Skip to main content
Log in

Expert List of Absorption Lines of the SO2 Molecule in the 2000–3000 cm–1 Spectral Region

  • SPECTROSCOPY OF AMBIENT MEDIUM
  • Published:
Atmospheric and Oceanic Optics Aims and scope Submit manuscript

Abstract

A detailed high-accuracy list of the SO2 molecule absorption lines was obtained in the 2000–3000 cm–1 spectral region, which is important for atmospheric applications, based on a combination of the high-accuracy data on experimental energy levels and variational calculations of the intensities of vibrational-rotational transitions. The expert list contains 70 565 absorption lines with an intensity cutoff 1.0E-27 cm/molecule. The results obtained are compared with the published data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. G. Ceselin, N. Tasinato, C. Puzzarini, A. P. Charmet, P. Stoppa, and S. Giorgianni, “CO2-, He-, and H2‑broadening coefficients of SO2 for ν1 band and ground state transitions for astrophysical applications,” J. Quant. Spectrosc. Radiat. Transfer 203, 367–376 (2017).

    Article  ADS  Google Scholar 

  2. R. W. Zurek, A. Chicarro, M. A. Allen, J. L. Bertaux, R. T. Clancy, F. Daerden, V. Formisano, J. B. Garvin, G. Neukum, and M. D. Smith, “Assessment of a 2016 mission concept: The search for trace gases in the atmosphere of mars,” Planet. Space Sci. 59, 284–291 (2011).

    Article  ADS  Google Scholar 

  3. V. A. Krasnopolsky, “Spatially-resolved high-resolution spectroscopy of Venus 2. Variations of HDO, OCS, and SO2 at the cloud tops,” Icarus 209, 314–322 (2010).

    Article  ADS  Google Scholar 

  4. L. Clarisse, D. Hurtmans, C. Clerbaux, J. Hadji-Lazaro, Y. Ngadi, and P.-F. Coheur, “Atmospheric measurement techniques retrieval of sulphur dioxide from the Infrared Atmospheric Sounding Interferometer (IASI),” Atmos. Meas. Tech. 5, 581–594 (2012).

    Article  Google Scholar 

  5. Y. G. Borkov, O. M. Lyulin, T. M. Petrova, A. M. Solodov, A. A. Solodov, V. M. Deichuli, and V. I. Perevalov, “CO2-broadening and shift coefficients of sulfur dioxide near 4 μm,” J. Quant. Spectrosc. Radiat. Transfer 225, 119–124 (2019).

    Article  ADS  Google Scholar 

  6. I. E. Gordon, L. S. Rothman, C. Hill, R. V. Kochanov, Y. Tan, P. F. Bernath, M. Birk, V. Boudon, A. Campargue, K. V. Chance, B. J. Drouin, J.-M. Flaud, R. R. Gamache, J. T. Hodges, D. Jacquemart, V. I. Perevalov, A. Perrin, K. P. Shine, M.-A. H. Smith, J. Tennyson, G. C. Toon, H. Tran, V. G. Tyuterev, A. Barbe, A. G. Csaszar, V. M. Devi, T. Furtenbacher, J. J. Harrison, J.-M. Hartmann, A. Jolly, T. J. Johnson, T. Karman, I. Kleiner, A. A. Kyuberis, J. Loos, O. M. Lyulin, S. T. Massie, S. N. Mikhailenko, N. Moazzen-Ahmadi, H. S. P. Muller, O. V. Naumenko, A. V. Nikitin, O. L. Polyansky, M. Rey, M. Rotger, S. W. Sharpe, K. Sung, E. Starikova, S. A. Tashkun, Auwera J. Vander, G. Wagner, J. Wilzewski, P. Wcislo, S. Yu, and E. J. Zak, “The HITRAN2016 molecular spectroscopic database,” J. Quant. Spectrosc. Radiat. Transfer 203, 3–69 (2017).

    Article  ADS  Google Scholar 

  7. N. Jacquinet-Husson, R. Armante, N. A. Scott, A. Chedin, L. Crepeau, C. Boutammine, A. Bouhdaoui, C. Crevoisier, V. Capelle, C. Boonne, N. Poulet-Crovisier, A. Barbe, Ch. D. Benner, V. Boudon, L. R. Brown, J. Buldyreva, A. Campargue, L. H. Coudert, V. M. Devi, M. J. Down, B. J. Drouin, A. Fayt, C. Fittschen, J.-M. Flaud, R. R. Gamache, J. J. Harrison, C. Hill, O. Hodnebrog, S.-M. Hu, D. Jacquemart, A. Jolly, E. Jimenez, N. N. Lavrentieva, A.-W. Liu, L. Lodi, O. M. Lyulin, S. T. Massie, S. Mikhailenko, H. S. P. Muller, O. V. Naumenko, A. Nikitin, C. J. Nielsen, J. Orphal, V. Perevalov, A. Perrin, E. Polovtseva, A. Predoi-Cross, M. Rotger, A. A. Ruth, S. S. Yu, K. Sung, S. A. Tashkun, J. Tennyson, Vl. G. Tyuterev, Auwera J. Vander, B. A. Voronin, and A. Makie, “The 2015 edition of the GEISA spectroscopic database,” J. Mol. Spectrosc. 327, 31–72 (2016).

