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Bifunctional Cobalt-Containing Catalytic Systems Based on SAPO-11 Molecular Sieves in Fischer–Tropsch Synthesis of Fuels

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Abstract

The study investigated, for the first time with respect to Fischer–Tropsch synthesis of fuels, cobalt-containing catalytic systems based on SAPO-11 molecular sieves with differing secondary porous structure characteristics. Various methods, such as XRD, low-temperature nitrogen adsorption/desorption, SEM, TEM, H2-TPD, and NH3-TPD, were used to characterize the prepared catalysts, which were subsequently examined in hydrocarbon synthesis at 2.0 MPa, 240°C, and gas WHSV = 1000 h–1. The study demonstrated good prospects for micro/mesoporous-structured SAPO-11 as an acid catalyst component for fuel production.

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Funding

The study described here was performed with financial support from the Russian Science Foundation (RSF grant no. 19-73-00089), using equipment of the Nanotechnology Center for Collective Use, South Russian State Polytechnic University.

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Authors and Affiliations

  1. South Russian State Polytechnic University, Rostov oblast, 346428, Novocherkassk, Russia

    R. E. Yakovenko, I. N. Zubkov, O. P. Papeta, G. T. Khliyan & A. P. Savostyanov

  2. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Bashkortostan, 450075, Ufa, Russia

    M. R. Agliullin

Authors
  1. R. E. Yakovenko
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  2. M. R. Agliullin
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  3. I. N. Zubkov
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  4. O. P. Papeta
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  5. G. T. Khliyan
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  6. A. P. Savostyanov
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Corresponding author

Correspondence to R. E. Yakovenko.

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Additional information

Translated from Sovremennye Molekulyarnye Sita. Advanced Molecular Sieves, 2021, Vol. 3, No. 1, pp. 133–142.

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Yakovenko, R.E., Agliullin, M.R., Zubkov, I.N. et al. Bifunctional Cobalt-Containing Catalytic Systems Based on SAPO-11 Molecular Sieves in Fischer–Tropsch Synthesis of Fuels. Pet. Chem. 61, 378–387 (2021). https://doi.org/10.1134/S0965544121030063

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