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Ceramic nanotubes for polymer composites with stable anticorrosion properties

  • Nanomaterials and Ceramics
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Abstract

The use of natural halloysite clay tubes 50 nm in diameter as nanocontainers for loading, storing, and slowly releasing organic corrosion inhibitors is described. Loaded nanotubes can be mixed well with many polymers and dyes in amounts of 5–10 wt % to form a ceramic framework (which increases the strength of halloysite composites by 30–50%), increase the adhesion of these coatings to metals, and allow for the slow release of corrosion inhibitors in defects of coatings. A significant improvement of protective anticorrosion properties of polyacryl and polyurethane coatings containing ceramic nanotubes loaded with benzotriazole and hydroxyquinoline is demonstrated.

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References

  1. E. Joussein, S. Petit, J. Churchman, et al., Clay Miner. 40, 383 (2005).

    Article  Google Scholar 

  2. Y. Lvov, D. Shchukin, H. Möhwald, et al., ACS Nano 2, 814 (2008).

    Article  Google Scholar 

  3. M. Du, B. Guo, and D. Jia, Polymer Intern. 59, 574 (2010).

    Google Scholar 

  4. Y. Lvov and E. Abdullayev, Progress Polymer Sci. 38, 1690 (2013).

    Article  Google Scholar 

  5. E. Abdullayev, V. Abbasov, A. Tursunbayeva, et al., ACS Appl. Mater. Surf. 5, 4464 (2013).

    Google Scholar 

  6. E. Abdullayev and Y. Lvov, J. Mater. Chem. B 1, 2894 (2013).

    Article  Google Scholar 

  7. E. Abdullayev, A. Joshi, W. Wei, et al., ACS Nano 6, 7216 (2012).

    Article  Google Scholar 

  8. W-O. Yah, A. Takahara, and Y. Lvov, J. Am. Chem. Soc. 134, 1853 (2012).

    Article  Google Scholar 

  9. X. Lai, M. Agarwal, Y. Lvov, et al., J. Appl. Toxicity 33, 1316 (2013).

    Google Scholar 

  10. V. Vergaro, E. Abdullayev, R. Cingolani, et al., Biomacromol. 11, 820 (2010).

    Article  Google Scholar 

  11. Y. Zhang, Y. Chen, H. Zhang, et al., J. Inorg. Biochem. 118, 59 (2013).

    Article  Google Scholar 

  12. D. Shchukin and H. Möhwald, Small 3, 926 (2007).

    Article  Google Scholar 

  13. F. Presuel-Moreno, M. Jakab, N. Tailleart, et al., Mater. Today 11, 14 (2008).

    Article  Google Scholar 

  14. H. Kelly, P. Deasy, E. Ziaka, et al., Int. J. Pharm. 274, 167 (2004).

    Article  Google Scholar 

  15. Y. Lvov, A. Aerov, and R. Fakhrullin, Adv. Colloid Interface Sci. 201, 1287 (2013).

    Google Scholar 

  16. E. Abdullayev, K. Sakakibara, K. Okamoto, et al., ACS Appl. Mater. Interf. 3, 4040 (2011).

    Article  Google Scholar 

  17. K. Babic-Samardzija and N. Hackerman, J. Solid State Electrochem. 9, 483 (2005).

    Article  Google Scholar 

  18. B. Guo, Y. Lei, F. Chen, et al., Appl. Surf. Sci. 7, 188 (2008).

    Google Scholar 

  19. B. Guo, Q. Zou, Y. Lei, et al., New Chem. Mater. 36, 32 (2008).

    Google Scholar 

  20. M. Liu, B. Guo, M. Du, et al., Nanotechnology 18, 455703 (2007).

    Article  ADS  Google Scholar 

  21. M. Du, B. Guo, and D. Jia, Eur. Polym. J. 42, 1362 (2006).

    Article  Google Scholar 

  22. G. Cavallaro, G. Lazzara, S. Milioto, et al., Langmuir 27, 1158 (2011).

    Article  Google Scholar 

  23. M. Liu, C. Wu, Y. Jiao, et al., J. Mater. Chem. B 1, 2078 (2013).

    Article  Google Scholar 

  24. Z. Huang, Z. Jia, B. Guo, et al., China Plast. Ind. 36, 29 (2008).

    Google Scholar 

  25. D. Fix, D. Andreeva, H. Möhwald, et al., Adv. Funct. Mater. 19, 1720 (2009).

    Article  Google Scholar 

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Authors and Affiliations

  1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia

    R. F. Fakhrullin

  2. S. Seifullin Kazakh Agro Technical University, pr. Pobedy 62, Astana, 010000, Kazakhstan

    A. Tursunbayeva

  3. Karaganda State Technical University, Karaganda, 100027, Kazakhstan

    V. S. Portnov

  4. Louisiana Tech University, Ruston, LA, 71272, USA

    Yu. M. L’vov

Authors
  1. R. F. Fakhrullin
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  2. A. Tursunbayeva
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  3. V. S. Portnov
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  4. Yu. M. L’vov
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Corresponding author

Correspondence to Yu. M. L’vov.

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Fakhrullin, R.F., Tursunbayeva, A., Portnov, V.S. et al. Ceramic nanotubes for polymer composites with stable anticorrosion properties. Crystallogr. Rep. 59, 1107–1113 (2014). https://doi.org/10.1134/S1063774514070104

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  • DOI: https://doi.org/10.1134/S1063774514070104

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