Skip to main content
Log in

Surface tension of solutions of low-molecular epoxy resins in monoglycidyl ether on the interface with air and production of filled epoxy compositions

  • Physicochemical Studies of Systems and Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The surface tension of solutions of epoxydiane resin (M n ∼400) in versatic acid monoglycidyl ether (Cardura) at the interface with air in the range of concentrations c = 5–60% in the presence of non-ionic surfactants was studied. The effect of concentration of epoxydiane resin in solution on the rate of dispersion of pigment particles (filler) was revealed. The structural parameters of aggregates of the epoxydiane resin molecules and pigment particles in the composition, as well as the optimal concentration of oligomeric resin, corresponding to the maximum rate of dispersion of pigments in solution were determined in the approximation of the model of fractal clusters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Lakokrasochnye materialy i pokrytiya: Teoriya i praktika (Painr and Varnish Materials and Films). Lyamburn, R., Ed., Mashlyakovskii, L.M. and Frost, A.M., Eds., St.-Petersburg.: Khimiya, 1991.

    Google Scholar 

  2. Chernin, I.Z., Smekhov, F.M., and Zherdyaev, Yu.M., Epoksidnye polimery i kompozitsii (Epoxy Polymers and Compositions), Moscow: Khimiya, 1982.

    Google Scholar 

  3. Krasovskii, A.N., Potashev, M.G., Filippov, V.N., and Mnatsakanov S.S., Zh. Prikl. Khim., 2006, vol. 79, no. 10, pp. 1693–1700.

    Google Scholar 

  4. Krasovskii, A.N., Kharlampiev, A.A., and Krasheninnikov, V.A., Vysokomol. Soedin. A, 1997, vol. 39, no. 2, pp. 250–258.

    CAS  Google Scholar 

  5. Krasovskii, A.N., Kharlampiev, A.A., and Plodistyi, A.B., Zh. Prikl. Khim., 1997, vol. 70, no. 4, pp. 661–669.

    CAS  Google Scholar 

  6. Demidov, V.N., Dokl. Akad. Nauk, 2004, vol. 394, no. 2, pp. 218–221.

    Google Scholar 

  7. Feder, J., Fractals, New York: Plenum Press, 1988.

    Google Scholar 

  8. Filippov, V.N., Cand. Sci. (Chem.) Dissertation, St.-Petersburg, 2004.

  9. Krasovskii, A.N., Filippov, V.N., and Novikov, D.V., Zh. Prikl. Khim., 2007, vol. 80, no. 7, pp. 1190–1199.

    Google Scholar 

  10. Pugachevich, P.P., Beglyarov, E.M., Lavygin, I.A., Poverkhnostnye yavleniya v polimerakh (Surface Phenomena in Polimers), Moscow: Khimiya, 1982.

    Google Scholar 

  11. De Zhen, P., Idei skeilinga v fizike polimerov (Skeiling’s Ideas in Physic of Polymers), Lifshits, I.M., Moscow: Mir, 1982.

    Google Scholar 

  12. Von Smoluchovski, M., Phys. Z., 1916, vol. 17, pp. 557–599.

    Google Scholar 

  13. Wu, S., Polymer Interfaces and Adhesion, New-York: Marcel Dekker, 1982.

    Google Scholar 

  14. Avnir, D., Farin, D., and Pfeifer, P., Nature, 1984, vol. 308, pp. 261–263.

    Article  CAS  Google Scholar 

  15. Hare, C.H., Protective Coatings. Fundamentals of Chemistry and Composition, London: Technology Publishing Comp., 2001.

    Google Scholar 

  16. Drinberg, S.A. and Itsko, E.F., Rastvoriteli dlya lakokrasochnykh materialov (Solvents for Paint and Varnish Materials), St.-Petersburg: Khimizdat, 2003.

    Google Scholar 

  17. SERVO Coating Additives in Primary Formulations for Various Coatings, Delden: Sasol Servo BV, 2002.

  18. Kuleshov, I.D., Lakokrasochnye materialy i ikh primenenie, 2002, no. 12, pp. 4–8.

  19. Korsunskii, L.F., Kalinskaya, T.V., and Stepin, S.N., Neorganicheskie pigmenty: Spravochnik (Inorganic Pigments: Handbook), St.-Petersburg: Khimiya, 1992.

    Google Scholar 

  20. Ermilov, P.I., Indeikin, E.A., and Tolmachev, I.A., Pigmenty i pigmentirovannye lakokrasochnye materialy (Pigments and Paint and Varnish Materials Pigmented), Leningrad: Khimiya, 1987.

    Google Scholar 

  21. Khennei, N., Khimiya tverdogo tela (The Chemistry of Solid), Boldyrev, V.V., Ed., Moscow: Mir, 1971.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © A.N. Krasovskii, S.A. Lopato, M.G. Potashev, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 9, pp. 1436–1444.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krasovskii, A.N., Lopato, S.A. & Potashev, M.G. Surface tension of solutions of low-molecular epoxy resins in monoglycidyl ether on the interface with air and production of filled epoxy compositions. Russ J Appl Chem 82, 1533–1541 (2009). https://doi.org/10.1134/S1070427209090067

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427209090067

Keywords

Navigation