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Co- and ter-polymerization of poly(o-anthranilic acid): Synthesis and characterization

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Abstract

Three series of copolymers o-antranilic acid-co-aniline, o-antranilic acid-co-o-toluidine and otoluidine-co-aniline were synthesized by oxidative chemical polymerization and characterized by FTIR and UV–Vis spectroscopy, elemental analysis and conductivity. Poly(o-antranilic acid-co-o-toluidine) was synthesized at room temperature, and poly(o-toluidine-co-aniline) at molar ratio 25: 75 demonstrated a relatively high conductivity; whereas lower conductivity was observed for poly(o-antranilic acid-co-aniline). The terpolymers exhibited excellent solubility and higher conductivity than the two substituted anilines.

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References

  1. F. Trinidal, M. C. Montemayor, and E. Falas, J. Elec-troñhem. Soc. 138, 3186 (1991).

    Article  Google Scholar 

  2. D. C. Trivedi and S. K. D. Hhawan, J. Mater. Chem. 2, 1091 (1992).

    Article  CAS  Google Scholar 

  3. T. Kobayashi, H. Yoneyama, and H. Tamura, J. Elec-troanal. Chem. 161, 419 (1984).

    Article  CAS  Google Scholar 

  4. E. M. Genies, M. Lipkowsski, C. Santier, and E. Viel, Synth. Met. 18, 631 (1987).

    Article  CAS  Google Scholar 

  5. E. W. Paul, A. J. Ricc, and M. S. Wrighton, J. Phys. Chem. 89, 1441 (1985).

    Article  CAS  Google Scholar 

  6. P. N. Bartlett, B. M. A. Patricia, and K. L. C. Sin, Sen-sor Actuators 19, 125 (1989).

    Article  CAS  Google Scholar 

  7. N. Gospodinova and L. Terlemezyan, Prog. Polym. Sci. 23, 1443 (1998).

    Article  CAS  Google Scholar 

  8. A. Pron and P. Pron, Prog. Polym. Sci. 27, 135 (2002).

    Article  CAS  Google Scholar 

  9. J. Stejskal, I. Sapurina, and M. Trchova, Prog. Polym. Sci. 35, 1420 (2010).

    Article  CAS  Google Scholar 

  10. J. X. Huang and R. B. Kaner, J. Am. Chem. Soc. 126, 851 (2004).

    Article  CAS  Google Scholar 

  11. B. K. Yang, K. C. Jae, A. Y. Jeong, and W. H. Jin, Synth. Met. 131, 79 (2002).

    Article  Google Scholar 

  12. M. Sato, S. Tanaka, and K. Kaeriyama, J. Chem. Soc., Chem. Commun. 1986, 873 (1986).

    Article  Google Scholar 

  13. Y. Cao, P. Smith, and A. J. Hegger, Synth. Met. 57, 3514 (1993).

    Article  CAS  Google Scholar 

  14. Y. Lee, D. Shin, J. Cho, Y. H. Park, Y. Son, and D. H. Baik, J. App. Polym. Sci. 69, 2641 (1998).

    Article  CAS  Google Scholar 

  15. Y. Siyu, N. T. Do, L. H. Dao, and A. K. Vijh, Synth. Met. 88, 65 (1997).

    Article  Google Scholar 

  16. J. Vivekanandan, V. Ponnusamy, A. Mahudeswaran, and P. S. Vijayanand, Arch. Appl. Sci. Res. 3 (6), 147 (2011).

    CAS  Google Scholar 

  17. M. Blaha, M. Varga, J. Prokes, A. Zhigunov, and J. Vohlidal, Eur. Polym. J. 49, 3904 (2013).

    Article  CAS  Google Scholar 

  18. M. R. Nabid, Z. Zamiraei, and R. Sedghi, Iran. Polym. J. 19 (9), 699 (2010).

    CAS  Google Scholar 

  19. A. H. Navarchian, Z. Hasanzadeh, and M. Joulazadeh, Adv. Polym. Technol. 32 (3), 21356 (2013).

    Article  Google Scholar 

  20. S. M. Hassan, A. G. Baker, and H. I. Jaffar, Int. J. Basic Appl. Sci. 1 (2), 352 (2012).

    Google Scholar 

  21. A. Watanabe, K. Mori, A. Iwabuchi, Y. Iwasaki, and Y. Nakamura, Macromolecules 22, 3521 (1989).

    Article  CAS  Google Scholar 

  22. M. C. Gupta and S. S. Umare, Macromolecules 25, 138 (1992).

    Article  CAS  Google Scholar 

