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New Sterically Hindered Bis-o-Benzoquinones with Electron-Donor Bridging Groups and Related Binuclear Triphenylantimony(V) Catecholate Complexes

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Abstract

New bis-o-benzoquinones (3,5-Q)-6-CH2O–(CH2)n–OCH2-6-(3,5-Q) (n = 2 (L1), 4 (L2), and 6 (L3)) and (3,5-Q)-6-(CH2OCH2)3-6-(3,5-Q) (L4) (3,5-Q is 3,5-di-tert-butyl-o-benzoquinone) with various diol spacers have been synthesized and characterized. The oxidative addition of SbPh3 to these bis-o-benzoquinones affords binuclear triphenylantimony(V) bis(catecholate) complexes Ph3Sb(3,5-Cat)-6-CH2O–(CH2)n–OCH2-6-(3,5-Cat)SbPh3 (I–III, respectively) and Ph3Sb(3,5-Cat)-6-(CH2OCH2)3-6-(3,5-Cat)SbPh3 (IV) (3,5-Cat is 3,5-di-tert-butyl catecholate). The molecular structures of quinones L1–L4 and bis(catecholate) complex I in the crystalline state were determined by X-ray diffraction analysis (CIF files CCDC nos. 1998601 (L1), 1998602 (L2), 1998603 (L3), 1998604 (L4), and 1998605 (I ∙ n-pentane)).

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ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Analytical Center for Collective Use at the Razuvaev Institute of Organometallic Chemistry (Russian Academy of Sciences) in terms of the federal target program “Investigation and Developments on Priority Directions of the Scientific Technological Complex of Russia for 2014–2020” (unique project identifier RFMEFI62120X0040).

Funding

The synthesis of bis-o-benzoquinones was supported by the Russian Foundation for Basic Research (project no. 19-33-90263). The synthesis and study of the antimony(V) catecholate complexes were in the accordance with state assignment of the Razuvaev Institute of Organometallic Chemistry (Russian Academy of Sciences).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    S. Yu. Bukhvalova, E. R. Zhiganshina, T. V. Astaf’eva, M. V. Arsenyev, E. V. Baranov, S. A. Chesnokov & A. I. Poddel’sky

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  1. S. Yu. Bukhvalova
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  2. E. R. Zhiganshina
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  3. T. V. Astaf’eva
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  4. M. V. Arsenyev
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  6. S. A. Chesnokov
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  7. A. I. Poddel’sky
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Correspondence to A. I. Poddel’sky.

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Translated by E. Yablonskaya

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Bukhvalova, S.Y., Zhiganshina, E.R., Astaf’eva, T.V. et al. New Sterically Hindered Bis-o-Benzoquinones with Electron-Donor Bridging Groups and Related Binuclear Triphenylantimony(V) Catecholate Complexes. Russ J Coord Chem 46, 817–827 (2020). https://doi.org/10.1134/S1070328420120027

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