Skip to main content
SpringerLink
Log in

Analytical Control of the Mass Fraction of the Basic Substance in Antioxidants 2,4,6-Tri-tert-butylphenol and Pentaerythritol Tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate) by High-Performance Liquid Chromatography

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

A technique for high-performance liquid chromatographic determination of the mass fraction of the basic substance in antioxidants 2,4,6-tri-tert-butylphenol (antioxidant P-23) and pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate) (antioxidant Agidol-110) was developed. The technique consists in dissolution of the antioxidant in acetonitrile, followed by adding ethanol, separation of the basic substance and impurities by column chromatography, and recording the chromatogram, whereupon the mass fraction of the basic substance is calculated by the normalization method. Use of this technique allows determining the mass fraction of the basic substance in the 98.0–100% range for P-23 antioxidant and in the 95.0–100% range for Agidol-110 antioxidant. The technique developed can be recommended for analytical monitoring of the mass fraction of the basic substance in antioxidants for the purpose of incoming inspection of the raw materials and of the control after expiration of the warranty storage period.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Rogov, N.G. and Ishchenko, M.A., Smesevye raketnye tverdye topliva: Komponenty. Trebovaniya. Svoistva (Mixed Rocket Solid Propellants: Components, Requirements, Properties), St. Petersburg: Sankt-Peterb. Gos. Tech. Inst. (Tech. Univ.), 2005.

  2. Antioxidant P-23: Technical Specifications TU 2425-030-05807999-2002, Novocherkassk: Novocherkassk. Zavod Sintet. Produktov, 2002.

  3. Agidol-110: Technical Specifications TU 2492-447-05742686-2006, Sterlitamak: Sterlitamak. Neftekhim. Zavod, 2006.

  4. COMMON CHEMISTRY. A CASSOLUTION https://commonchemistry.cas.org/

  5. Sychev, K.S., Prakticheskoe rukovodstvo po zhidkostnoi khromatografii (A Practical Guide on Liquid Chromatography), Moscow: Tekhnosfera, 2010.

  6. Draper, N.R. and Smith, H., Applied Regression Analysis, 2 ed., New York: John Wiley & Sons, 1981.

  7. Rekomendatsii po mezhdunarodnoi standartizatsii RMG61-2010. Pokazateli tochnosti, pravil’nosti, pretsizionnosti metodik kolichestvennogo khimicheskogo analiza. Metody otsenki (Recommendations for Intersate Standardization RMG61-2010: Indicators of Accuracy, Correctness, Precision of Techniques of Quantitative Chemical Analysis: Assessment Methods), Moscow: Standartinform, 2012.

Download references

Author information

Authors and Affiliations

  1. Research Institute of Polymeric Materials, Joint-Stock Company, 614113, Perm, Russia

    G. V. Kalikina, O. V. Shestakova, O. A. Vozisova, M. A. Leukhina & I. L. Isupova

Authors
  1. G. V. Kalikina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Shestakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. A. Vozisova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. A. Leukhina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. L. Isupova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. A. Leukhina.

Ethics declarations

No conflict of interest was declared by the authors.

Additional information

Translated from Rossiiskii Khimicheskii Zhurnal, 2020, Vol. 64, No. 1, pp. 86–92 https://doi.org/10.6060/rcj.2020641.9.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kalikina, G.V., Shestakova, O.V., Vozisova, O.A. et al. Analytical Control of the Mass Fraction of the Basic Substance in Antioxidants 2,4,6-Tri-tert-butylphenol and Pentaerythritol Tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate) by High-Performance Liquid Chromatography. Russ J Gen Chem 91, 1869–1874 (2021). https://doi.org/10.1134/S1070363221090334

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363221090334

Keywords:

Search

Navigation