical Analyses of Volcanic rocks and Main Rock-Forming Mineral), Koloskov, A.V., Eds., Moscow: Nauka, 2008.
Jayasuriya, K.D., O’Neill, H.S.C., Berry, A.J., and Campbell, S.J., A Mössbauer study of the oxidation state of Fe in silicate melts, Am. Mineral., 2004, vol. 89, pp. 1597–1609.
Johnson, M.E. and Rutherford, M.J., Experimental calibration of the aluminum-in-hornblende geobarometer with application to Long Valley Caldera (California) volcanic rocks, Geology, 1989, vol. 17, pp. 837–841.
Koloskov, A.V., Anan’ev, V.V., and Puzankov, M.Yu., Amphibole in Quaternary hawaiites of the Kekuknai volcanic massif (Kamchatka) as indicator of decompressional evolution of melts of elevated alkalinity, Zap. Vseross. Mineral. O‑va, 2014, no. 2, pp. 94–115.
Koulakov, I., Multiscale seismic tomography imaging of volcanic complexes. updates in volcanology—a comprehensive approach to volcanological problems, Updates in Volcanology. A Comprechensive Approach to Volcanological Problems, Stoppa, F., Ed., IntechOpen, 2012, pp. 207–242. https://doi.org/10.5772/24653
Krawczynski, M.J., Grove, T.L., and Behrens, H., Amphibole stability in primitive arc magmas: effects of temperature, H2O content, and oxygen fugacity, Contrib. Mineral. Petrol., 2012, vol. 164, pp. 317–319. https://doi.org/10.1007/s00410-012-0740-x
Kuznetsov, A.D. and Epel’baum, M.B., Evtekticheskie sootnosheniya v otkrytykh sistemakh s vpolne podvizhnymi komponentami (Eutectic Relations in Open Systems with Perfectly Mobile Components), Moscow: Nauka, 1985.
Leake, B.E., Woolley, A.R., Arps, C.E.S., et al., Nomenclature of amphiboles: report of the subcommittee on amphiboles of the international mineralogical association, commission on new minerals and mineral names, Am. Mineral., 1997, vol. 82, nos. 9–10, pp. 1019–1037.
Levin, V., Droznina, S., Gavrilenko, M., Carr, M.J., and Senyukov, S., Seismically active subcrustal magma source of the Klyuchevskoy Volcano in Kamchatka, Russia, Geology, 2014. https://doi.org/10.1130/G35972.1
Melekestsev, I.V., Volynets, O.N., Ermakov, V.A., et al., Shiveluch Volcano, Deistvuyushchie vulkany Kamchatki (Active Volcanoes of Kamchatka), Moscow: Nauka, 1991, vol. 1, pp. 84–97.
Menyailov, A.A., Vulkan Shiveluch—ego geologicheskoe stroenie, sostav i izverzheniya (Shiveluch Volcano: its Geological Structure, Composition, and Eruptions), Tr. Laboratorii vulkanologii AN SSSR, 1955, vol. 9.
Mössbuaer Mineral Handbook // Eds. J.G. Stevens, A.M. Khasanov, J.W. Miller, et al. Mössbauer Effect Data Center. North Carolina. Asheville: University of North Carolina at Asheville, 2005.
Putirka, K., Thermometers and barometers for volcanic systems, Putirka, K. and Tepley, F., Eds., Minerals, Inclusions and Volcanic Processes, Rev. Mineral. Geochem. Mineral Soc. Am., 2008, vol. 69, pp. 61–120.
Ridolfi, F., Renzulli, A., and Puerini, M., Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes,Contrib. Mineral. Petrol., 2010, vol. 160, pp. 45–66. https://doi.org/10.1007/s00410-009-0465-7
Rutherford, J. and Hill, P.M., Magma ascent rates from amphibole breakdown: an experimental study applied to the 1980–1986 Mount St. Helens eruptions, J. Geophys. Res., 1993, vol. 98, pp. 19667–19685.
