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A Procedure for the Deposition of Macrocomponents in Determining Selenium and Tellurium in Metallurgical Materials by Inductively Coupled Plasma Atomic Emission Spectrometry

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Abstract

Studies on the separation of the Se and Te trace components from Co, Ni, Cu, Fe, Cr, Mo, and W macrocomponents for their determination by inductively coupled plasma atomic emission spectrometry are performed. It is found that the use of sodium oxalate and sodium fluoride as precipitants results in the almost complete removal of four macrocomponents Co, Ni, Cu, and Fe from the analyzed solutions. It is shown that the introduction of hydrofluoric acid in a certain amount leads to the inhibition of the process of the coprecipitation of Se and Te in the separation of the material matrix. A procedure is developed for the simultaneous determination of the concentrations of Se and Te in materials with high concentrations of Co, Ni, Cu, and Fe by inductively coupled plasma atomic emission spectrometry.

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Funding

The work was carried out within the framework of the State Assignment of Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciencesusing the equipment of the Ural-M collective use center.

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Authors and Affiliations

  1. Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    A. V. Maiorova, A. A. Belozerova & M. N. Bardina

  2. Ural Federal University Named after the First President of Russia B. N. Yeltsin, 620002, Yekaterinburg, Russia

    A. V. Maiorova, A. A. Belozerova & M. N. Bardina

Authors
  1. A. V. Maiorova
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  2. A. A. Belozerova
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  3. M. N. Bardina
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Correspondence to A. V. Maiorova.

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Translated by V. Kudrinskaya

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Maiorova, A.V., Belozerova, A.A. & Bardina, M.N. A Procedure for the Deposition of Macrocomponents in Determining Selenium and Tellurium in Metallurgical Materials by Inductively Coupled Plasma Atomic Emission Spectrometry. J Anal Chem 76, 930–938 (2021). https://doi.org/10.1134/S1061934821080104

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  • DOI: https://doi.org/10.1134/S1061934821080104

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