    Article  ADS  Google Scholar 

  8. R. Tóbiás, T. Furtenbacher, A. G. Császár, O. V. Naumenko, and B. Piorier, “Critical evaluation of measured rotational vibrational transitions of four sulphur isotopologues of S16O2,” J. Quant. Spectrosc. Radiat. Transfer 208, 152–163 (2018).

    Article  ADS  Google Scholar 

  9. D. Underwood, J. Tennyson, S. Yurchenko, X. Huang, D. Schwenke, T. Lee, S. Clausen, and A. Fateev, “ExoMol molecular line lists-XIV. The rotation-vibration spectrum of hot SO2,” Mon. Not. Roy. Astron. Soc. 459, 3890–3899 (2016).

    Article  ADS  Google Scholar 

  10. T. Furtenbacher and A. G. Csaszar, “MARVEL: Measured Active Rotational-Vibrational Energy Levels. II. Algorithmic improvements,” J. Quant. Spectrosc. Radiat. Transfer 113, 929–935 (2012).

    Article  ADS  Google Scholar 

  11. W. J. Lafferty, A. S. Pine, G. Hilpert, R. L. Sams, and J.-M. Flaud, “The ν1 + ν3 and 2ν1 + ν3 band systems of SO2: Line positions and intensities,” J. Mol. Spectrosc. 176, 280–286 (1996).

    Article  ADS  Google Scholar 

  12. W. J. Lafferty, A. S. Pine, J.-M. Flaud, and C. Camy-Peyret, “The 2ν3 band of 32S16O2: Line positions and intensities,” J. Mol. Spectrosc. 157, 499–511 (1993).

    Article  ADS  Google Scholar 

  13. W. J. Lafferty, J.-M. Flaud, and G. Guelachvili, “Analysis of the 2ν1 band system of SO2,” J. Mol. Spectrosc. 188, 106–107 (1998).

    Article  ADS  Google Scholar 

  14. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, I. B. Bolotova, I. A. Konov, V.-M. Horneman, and C. Leroy, “High resolution analysis of the SO2 spectrum in the 2600–2900 cm−1 region: 2ν3, ν2 + 2ν3 − ν2 and 2ν1 + ν2 bands,” J. Quant. Spectrosc. Radiat. Transfer 113, 500–517 (2012).

    Article  ADS  Google Scholar 

  15. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, A. S. Belova, S. Bauerecker, C. Maul, C. Sydov, and V.-M. Horneman, “High resolution analysis of the (111) vibrational state of SO2,” J. Quant. Spectrosc. Radiat. Transfer 144, 1–10 (2014).

    Article  ADS  Google Scholar 

  16. I. Vasilenko, O. Naumenko, and V.-M. Horneman, http://www.hrms-bilbao2018.com/daily-program.html. Cited February 25, 2020.

  17. O. V. Naumenko, I. A. Vasilenko, and V.-M. Horneman, http://vesta.u-bourgogne.fr/hrms/Program/ AbsBook-HRMS-26-HRefs.pdf. Cited February 25, 2020.

  18. O. N. Ulenikov, E. S. Bekhtereva, O. V. Gromova, S. Alanko, V.-M. Horneman, and C. Leroy, “Analysis of highly excited "hot” bands in the SO2 molecule: ν2 + 3ν3 − ν2, 2ν1 + ν2 + ν3 − ν2," Mol. Phys. 108, 1253–1261 (2010).

    Article  ADS  Google Scholar 

  19. V. Dana, J.-Y. Mandin, A. Barbe, J. J. Plateaux, and S. Bouazza, “The 3ν3 band of 32S16O2: Line positions and intensities,” J. Mol. Spectrosc. 154, 51–60 (1992).

    Article  ADS  Google Scholar 

  20. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, I. B. Bolotova, C. Leroy, V.-M. Horneman, and S. Alanko, “High resolution study of the ν1 + 2ν2 − ν2 and 2ν2 + ν3 − ν2 “hot” bands and ro-vibrational re-analysis of the ν1 + ν22 + ν3/3ν2 polyad of the 32SO2 molecule," J. Quant. Spectrosc. Radiat. Transfer 112, 486–512 (2011).

    Article  ADS  Google Scholar 

  21. O. N. Ulenikov, E. S. Bekhtereva, V.-M. Horneman, S. Alanko, and O. V. Gromova, “High resolution study of the 3ν1 band of SO2,” J. Mol. Spectrosc. 255, 111–121 (2009).

    Article  ADS  Google Scholar 

  22. X. Huang, D. W. Schwenke, and T. J. Lee, “Quantitative validation of Ames IR intensity and new line lists for 32/33/34SO2, 32S18O2, and 16O32S18O,” J. Quant. Spectrosc. Radiat. Transfer 225, 327–336 (2019).

    Article  ADS  Google Scholar 

Download references

Funding

This work was financially supported by the project no. АААА-А17-117021310147-0 and the Russian Foundation for Basic Research (project no. 18-35-00575).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to I. A. Vasilenko, O. V. Naumenko or V.-M. Horneman.

Ethics declarations

The authors declare that they have no conflict of interes

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vasilenko, I.A., Naumenko, O.V. & Horneman, VM. Expert List of Absorption Lines of the SO2 Molecule in the 2000–3000 cm–1 Spectral Region. Atmos Ocean Opt 33, 443–448 (2020). https://doi.org/10.1134/S1024856020050188

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1024856020050188

Keywords:

Navigation