Schmidt, M.W., Amphibole composition in tonalite as a function of pressure: an experimental calibration of the Al-in-hornblende barometer, Contrib. Mineral. Petrol., 1992, vol. 110, pp. 304–310.
Simakin, A.G. and Salova, T.P., Evolution of bubble size distribution during the gradual degassing of granitic melt: experimental data, Geochem. Int., 2001, vol. 39, no. 3, pp. 258–267.
Simakin, A.G. and Shaposhnikova, O.Yu., Novel amphibole geobarometer for high-magnesium andesite and basalt magmas, Petrology, 2017, vol. 25, no. 2, pp. 226–240.
Simakin, A.G., Salova, T.P., and Armienti, P., Kinetics of clinopyroxene growth from a hydrous hawaiite melt, Geochem. Int., 2003, vol. 41, no. 12, pp. 1165–1175.
Simakin, A.G., Salova, T.P., and Babansky, A.D., Amphibole crystallization from a water-saturated andesite melt: experimental data at P = 2 kbar, Petrology, 2009, vol. 17, no. 6, pp. 591–605.
Simakin А.G., Zakrevskaya O., Salova T.P., Novel Amphibole Geo-barometer with Application to Mafic Xenoliths, Earth Sci. Res., 2012, vol. 1, no. 2, pp. 82–97.
Spear, F.S., An experimental study of hornblende stability and compositional variability in amphibolite, Am. J. Sci., 1981, vol. 281, pp. 697–734.
Tatsumi, Y., Shukuno, H., Tani, K., et al., Structure and growth of the Izu–Bonin–Mariana arc crust: 2. Role of crust–mantle transformation and the transparent Moho in arc crust evolution, J. Geophys. Res., 2008, vol. 113, p. B02203. https://doi.org/10.1029/2007JB00512
Volynets, O.N., Ponomareva, V.V., and Babansky, A.D., Magnesian basalts of Shiveluch andesite volcano, Kamchatka, Petrology, 1997, vol. 5, no. 2, pp. 183–196.
Votyakov, S.L., Suetin, V.P., and Mironov, A.B., Isomorphism of iron ions in the natural staurolite and amphibole according to Mössbauer spectroscopy data, Phys. Met. Metallurg., 2007, vol. 104, no. 4, pp. 425–434.
Yogodzinski, G.M., Lees, J.M., Churikova, T.G., et al., Geochemical evidence for the melting of subducting oceanic lithosphere at plate edges, Nature, 2001, vol. 409, pp. 500–504.
Zakrevskaya, O. and Salova, T.P., Novel amphibole geo-barometer with application to mafic xenoliths, Earth Sci. Res., 2012, vol. 1, no. 2, pp. 82–97.
Zhang, H.L., Solheid, P.A., Lange, R.A., et al., Accurate determination of Fe3+/ΣFe of andesitic glass by Mössbauer spectroscopy, Am. Mineral., 2006, vol. 100, pp. 1967–1977.
ACKNOWLEDGMENTS
The authors thank K.I. Shmulovich (Korzhinskii Institute of Experimental Mineralogy, Russian Academy of Sciences) for his review that allowed us to significantly improve the manuscript.
Funding
This study was carried out under government-financed Program AAAA-A18-118020590141-4 for the Korzhinskii Institute of Experimental Mineralogy, Russian Academy of Sciences, in 2019–2021.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
The authors declare that they have no conflict of interest.
Additional information
Translated by E. Kurdyukov
Rights and permissions
About this article
Cite this article
Simakin, A.G., Devyatova, V.N., Salova, T.P. et al. Experimental Study of Amphibole Crystallization from the Highly Magnesian Melt of Shiveluch Volcano, Kamchatka. Petrology 27, 442–459 (2019). https://doi.org/10.1134/S0869591119050072
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0869591119050072