  23. Y. H. Liao, M. Angelopoulos, and K. Levon, J. Polym. Sci., Part A: Polym. Chem. 33, 2725 (1995).

    Article  CAS  Google Scholar 

  24. G. D. Storrier, S. B. Colbran, and D. Hibbert, Synth. Met. 62, 179 (1994).

    Article  CAS  Google Scholar 

  25. D. Kumar, Synth. Met. 114, 369 (2000).

    Article  CAS  Google Scholar 

  26. M. P. Huang, X.-G. Li, Y.-L. Yang, X.-S. Wang, and D. Yan, J. Appl. Polym. Sci. 81, 1838 (2001).

    Article  CAS  Google Scholar 

  27. N. Gupta and D. Kumar, Indian J. Eng. Mater. Sci. 16, 403 (2009).

    Google Scholar 

  28. P. Savitha and D. N. Sathyanarayana, Polym. Int. 53, 106 (2004).

    Article  CAS  Google Scholar 

  29. B. L. Rivas and C. O. Sanchez, J. Appl. Polym. Sci. 89, 2641 (2003).

    Article  CAS  Google Scholar 

  30. I. A. Sophia, G. Gopu, and C. Vedhi, Open J. Synth. Theory Appl. 1, 1 (2012).

    Article  CAS  Google Scholar 

  31. M. M. Ayad, N. A. Salahuddin, A. K. Abou-Seif, and M. O. Alghaysh, Eur. Polym. J. 44, 426 (2008).

    Article  CAS  Google Scholar 

  32. M. T. Nguyen and A. F. Diaz, Macromolecules 28, 3411 (1995).

    Article  CAS  Google Scholar 

  33. O. Melad and M. Esleem, Open J. Org. Polym. Mater. 5, 31 (2015).

    Article  CAS  Google Scholar 

  34. X. G. Li, M. R. Huang, L. H. Zhu, and Y. Yang, J. Appl. Polym. Sci. 82, 790 (2001).

    Article  CAS  Google Scholar 

  35. P. Savitha and D. N. Sathyanarayana, J. Polym. Sci., Part A: Polym. Chem. 43, 3040 (2005).

    Article  CAS  Google Scholar 

  36. X. G. Li, W. Duan, M.-R. Huang, and Yu. Yang, J. Polym. Sci., Part A: Polym. Chem. 39, 3989 (2001).

    Article  CAS  Google Scholar 

  37. H. J. Salvagion, D. F. Acevedo, M. C. Miras, and A. J. Motheo, J. Polym. Sci., Part A: Polym. Chem. 42, 5587 (2004).

    Article  Google Scholar 

  38. W. Yen, T. Xun, and S. Yan, J. Polym. Sci. 27, 2385 (1989).

    Google Scholar 

  39. O. M. Ya, Yu. V. Korshak, and M. I. Shtilman, Russ. J. Phys. Chem. B 9, 306 (2015).

    Article  Google Scholar 

  40. O. M. Ya, Yu. V. Korshak, M. I. Shtilman, and I. V. Solov’eva, Russ. J. Gen. Chem. 84, 2445 (2014).

    Article  Google Scholar 

  41. M. Ida and Z. Majda, J. Polym. Sci. 39, 2471 (2001).

    Article  Google Scholar 

  42. O. M. Ya, Yu. V. Korshak, M. I. Shtilman, and I. S. Strakhov, Theor. Exp. Chem. 50, 311 (2014).

    Article  Google Scholar 

  43. C. Theimann and C. M. A. Brett, Synth. Met. 123, 1 (2001).

    Article  Google Scholar 

  44. H. S. O. Chan, S. C. Ng, W. S. Sim, K. L. Tan, B. T. G. Tan, Macromolecules 25, 6029 (1992).

    Article  CAS  Google Scholar 

  45. P. S. Rao and D. N. Sathyanarayana, Synth. Met. 138, 519 (2003).

    Article  CAS  Google Scholar 

  46. D. S. Pearson, P. A. Pincus, and G. W. Heffiner, Mac-romolecules 26, 1570 (1993).

    Article  CAS  Google Scholar 

  47. W. Zheng, M. Angelopoulos, A. J. Epstein, and M. Diarmid, Macromolecules 30, 7634 (1997).

    Article  CAS  Google Scholar 

  48. S. K. Dhawan and D. C. Trivedi, Synth. Met. 60, 63 (1993).

    Article  CAS  Google Scholar 

  49. Y. Wei, R. Hariharan, and S. A. Patel, Macromolecules 23, 758 (1990).

    Article  CAS  Google Scholar 

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Melad, O. Co- and ter-polymerization of poly(o-anthranilic acid): Synthesis and characterization. Polym. Sci. Ser. B 57, 669–676 (2015). https://doi.org/10.1134/S1560090415060135

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  • DOI: https://doi.org/10.1134/S1560090415060135

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