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The statistical integrals of bound and quasi-bound states of gas phase complexes formed by symmetrical nonpoint monomers

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
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Abstract

Equations for calculations of the statistical integrals of bound and quasi-bound weak binary complex states in the gas phase are extended to nonpoint monomers. The equations for states of both types are derived using a unified approach different from those reported earlier. The equations can be used for estimating the thermodynamic functions, equilibrium constants, and concentrations of weakly bound complexes in the ideal gas state and for verifying the results of numerical simulation of association processes in the gas phase.

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Authors and Affiliations

  1. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603600, Russia

    S. K. Ignatov, N. N. Vyshinskii & A. G. Razuvaev

Authors
  1. S. K. Ignatov
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  2. N. N. Vyshinskii
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  3. A. G. Razuvaev
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Correspondence to S. K. Ignatov.

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Original Russian Text © S.K. Ignatov, N.N. Vyshinskii, A.G. Razuvaev, 2010, published in Khimicheskaya Fizika, 2010, Vol. 29, No. 1, pp. 30–38.

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Ignatov, S.K., Vyshinskii, N.N. & Razuvaev, A.G. The statistical integrals of bound and quasi-bound states of gas phase complexes formed by symmetrical nonpoint monomers. Russ. J. Phys. Chem. B 4, 44–52 (2010). https://doi.org/10.1134/S1990793110010070

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  • DOI: https://doi.org/10.1134/S1990793110010070

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